Poly[(μ(5)-2,6-dimethyl­pyridine-3,5-dicarboxyl­ato)zinc]

In the polymeric title complex, [Zn(C(9)H(7)NO(4))](n), the Zn(II) cation is located on a twofold rotation axis and is coordinated by five 2,6-dimethyl­pyridine-3,5-dicarboxyl­ate (mpdc) anions in a distorted ZnNO(4) trigonal–bipyramidal geometry. The mpdc anion is also located on the twofold rotati...

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Detalles Bibliográficos
Autores principales: Zhang, Ming-Xing, Chen, Xin, Zhu, Yi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151958/
https://www.ncbi.nlm.nih.gov/pubmed/21836951
http://dx.doi.org/10.1107/S1600536811024172
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author Zhang, Ming-Xing
Chen, Xin
Zhu, Yi
author_facet Zhang, Ming-Xing
Chen, Xin
Zhu, Yi
author_sort Zhang, Ming-Xing
collection PubMed
description In the polymeric title complex, [Zn(C(9)H(7)NO(4))](n), the Zn(II) cation is located on a twofold rotation axis and is coordinated by five 2,6-dimethyl­pyridine-3,5-dicarboxyl­ate (mpdc) anions in a distorted ZnNO(4) trigonal–bipyramidal geometry. The mpdc anion is also located on the twofold rotation axis and bridges five Zn(II) cations, forming the three-dimensional polymeric complex. Weak C—H⋯π inter­actions are present in the crystal structure.
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spelling pubmed-31519582011-08-11 Poly[(μ(5)-2,6-dimethyl­pyridine-3,5-dicarboxyl­ato)zinc] Zhang, Ming-Xing Chen, Xin Zhu, Yi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the polymeric title complex, [Zn(C(9)H(7)NO(4))](n), the Zn(II) cation is located on a twofold rotation axis and is coordinated by five 2,6-dimethyl­pyridine-3,5-dicarboxyl­ate (mpdc) anions in a distorted ZnNO(4) trigonal–bipyramidal geometry. The mpdc anion is also located on the twofold rotation axis and bridges five Zn(II) cations, forming the three-dimensional polymeric complex. Weak C—H⋯π inter­actions are present in the crystal structure. International Union of Crystallography 2011-06-25 /pmc/articles/PMC3151958/ /pubmed/21836951 http://dx.doi.org/10.1107/S1600536811024172 Text en © Zhang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Ming-Xing
Chen, Xin
Zhu, Yi
Poly[(μ(5)-2,6-dimethyl­pyridine-3,5-dicarboxyl­ato)zinc]
title Poly[(μ(5)-2,6-dimethyl­pyridine-3,5-dicarboxyl­ato)zinc]
title_full Poly[(μ(5)-2,6-dimethyl­pyridine-3,5-dicarboxyl­ato)zinc]
title_fullStr Poly[(μ(5)-2,6-dimethyl­pyridine-3,5-dicarboxyl­ato)zinc]
title_full_unstemmed Poly[(μ(5)-2,6-dimethyl­pyridine-3,5-dicarboxyl­ato)zinc]
title_short Poly[(μ(5)-2,6-dimethyl­pyridine-3,5-dicarboxyl­ato)zinc]
title_sort poly[(μ(5)-2,6-dimethyl­pyridine-3,5-dicarboxyl­ato)zinc]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151958/
https://www.ncbi.nlm.nih.gov/pubmed/21836951
http://dx.doi.org/10.1107/S1600536811024172
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