Potassium N-chloro-o-toluene­sulfonamidate monohydrate

In the crystal structure of the title compound, K(+)·C(7)H(7)ClNO(2)S(−)·H(2)O, the K(+) ion is hepta­coordinated by two O atoms from water mol­ecules, four sulfonyl O atoms and the Cl atom of the anion. The S—N distance of 1.584 (3) Å is consistent with an S—N double bond. In the crystal, anions ar...

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Detalles Bibliográficos
Autores principales: Gowda, B. Thimme, Foro, Sabine, Shakuntala, K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151940/
https://www.ncbi.nlm.nih.gov/pubmed/21836939
http://dx.doi.org/10.1107/S1600536811023555
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author Gowda, B. Thimme
Foro, Sabine
Shakuntala, K.
author_facet Gowda, B. Thimme
Foro, Sabine
Shakuntala, K.
author_sort Gowda, B. Thimme
collection PubMed
description In the crystal structure of the title compound, K(+)·C(7)H(7)ClNO(2)S(−)·H(2)O, the K(+) ion is hepta­coordinated by two O atoms from water mol­ecules, four sulfonyl O atoms and the Cl atom of the anion. The S—N distance of 1.584 (3) Å is consistent with an S—N double bond. In the crystal, anions are connected by K(+) cations into layers parallel to the ab plane. The water mol­ecules are coordinated to the K(+) cations and are additionally linked by inter­molecular O—H⋯Cl and O—H⋯N hydrogen bonding.
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spelling pubmed-31519402011-08-11 Potassium N-chloro-o-toluene­sulfonamidate monohydrate Gowda, B. Thimme Foro, Sabine Shakuntala, K. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, K(+)·C(7)H(7)ClNO(2)S(−)·H(2)O, the K(+) ion is hepta­coordinated by two O atoms from water mol­ecules, four sulfonyl O atoms and the Cl atom of the anion. The S—N distance of 1.584 (3) Å is consistent with an S—N double bond. In the crystal, anions are connected by K(+) cations into layers parallel to the ab plane. The water mol­ecules are coordinated to the K(+) cations and are additionally linked by inter­molecular O—H⋯Cl and O—H⋯N hydrogen bonding. International Union of Crystallography 2011-06-22 /pmc/articles/PMC3151940/ /pubmed/21836939 http://dx.doi.org/10.1107/S1600536811023555 Text en © Gowda et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gowda, B. Thimme
Foro, Sabine
Shakuntala, K.
Potassium N-chloro-o-toluene­sulfonamidate monohydrate
title Potassium N-chloro-o-toluene­sulfonamidate monohydrate
title_full Potassium N-chloro-o-toluene­sulfonamidate monohydrate
title_fullStr Potassium N-chloro-o-toluene­sulfonamidate monohydrate
title_full_unstemmed Potassium N-chloro-o-toluene­sulfonamidate monohydrate
title_short Potassium N-chloro-o-toluene­sulfonamidate monohydrate
title_sort potassium n-chloro-o-toluene­sulfonamidate monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151940/
https://www.ncbi.nlm.nih.gov/pubmed/21836939
http://dx.doi.org/10.1107/S1600536811023555
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