1,3-Bis[(−)-(S)-(1-phenyl­eth­yl)imino­meth­yl]benzene

The title compound, C(24)H(24)N(2), is an enanti­omerically pure bis-aldimine, which displays twofold crystallographic symmetry, with two C atoms of the central benzene ring lying on the symmetry axis. The imine group is slightly twisted from the benzene core, with a dihedral angle of 12.72 (16)° be...

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Autores principales: García, Tania, Bernès, Sylvain, Flores-Alamo, Marcos, Hernández, Guadalupe, Gutiérrez, René
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151960/
https://www.ncbi.nlm.nih.gov/pubmed/21837052
http://dx.doi.org/10.1107/S1600536811021556
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author García, Tania
Bernès, Sylvain
Flores-Alamo, Marcos
Hernández, Guadalupe
Gutiérrez, René
author_facet García, Tania
Bernès, Sylvain
Flores-Alamo, Marcos
Hernández, Guadalupe
Gutiérrez, René
author_sort García, Tania
collection PubMed
description The title compound, C(24)H(24)N(2), is an enanti­omerically pure bis-aldimine, which displays twofold crystallographic symmetry, with two C atoms of the central benzene ring lying on the symmetry axis. The imine group is slightly twisted from the benzene core, with a dihedral angle of 12.72 (16)° between the benzene ring and the C=N—C(*) plane. The terminal phenyl rings make an angle of 66.44 (4)° and are oriented in opposite directions with respect to the benzene ring. In the crystal, mol­ecules inter­act weakly through a C—H⋯π inter­action involving the phenyl rings, and form chains along the 2(1) screw-axis in the [100] direction.
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spelling pubmed-31519602011-08-11 1,3-Bis[(−)-(S)-(1-phenyl­eth­yl)imino­meth­yl]benzene García, Tania Bernès, Sylvain Flores-Alamo, Marcos Hernández, Guadalupe Gutiérrez, René Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(24)H(24)N(2), is an enanti­omerically pure bis-aldimine, which displays twofold crystallographic symmetry, with two C atoms of the central benzene ring lying on the symmetry axis. The imine group is slightly twisted from the benzene core, with a dihedral angle of 12.72 (16)° between the benzene ring and the C=N—C(*) plane. The terminal phenyl rings make an angle of 66.44 (4)° and are oriented in opposite directions with respect to the benzene ring. In the crystal, mol­ecules inter­act weakly through a C—H⋯π inter­action involving the phenyl rings, and form chains along the 2(1) screw-axis in the [100] direction. International Union of Crystallography 2011-06-11 /pmc/articles/PMC3151960/ /pubmed/21837052 http://dx.doi.org/10.1107/S1600536811021556 Text en © García et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
García, Tania
Bernès, Sylvain
Flores-Alamo, Marcos
Hernández, Guadalupe
Gutiérrez, René
1,3-Bis[(−)-(S)-(1-phenyl­eth­yl)imino­meth­yl]benzene
title 1,3-Bis[(−)-(S)-(1-phenyl­eth­yl)imino­meth­yl]benzene
title_full 1,3-Bis[(−)-(S)-(1-phenyl­eth­yl)imino­meth­yl]benzene
title_fullStr 1,3-Bis[(−)-(S)-(1-phenyl­eth­yl)imino­meth­yl]benzene
title_full_unstemmed 1,3-Bis[(−)-(S)-(1-phenyl­eth­yl)imino­meth­yl]benzene
title_short 1,3-Bis[(−)-(S)-(1-phenyl­eth­yl)imino­meth­yl]benzene
title_sort 1,3-bis[(−)-(s)-(1-phenyl­eth­yl)imino­meth­yl]benzene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151960/
https://www.ncbi.nlm.nih.gov/pubmed/21837052
http://dx.doi.org/10.1107/S1600536811021556
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