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{4-Hydroxy-N′-[(2E,3Z)-4-oxido-4-phenylbut-3-en-2-ylidene]benzohydrazidato}diphenyltin(IV) methanol monosolvate
Two independent diphenyltin molecules and two independent methanol molecules comprise the asymmetric unit of the title compound, [Sn(C(6)H(5))(2)(C(17)H(14)N(2)O(3))]·CH(3)OH. The Sn atom in each is five-coordinated by a tridentate ligand and the ipso-C atoms of the Sn-bound benzene substituents....
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151954/ https://www.ncbi.nlm.nih.gov/pubmed/21836941 http://dx.doi.org/10.1107/S1600536811023415 |
Sumario: | Two independent diphenyltin molecules and two independent methanol molecules comprise the asymmetric unit of the title compound, [Sn(C(6)H(5))(2)(C(17)H(14)N(2)O(3))]·CH(3)OH. The Sn atom in each is five-coordinated by a tridentate ligand and the ipso-C atoms of the Sn-bound benzene substituents. The resulting C(2)N(2)O donor set defines a coordination geometry that is intermediate between trigonal-bipyramidal (TP) and square-pyramidal (SP), with one molecule slightly tending towards TP and the other slightly towards SP. The molecules differ in terms of the relative orientations of the terminal benzene rings [dihedral angles = 45.71 (18) and 53.98 (17)°] and of the Sn-bound benzene substituents [dihedral angles = 59.5 (2) and 45.77 (18)°, respectively]. The most prominent feature of the crystal packing is the formation of four-molecule aggregates via O—H⋯O and O—H⋯N hydrogen bonds, in which the hydroxy group is connected to a methanol molecule which, in turn, is linked to a non-coordinating N atom. Weak C—H⋯π interactions also occur. |
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