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Ammonium O,O′-diethyl dithiophosphate
In the title compound, NH(4) (+)·(C(2)H(5)O)(2)PS(2) (−), the ammonium cation is connected by four charge-assisted N—H⋯S hydrogen bonds to four tetrahedral O,O′-diethyl dithiophosphate anions, forming layers parallel to (100). The polar and non-polar constituents of the layers are stacked alternat...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151957/ https://www.ncbi.nlm.nih.gov/pubmed/21837134 http://dx.doi.org/10.1107/S1600536811022811 |
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author | Okuniewski, Andrzej Becker, Barbara |
author_facet | Okuniewski, Andrzej Becker, Barbara |
author_sort | Okuniewski, Andrzej |
collection | PubMed |
description | In the title compound, NH(4) (+)·(C(2)H(5)O)(2)PS(2) (−), the ammonium cation is connected by four charge-assisted N—H⋯S hydrogen bonds to four tetrahedral O,O′-diethyl dithiophosphate anions, forming layers parallel to (100). The polar and non-polar constituents of the layers are stacked alternately along [100]. Interlacing of the external ethyl groups through van der Waals interactions combines these layers into a three-dimensional structure. |
format | Online Article Text |
id | pubmed-3151957 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31519572011-08-11 Ammonium O,O′-diethyl dithiophosphate Okuniewski, Andrzej Becker, Barbara Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, NH(4) (+)·(C(2)H(5)O)(2)PS(2) (−), the ammonium cation is connected by four charge-assisted N—H⋯S hydrogen bonds to four tetrahedral O,O′-diethyl dithiophosphate anions, forming layers parallel to (100). The polar and non-polar constituents of the layers are stacked alternately along [100]. Interlacing of the external ethyl groups through van der Waals interactions combines these layers into a three-dimensional structure. International Union of Crystallography 2011-06-18 /pmc/articles/PMC3151957/ /pubmed/21837134 http://dx.doi.org/10.1107/S1600536811022811 Text en © Okuniewski and Becker 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Okuniewski, Andrzej Becker, Barbara Ammonium O,O′-diethyl dithiophosphate |
title | Ammonium O,O′-diethyl dithiophosphate |
title_full | Ammonium O,O′-diethyl dithiophosphate |
title_fullStr | Ammonium O,O′-diethyl dithiophosphate |
title_full_unstemmed | Ammonium O,O′-diethyl dithiophosphate |
title_short | Ammonium O,O′-diethyl dithiophosphate |
title_sort | ammonium o,o′-diethyl dithiophosphate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151957/ https://www.ncbi.nlm.nih.gov/pubmed/21837134 http://dx.doi.org/10.1107/S1600536811022811 |
work_keys_str_mv | AT okuniewskiandrzej ammoniumoodiethyldithiophosphate AT beckerbarbara ammoniumoodiethyldithiophosphate |