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1,3-Bis[(−)-(S)-(1-phenylethyl)iminomethyl]benzene
The title compound, C(24)H(24)N(2), is an enantiomerically pure bis-aldimine, which displays twofold crystallographic symmetry, with two C atoms of the central benzene ring lying on the symmetry axis. The imine group is slightly twisted from the benzene core, with a dihedral angle of 12.72 (16)° be...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151960/ https://www.ncbi.nlm.nih.gov/pubmed/21837052 http://dx.doi.org/10.1107/S1600536811021556 |
Sumario: | The title compound, C(24)H(24)N(2), is an enantiomerically pure bis-aldimine, which displays twofold crystallographic symmetry, with two C atoms of the central benzene ring lying on the symmetry axis. The imine group is slightly twisted from the benzene core, with a dihedral angle of 12.72 (16)° between the benzene ring and the C=N—C(*) plane. The terminal phenyl rings make an angle of 66.44 (4)° and are oriented in opposite directions with respect to the benzene ring. In the crystal, molecules interact weakly through a C—H⋯π interaction involving the phenyl rings, and form chains along the 2(1) screw-axis in the [100] direction. |
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