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{4-Hydroxy-N′-[(2E,3Z)-4-oxido-4-phenylbut-3-en-2-ylidene]benzohydrazidato}diphenyltin(IV) methanol monosolvate
Two independent diphenyltin molecules and two independent methanol molecules comprise the asymmetric unit of the title compound, [Sn(C(6)H(5))(2)(C(17)H(14)N(2)O(3))]·CH(3)OH. The Sn atom in each is five-coordinated by a tridentate ligand and the ipso-C atoms of the Sn-bound benzene substituents....
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151954/ https://www.ncbi.nlm.nih.gov/pubmed/21836941 http://dx.doi.org/10.1107/S1600536811023415 |
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author | Affan, Md. Abu Sam, Norrihan B. Ahmad, Fasihuddin B. White, Fraser Tiekink, Edward R. T. |
author_facet | Affan, Md. Abu Sam, Norrihan B. Ahmad, Fasihuddin B. White, Fraser Tiekink, Edward R. T. |
author_sort | Affan, Md. Abu |
collection | PubMed |
description | Two independent diphenyltin molecules and two independent methanol molecules comprise the asymmetric unit of the title compound, [Sn(C(6)H(5))(2)(C(17)H(14)N(2)O(3))]·CH(3)OH. The Sn atom in each is five-coordinated by a tridentate ligand and the ipso-C atoms of the Sn-bound benzene substituents. The resulting C(2)N(2)O donor set defines a coordination geometry that is intermediate between trigonal-bipyramidal (TP) and square-pyramidal (SP), with one molecule slightly tending towards TP and the other slightly towards SP. The molecules differ in terms of the relative orientations of the terminal benzene rings [dihedral angles = 45.71 (18) and 53.98 (17)°] and of the Sn-bound benzene substituents [dihedral angles = 59.5 (2) and 45.77 (18)°, respectively]. The most prominent feature of the crystal packing is the formation of four-molecule aggregates via O—H⋯O and O—H⋯N hydrogen bonds, in which the hydroxy group is connected to a methanol molecule which, in turn, is linked to a non-coordinating N atom. Weak C—H⋯π interactions also occur. |
format | Online Article Text |
id | pubmed-3151954 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31519542011-08-11 {4-Hydroxy-N′-[(2E,3Z)-4-oxido-4-phenylbut-3-en-2-ylidene]benzohydrazidato}diphenyltin(IV) methanol monosolvate Affan, Md. Abu Sam, Norrihan B. Ahmad, Fasihuddin B. White, Fraser Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers Two independent diphenyltin molecules and two independent methanol molecules comprise the asymmetric unit of the title compound, [Sn(C(6)H(5))(2)(C(17)H(14)N(2)O(3))]·CH(3)OH. The Sn atom in each is five-coordinated by a tridentate ligand and the ipso-C atoms of the Sn-bound benzene substituents. The resulting C(2)N(2)O donor set defines a coordination geometry that is intermediate between trigonal-bipyramidal (TP) and square-pyramidal (SP), with one molecule slightly tending towards TP and the other slightly towards SP. The molecules differ in terms of the relative orientations of the terminal benzene rings [dihedral angles = 45.71 (18) and 53.98 (17)°] and of the Sn-bound benzene substituents [dihedral angles = 59.5 (2) and 45.77 (18)°, respectively]. The most prominent feature of the crystal packing is the formation of four-molecule aggregates via O—H⋯O and O—H⋯N hydrogen bonds, in which the hydroxy group is connected to a methanol molecule which, in turn, is linked to a non-coordinating N atom. Weak C—H⋯π interactions also occur. International Union of Crystallography 2011-06-22 /pmc/articles/PMC3151954/ /pubmed/21836941 http://dx.doi.org/10.1107/S1600536811023415 Text en © Affan et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Affan, Md. Abu Sam, Norrihan B. Ahmad, Fasihuddin B. White, Fraser Tiekink, Edward R. T. {4-Hydroxy-N′-[(2E,3Z)-4-oxido-4-phenylbut-3-en-2-ylidene]benzohydrazidato}diphenyltin(IV) methanol monosolvate |
title | {4-Hydroxy-N′-[(2E,3Z)-4-oxido-4-phenylbut-3-en-2-ylidene]benzohydrazidato}diphenyltin(IV) methanol monosolvate |
title_full | {4-Hydroxy-N′-[(2E,3Z)-4-oxido-4-phenylbut-3-en-2-ylidene]benzohydrazidato}diphenyltin(IV) methanol monosolvate |
title_fullStr | {4-Hydroxy-N′-[(2E,3Z)-4-oxido-4-phenylbut-3-en-2-ylidene]benzohydrazidato}diphenyltin(IV) methanol monosolvate |
title_full_unstemmed | {4-Hydroxy-N′-[(2E,3Z)-4-oxido-4-phenylbut-3-en-2-ylidene]benzohydrazidato}diphenyltin(IV) methanol monosolvate |
title_short | {4-Hydroxy-N′-[(2E,3Z)-4-oxido-4-phenylbut-3-en-2-ylidene]benzohydrazidato}diphenyltin(IV) methanol monosolvate |
title_sort | {4-hydroxy-n′-[(2e,3z)-4-oxido-4-phenylbut-3-en-2-ylidene]benzohydrazidato}diphenyltin(iv) methanol monosolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151954/ https://www.ncbi.nlm.nih.gov/pubmed/21836941 http://dx.doi.org/10.1107/S1600536811023415 |
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