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{4-Hy­droxy-N′-[(2E,3Z)-4-oxido-4-phenyl­but-3-en-2-yl­idene]benzo­hydra­zidato}diphenyl­tin(IV) methanol monosolvate

Two independent diphenyl­tin mol­ecules and two independent methanol mol­ecules comprise the asymmetric unit of the title compound, [Sn(C(6)H(5))(2)(C(17)H(14)N(2)O(3))]·CH(3)OH. The Sn atom in each is five-coordinated by a tridentate ligand and the ipso-C atoms of the Sn-bound benzene substituents....

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Detalles Bibliográficos
Autores principales: Affan, Md. Abu, Sam, Norrihan B., Ahmad, Fasihuddin B., White, Fraser, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151954/
https://www.ncbi.nlm.nih.gov/pubmed/21836941
http://dx.doi.org/10.1107/S1600536811023415
Descripción
Sumario:Two independent diphenyl­tin mol­ecules and two independent methanol mol­ecules comprise the asymmetric unit of the title compound, [Sn(C(6)H(5))(2)(C(17)H(14)N(2)O(3))]·CH(3)OH. The Sn atom in each is five-coordinated by a tridentate ligand and the ipso-C atoms of the Sn-bound benzene substituents. The resulting C(2)N(2)O donor set defines a coordination geometry that is inter­mediate between trigonal-bipyramidal (TP) and square-pyramidal (SP), with one mol­ecule slightly tending towards TP and the other slightly towards SP. The mol­ecules differ in terms of the relative orientations of the terminal benzene rings [dihedral angles = 45.71 (18) and 53.98 (17)°] and of the Sn-bound benzene substituents [dihedral angles = 59.5 (2) and 45.77 (18)°, respectively]. The most prominent feature of the crystal packing is the formation of four-mol­ecule aggregates via O—H⋯O and O—H⋯N hydrogen bonds, in which the hy­droxy group is connected to a methanol mol­ecule which, in turn, is linked to a non-coordinating N atom. Weak C—H⋯π inter­actions also occur.