Poly[(μ(5)-2,6-dimethyl­pyridine-3,5-dicarboxyl­ato)zinc]

In the polymeric title complex, [Zn(C(9)H(7)NO(4))](n), the Zn(II) cation is located on a twofold rotation axis and is coordinated by five 2,6-dimethyl­pyridine-3,5-dicarboxyl­ate (mpdc) anions in a distorted ZnNO(4) trigonal–bipyramidal geometry. The mpdc anion is also located on the twofold rotati...

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Detalles Bibliográficos
Autores principales: Zhang, Ming-Xing, Chen, Xin, Zhu, Yi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151958/
https://www.ncbi.nlm.nih.gov/pubmed/21836951
http://dx.doi.org/10.1107/S1600536811024172
Descripción
Sumario:In the polymeric title complex, [Zn(C(9)H(7)NO(4))](n), the Zn(II) cation is located on a twofold rotation axis and is coordinated by five 2,6-dimethyl­pyridine-3,5-dicarboxyl­ate (mpdc) anions in a distorted ZnNO(4) trigonal–bipyramidal geometry. The mpdc anion is also located on the twofold rotation axis and bridges five Zn(II) cations, forming the three-dimensional polymeric complex. Weak C—H⋯π inter­actions are present in the crystal structure.

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