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1,3-Bis[(−)-(S)-(1-phenyl­eth­yl)imino­meth­yl]benzene

The title compound, C(24)H(24)N(2), is an enanti­omerically pure bis-aldimine, which displays twofold crystallographic symmetry, with two C atoms of the central benzene ring lying on the symmetry axis. The imine group is slightly twisted from the benzene core, with a dihedral angle of 12.72 (16)° be...

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Detalles Bibliográficos
Autores principales: García, Tania, Bernès, Sylvain, Flores-Alamo, Marcos, Hernández, Guadalupe, Gutiérrez, René
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151960/
https://www.ncbi.nlm.nih.gov/pubmed/21837052
http://dx.doi.org/10.1107/S1600536811021556
Descripción
Sumario:The title compound, C(24)H(24)N(2), is an enanti­omerically pure bis-aldimine, which displays twofold crystallographic symmetry, with two C atoms of the central benzene ring lying on the symmetry axis. The imine group is slightly twisted from the benzene core, with a dihedral angle of 12.72 (16)° between the benzene ring and the C=N—C(*) plane. The terminal phenyl rings make an angle of 66.44 (4)° and are oriented in opposite directions with respect to the benzene ring. In the crystal, mol­ecules inter­act weakly through a C—H⋯π inter­action involving the phenyl rings, and form chains along the 2(1) screw-axis in the [100] direction.