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Potassium N-chloro-o-toluenesulfonamidate monohydrate
In the crystal structure of the title compound, K(+)·C(7)H(7)ClNO(2)S(−)·H(2)O, the K(+) ion is heptacoordinated by two O atoms from water molecules, four sulfonyl O atoms and the Cl atom of the anion. The S—N distance of 1.584 (3) Å is consistent with an S—N double bond. In the crystal, anions ar...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151940/ https://www.ncbi.nlm.nih.gov/pubmed/21836939 http://dx.doi.org/10.1107/S1600536811023555 |
| Sumario: | In the crystal structure of the title compound, K(+)·C(7)H(7)ClNO(2)S(−)·H(2)O, the K(+) ion is heptacoordinated by two O atoms from water molecules, four sulfonyl O atoms and the Cl atom of the anion. The S—N distance of 1.584 (3) Å is consistent with an S—N double bond. In the crystal, anions are connected by K(+) cations into layers parallel to the ab plane. The water molecules are coordinated to the K(+) cations and are additionally linked by intermolecular O—H⋯Cl and O—H⋯N hydrogen bonding. |
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