Cargando…
{4,4′-Dichloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato-κ(4) O,N,N′,O′}nickel(II)
In the title compound, [Ni(C(19)H(18)Cl(2)N(2)O(2))], the Ni(II) atom shows a slightly distorted square-planar geometry. The dihedral angle between the mean planes of the coordination rings is 9.15 (12)° while the dihedral angle between the mean planes of the two aromatic rings is 3.48 (16)°. In the...
| Autores principales: | , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151962/ https://www.ncbi.nlm.nih.gov/pubmed/21836924 http://dx.doi.org/10.1107/S1600536811022732 |
| _version_ | 1782209696132759552 |
|---|---|
| author | Kargar, Hadi Kia, Reza Pahlavani, Elham Tahir, Muhammad Nawaz |
| author_facet | Kargar, Hadi Kia, Reza Pahlavani, Elham Tahir, Muhammad Nawaz |
| author_sort | Kargar, Hadi |
| collection | PubMed |
| description | In the title compound, [Ni(C(19)H(18)Cl(2)N(2)O(2))], the Ni(II) atom shows a slightly distorted square-planar geometry. The dihedral angle between the mean planes of the coordination rings is 9.15 (12)° while the dihedral angle between the mean planes of the two aromatic rings is 3.48 (16)°. In the crystal, pairs of intermolecular C—H⋯O hydrogen bonds link neighboring molecules into a chain along the a axis. The crystal structure is further stabilized by π–π interactions [centroid–centroid distance = 3.883 (2) Å]. |
| format | Online Article Text |
| id | pubmed-3151962 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-31519622011-08-11 {4,4′-Dichloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato-κ(4) O,N,N′,O′}nickel(II) Kargar, Hadi Kia, Reza Pahlavani, Elham Tahir, Muhammad Nawaz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(19)H(18)Cl(2)N(2)O(2))], the Ni(II) atom shows a slightly distorted square-planar geometry. The dihedral angle between the mean planes of the coordination rings is 9.15 (12)° while the dihedral angle between the mean planes of the two aromatic rings is 3.48 (16)°. In the crystal, pairs of intermolecular C—H⋯O hydrogen bonds link neighboring molecules into a chain along the a axis. The crystal structure is further stabilized by π–π interactions [centroid–centroid distance = 3.883 (2) Å]. International Union of Crystallography 2011-06-18 /pmc/articles/PMC3151962/ /pubmed/21836924 http://dx.doi.org/10.1107/S1600536811022732 Text en © Kargar et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Kargar, Hadi Kia, Reza Pahlavani, Elham Tahir, Muhammad Nawaz {4,4′-Dichloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato-κ(4) O,N,N′,O′}nickel(II) |
| title | {4,4′-Dichloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato-κ(4)
O,N,N′,O′}nickel(II) |
| title_full | {4,4′-Dichloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato-κ(4)
O,N,N′,O′}nickel(II) |
| title_fullStr | {4,4′-Dichloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato-κ(4)
O,N,N′,O′}nickel(II) |
| title_full_unstemmed | {4,4′-Dichloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato-κ(4)
O,N,N′,O′}nickel(II) |
| title_short | {4,4′-Dichloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato-κ(4)
O,N,N′,O′}nickel(II) |
| title_sort | {4,4′-dichloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato-κ(4)
o,n,n′,o′}nickel(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151962/ https://www.ncbi.nlm.nih.gov/pubmed/21836924 http://dx.doi.org/10.1107/S1600536811022732 |
| work_keys_str_mv | AT kargarhadi 44dichloro2222dimethylpropane13diylbisnitrilomethanylylidenediphenolatok4onnonickelii AT kiareza 44dichloro2222dimethylpropane13diylbisnitrilomethanylylidenediphenolatok4onnonickelii AT pahlavanielham 44dichloro2222dimethylpropane13diylbisnitrilomethanylylidenediphenolatok4onnonickelii AT tahirmuhammadnawaz 44dichloro2222dimethylpropane13diylbisnitrilomethanylylidenediphenolatok4onnonickelii |