Tetra­methyl­ammonium hemi(terephthalate) dihydrate

In the title compound, (CH(3))(4)N(+)·0.5C(8)H(4)O(4) (2−)·2H(2)O, the complete terephthalate dianion is completed by twofold symmetry and has a dihedral angle of 23.5 (2)° between the carboxyl­ate group and its parent ring. Two independent water mol­ecules serve as both donors and acceptor in the c...

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Detalles Bibliográficos
Autores principales: Yang, Yunxia, Shi, Laipeng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151964/
https://www.ncbi.nlm.nih.gov/pubmed/21837146
http://dx.doi.org/10.1107/S1600536811023312
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author Yang, Yunxia
Shi, Laipeng
author_facet Yang, Yunxia
Shi, Laipeng
author_sort Yang, Yunxia
collection PubMed
description In the title compound, (CH(3))(4)N(+)·0.5C(8)H(4)O(4) (2−)·2H(2)O, the complete terephthalate dianion is completed by twofold symmetry and has a dihedral angle of 23.5 (2)° between the carboxyl­ate group and its parent ring. Two independent water mol­ecules serve as both donors and acceptor in the construction of undulating hydrogen-bonded host layers with various O—H⋯O contacts ocurring between the anion and two water mol­ecules. At the same time, the tetra­methyl­ammonium cations, as the sphere-like guest species, are arranged in two rows between neighboring host layers, with an approximate inter­layer distance of 7.36 Å, forming a sandwich-like crystal structure.
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spelling pubmed-31519642011-08-11 Tetra­methyl­ammonium hemi(terephthalate) dihydrate Yang, Yunxia Shi, Laipeng Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, (CH(3))(4)N(+)·0.5C(8)H(4)O(4) (2−)·2H(2)O, the complete terephthalate dianion is completed by twofold symmetry and has a dihedral angle of 23.5 (2)° between the carboxyl­ate group and its parent ring. Two independent water mol­ecules serve as both donors and acceptor in the construction of undulating hydrogen-bonded host layers with various O—H⋯O contacts ocurring between the anion and two water mol­ecules. At the same time, the tetra­methyl­ammonium cations, as the sphere-like guest species, are arranged in two rows between neighboring host layers, with an approximate inter­layer distance of 7.36 Å, forming a sandwich-like crystal structure. International Union of Crystallography 2011-06-22 /pmc/articles/PMC3151964/ /pubmed/21837146 http://dx.doi.org/10.1107/S1600536811023312 Text en © Yang and Shi 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Yang, Yunxia
Shi, Laipeng
Tetra­methyl­ammonium hemi(terephthalate) dihydrate
title Tetra­methyl­ammonium hemi(terephthalate) dihydrate
title_full Tetra­methyl­ammonium hemi(terephthalate) dihydrate
title_fullStr Tetra­methyl­ammonium hemi(terephthalate) dihydrate
title_full_unstemmed Tetra­methyl­ammonium hemi(terephthalate) dihydrate
title_short Tetra­methyl­ammonium hemi(terephthalate) dihydrate
title_sort tetra­methyl­ammonium hemi(terephthalate) dihydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151964/
https://www.ncbi.nlm.nih.gov/pubmed/21837146
http://dx.doi.org/10.1107/S1600536811023312
work_keys_str_mv AT yangyunxia tetramethylammoniumhemiterephthalatedihydrate
AT shilaipeng tetramethylammoniumhemiterephthalatedihydrate

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