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Ammonium O,O′-diethyl dithio­phosphate

In the title compound, NH(4) (+)·(C(2)H(5)O)(2)PS(2) (−), the ammonium cation is connected by four charge-assisted N—H⋯S hydrogen bonds to four tetra­hedral O,O′-diethyl dithio­phosphate anions, forming layers parallel to (100). The polar and non-polar constituents of the layers are stacked alternat...

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Detalles Bibliográficos
Autores principales: Okuniewski, Andrzej, Becker, Barbara
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151957/
https://www.ncbi.nlm.nih.gov/pubmed/21837134
http://dx.doi.org/10.1107/S1600536811022811
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author Okuniewski, Andrzej
Becker, Barbara
author_facet Okuniewski, Andrzej
Becker, Barbara
author_sort Okuniewski, Andrzej
collection PubMed
description In the title compound, NH(4) (+)·(C(2)H(5)O)(2)PS(2) (−), the ammonium cation is connected by four charge-assisted N—H⋯S hydrogen bonds to four tetra­hedral O,O′-diethyl dithio­phosphate anions, forming layers parallel to (100). The polar and non-polar constituents of the layers are stacked alternately along [100]. Inter­lacing of the external ethyl groups through van der Waals inter­actions combines these layers into a three-dimensional structure.
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spelling pubmed-31519572011-08-11 Ammonium O,O′-diethyl dithio­phosphate Okuniewski, Andrzej Becker, Barbara Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, NH(4) (+)·(C(2)H(5)O)(2)PS(2) (−), the ammonium cation is connected by four charge-assisted N—H⋯S hydrogen bonds to four tetra­hedral O,O′-diethyl dithio­phosphate anions, forming layers parallel to (100). The polar and non-polar constituents of the layers are stacked alternately along [100]. Inter­lacing of the external ethyl groups through van der Waals inter­actions combines these layers into a three-dimensional structure. International Union of Crystallography 2011-06-18 /pmc/articles/PMC3151957/ /pubmed/21837134 http://dx.doi.org/10.1107/S1600536811022811 Text en © Okuniewski and Becker 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Okuniewski, Andrzej
Becker, Barbara
Ammonium O,O′-diethyl dithio­phosphate
title Ammonium O,O′-diethyl dithio­phosphate
title_full Ammonium O,O′-diethyl dithio­phosphate
title_fullStr Ammonium O,O′-diethyl dithio­phosphate
title_full_unstemmed Ammonium O,O′-diethyl dithio­phosphate
title_short Ammonium O,O′-diethyl dithio­phosphate
title_sort ammonium o,o′-diethyl dithio­phosphate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151957/
https://www.ncbi.nlm.nih.gov/pubmed/21837134
http://dx.doi.org/10.1107/S1600536811022811
work_keys_str_mv AT okuniewskiandrzej ammoniumoodiethyldithiophosphate
AT beckerbarbara ammoniumoodiethyldithiophosphate