9-(2-Chloro­benz­yloxy)-6,7-dihydro-2H-benzo[c][1,2,4]triazolo[4,3-a]azepin-3(5H)-one

In the title mol­ecule, C(18)H(16)ClN(3)O(2), the seven-membered ring adopts an envelope conformation with the flap atom deviating by 0.801 (5) Å from the mean plane formed by the remaining non-H atoms. Inter­molecular N—H⋯O hydrogen bonds link the mol­ecules into centrosymmetric dimers. The crystal...

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Detalles Bibliográficos
Autores principales: Jin, Da-Cheng, Zhang, Wen-Bin, Piao, Feng-Yu, Han, Rong-Bi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151951/
https://www.ncbi.nlm.nih.gov/pubmed/21837190
http://dx.doi.org/10.1107/S1600536811024470
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author Jin, Da-Cheng
Zhang, Wen-Bin
Piao, Feng-Yu
Han, Rong-Bi
author_facet Jin, Da-Cheng
Zhang, Wen-Bin
Piao, Feng-Yu
Han, Rong-Bi
author_sort Jin, Da-Cheng
collection PubMed
description In the title mol­ecule, C(18)H(16)ClN(3)O(2), the seven-membered ring adopts an envelope conformation with the flap atom deviating by 0.801 (5) Å from the mean plane formed by the remaining non-H atoms. Inter­molecular N—H⋯O hydrogen bonds link the mol­ecules into centrosymmetric dimers. The crystal packing also exhibits weak inter­molecular C—H⋯N hydrogen bonds and π–π inter­actions with a short distance of 3.734 (3) Å between the centroids of the aromatic rings of neighbouring mol­ecules.
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spelling pubmed-31519512011-08-11 9-(2-Chloro­benz­yloxy)-6,7-dihydro-2H-benzo[c][1,2,4]triazolo[4,3-a]azepin-3(5H)-one Jin, Da-Cheng Zhang, Wen-Bin Piao, Feng-Yu Han, Rong-Bi Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(18)H(16)ClN(3)O(2), the seven-membered ring adopts an envelope conformation with the flap atom deviating by 0.801 (5) Å from the mean plane formed by the remaining non-H atoms. Inter­molecular N—H⋯O hydrogen bonds link the mol­ecules into centrosymmetric dimers. The crystal packing also exhibits weak inter­molecular C—H⋯N hydrogen bonds and π–π inter­actions with a short distance of 3.734 (3) Å between the centroids of the aromatic rings of neighbouring mol­ecules. International Union of Crystallography 2011-06-25 /pmc/articles/PMC3151951/ /pubmed/21837190 http://dx.doi.org/10.1107/S1600536811024470 Text en © Jin et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Jin, Da-Cheng
Zhang, Wen-Bin
Piao, Feng-Yu
Han, Rong-Bi
9-(2-Chloro­benz­yloxy)-6,7-dihydro-2H-benzo[c][1,2,4]triazolo[4,3-a]azepin-3(5H)-one
title 9-(2-Chloro­benz­yloxy)-6,7-dihydro-2H-benzo[c][1,2,4]triazolo[4,3-a]azepin-3(5H)-one
title_full 9-(2-Chloro­benz­yloxy)-6,7-dihydro-2H-benzo[c][1,2,4]triazolo[4,3-a]azepin-3(5H)-one
title_fullStr 9-(2-Chloro­benz­yloxy)-6,7-dihydro-2H-benzo[c][1,2,4]triazolo[4,3-a]azepin-3(5H)-one
title_full_unstemmed 9-(2-Chloro­benz­yloxy)-6,7-dihydro-2H-benzo[c][1,2,4]triazolo[4,3-a]azepin-3(5H)-one
title_short 9-(2-Chloro­benz­yloxy)-6,7-dihydro-2H-benzo[c][1,2,4]triazolo[4,3-a]azepin-3(5H)-one
title_sort 9-(2-chloro­benz­yloxy)-6,7-dihydro-2h-benzo[c][1,2,4]triazolo[4,3-a]azepin-3(5h)-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151951/
https://www.ncbi.nlm.nih.gov/pubmed/21837190
http://dx.doi.org/10.1107/S1600536811024470
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