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{4,4′-Dichloro-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanyl­ylidene)]diphenolato-κ(4) O,N,N′,O′}nickel(II)

In the title compound, [Ni(C(19)H(18)Cl(2)N(2)O(2))], the Ni(II) atom shows a slightly distorted square-planar geometry. The dihedral angle between the mean planes of the coordination rings is 9.15 (12)° while the dihedral angle between the mean planes of the two aromatic rings is 3.48 (16)°. In the...

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Detalles Bibliográficos
Autores principales: Kargar, Hadi, Kia, Reza, Pahlavani, Elham, Tahir, Muhammad Nawaz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151962/
https://www.ncbi.nlm.nih.gov/pubmed/21836924
http://dx.doi.org/10.1107/S1600536811022732
Descripción
Sumario:In the title compound, [Ni(C(19)H(18)Cl(2)N(2)O(2))], the Ni(II) atom shows a slightly distorted square-planar geometry. The dihedral angle between the mean planes of the coordination rings is 9.15 (12)° while the dihedral angle between the mean planes of the two aromatic rings is 3.48 (16)°. In the crystal, pairs of inter­molecular C—H⋯O hydrogen bonds link neighboring mol­ecules into a chain along the a axis. The crystal structure is further stabilized by π–π inter­actions [centroid–centroid distance = 3.883 (2) Å].