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{4-Hy­droxy-N′-[(2E,3Z)-4-oxido-4-phenyl­but-3-en-2-yl­idene]benzo­hydra­zidato}diphenyl­tin(IV) methanol monosolvate

Two independent diphenyl­tin mol­ecules and two independent methanol mol­ecules comprise the asymmetric unit of the title compound, [Sn(C(6)H(5))(2)(C(17)H(14)N(2)O(3))]·CH(3)OH. The Sn atom in each is five-coordinated by a tridentate ligand and the ipso-C atoms of the Sn-bound benzene substituents....

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Autores principales: Affan, Md. Abu, Sam, Norrihan B., Ahmad, Fasihuddin B., White, Fraser, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151954/
https://www.ncbi.nlm.nih.gov/pubmed/21836941
http://dx.doi.org/10.1107/S1600536811023415
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author Affan, Md. Abu
Sam, Norrihan B.
Ahmad, Fasihuddin B.
White, Fraser
Tiekink, Edward R. T.
author_facet Affan, Md. Abu
Sam, Norrihan B.
Ahmad, Fasihuddin B.
White, Fraser
Tiekink, Edward R. T.
author_sort Affan, Md. Abu
collection PubMed
description Two independent diphenyl­tin mol­ecules and two independent methanol mol­ecules comprise the asymmetric unit of the title compound, [Sn(C(6)H(5))(2)(C(17)H(14)N(2)O(3))]·CH(3)OH. The Sn atom in each is five-coordinated by a tridentate ligand and the ipso-C atoms of the Sn-bound benzene substituents. The resulting C(2)N(2)O donor set defines a coordination geometry that is inter­mediate between trigonal-bipyramidal (TP) and square-pyramidal (SP), with one mol­ecule slightly tending towards TP and the other slightly towards SP. The mol­ecules differ in terms of the relative orientations of the terminal benzene rings [dihedral angles = 45.71 (18) and 53.98 (17)°] and of the Sn-bound benzene substituents [dihedral angles = 59.5 (2) and 45.77 (18)°, respectively]. The most prominent feature of the crystal packing is the formation of four-mol­ecule aggregates via O—H⋯O and O—H⋯N hydrogen bonds, in which the hy­droxy group is connected to a methanol mol­ecule which, in turn, is linked to a non-coordinating N atom. Weak C—H⋯π inter­actions also occur.
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spelling pubmed-31519542011-08-11 {4-Hy­droxy-N′-[(2E,3Z)-4-oxido-4-phenyl­but-3-en-2-yl­idene]benzo­hydra­zidato}diphenyl­tin(IV) methanol monosolvate Affan, Md. Abu Sam, Norrihan B. Ahmad, Fasihuddin B. White, Fraser Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers Two independent diphenyl­tin mol­ecules and two independent methanol mol­ecules comprise the asymmetric unit of the title compound, [Sn(C(6)H(5))(2)(C(17)H(14)N(2)O(3))]·CH(3)OH. The Sn atom in each is five-coordinated by a tridentate ligand and the ipso-C atoms of the Sn-bound benzene substituents. The resulting C(2)N(2)O donor set defines a coordination geometry that is inter­mediate between trigonal-bipyramidal (TP) and square-pyramidal (SP), with one mol­ecule slightly tending towards TP and the other slightly towards SP. The mol­ecules differ in terms of the relative orientations of the terminal benzene rings [dihedral angles = 45.71 (18) and 53.98 (17)°] and of the Sn-bound benzene substituents [dihedral angles = 59.5 (2) and 45.77 (18)°, respectively]. The most prominent feature of the crystal packing is the formation of four-mol­ecule aggregates via O—H⋯O and O—H⋯N hydrogen bonds, in which the hy­droxy group is connected to a methanol mol­ecule which, in turn, is linked to a non-coordinating N atom. Weak C—H⋯π inter­actions also occur. International Union of Crystallography 2011-06-22 /pmc/articles/PMC3151954/ /pubmed/21836941 http://dx.doi.org/10.1107/S1600536811023415 Text en © Affan et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Affan, Md. Abu
Sam, Norrihan B.
Ahmad, Fasihuddin B.
White, Fraser
Tiekink, Edward R. T.
{4-Hy­droxy-N′-[(2E,3Z)-4-oxido-4-phenyl­but-3-en-2-yl­idene]benzo­hydra­zidato}diphenyl­tin(IV) methanol monosolvate
title {4-Hy­droxy-N′-[(2E,3Z)-4-oxido-4-phenyl­but-3-en-2-yl­idene]benzo­hydra­zidato}diphenyl­tin(IV) methanol monosolvate
title_full {4-Hy­droxy-N′-[(2E,3Z)-4-oxido-4-phenyl­but-3-en-2-yl­idene]benzo­hydra­zidato}diphenyl­tin(IV) methanol monosolvate
title_fullStr {4-Hy­droxy-N′-[(2E,3Z)-4-oxido-4-phenyl­but-3-en-2-yl­idene]benzo­hydra­zidato}diphenyl­tin(IV) methanol monosolvate
title_full_unstemmed {4-Hy­droxy-N′-[(2E,3Z)-4-oxido-4-phenyl­but-3-en-2-yl­idene]benzo­hydra­zidato}diphenyl­tin(IV) methanol monosolvate
title_short {4-Hy­droxy-N′-[(2E,3Z)-4-oxido-4-phenyl­but-3-en-2-yl­idene]benzo­hydra­zidato}diphenyl­tin(IV) methanol monosolvate
title_sort {4-hy­droxy-n′-[(2e,3z)-4-oxido-4-phenyl­but-3-en-2-yl­idene]benzo­hydra­zidato}diphenyl­tin(iv) methanol monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151954/
https://www.ncbi.nlm.nih.gov/pubmed/21836941
http://dx.doi.org/10.1107/S1600536811023415
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