3-{[3-(4-Meth­oxy­phen­yl)-4,5-dihydro-1,2-oxazol-5-yl]meth­yl}-1,5-dimethyl-1H-1,5-benzodiazepine-2,4(3H,5H)-dione

The mol­ecule of the title compound, C(22)H(23)N(3)O(4), features a benzodiazepine fused-ring system whose seven-membered ring adopts a boat-shaped conformation (with the C atoms of the fused-ring as the stern and the methine C atom as the prow). The methyl­ene C atom connected to the methine C atom...

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Autores principales: Dardouri, Rachida, Rodi, Yousef Kandri, Saffon, Natalie, Essassi, El Mokhtar, Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151967/
https://www.ncbi.nlm.nih.gov/pubmed/21837118
http://dx.doi.org/10.1107/S1600536811022872
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author Dardouri, Rachida
Rodi, Yousef Kandri
Saffon, Natalie
Essassi, El Mokhtar
Ng, Seik Weng
author_facet Dardouri, Rachida
Rodi, Yousef Kandri
Saffon, Natalie
Essassi, El Mokhtar
Ng, Seik Weng
author_sort Dardouri, Rachida
collection PubMed
description The mol­ecule of the title compound, C(22)H(23)N(3)O(4), features a benzodiazepine fused-ring system whose seven-membered ring adopts a boat-shaped conformation (with the C atoms of the fused-ring as the stern and the methine C atom as the prow). The methyl­ene C atom connected to the methine C atom occupies an equatorial position. The methyl­ene C atom is connected to the five-membered oxazole ring, both of which are disordered over two positions in a 0.634 (4):0.366 (4) ratio. Weak inter­molecular C—H⋯O hydrogen bonding is present in the crystal structure.
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spelling pubmed-31519672011-08-11 3-{[3-(4-Meth­oxy­phen­yl)-4,5-dihydro-1,2-oxazol-5-yl]meth­yl}-1,5-dimethyl-1H-1,5-benzodiazepine-2,4(3H,5H)-dione Dardouri, Rachida Rodi, Yousef Kandri Saffon, Natalie Essassi, El Mokhtar Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title compound, C(22)H(23)N(3)O(4), features a benzodiazepine fused-ring system whose seven-membered ring adopts a boat-shaped conformation (with the C atoms of the fused-ring as the stern and the methine C atom as the prow). The methyl­ene C atom connected to the methine C atom occupies an equatorial position. The methyl­ene C atom is connected to the five-membered oxazole ring, both of which are disordered over two positions in a 0.634 (4):0.366 (4) ratio. Weak inter­molecular C—H⋯O hydrogen bonding is present in the crystal structure. International Union of Crystallography 2011-06-18 /pmc/articles/PMC3151967/ /pubmed/21837118 http://dx.doi.org/10.1107/S1600536811022872 Text en © Dardouri et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Dardouri, Rachida
Rodi, Yousef Kandri
Saffon, Natalie
Essassi, El Mokhtar
Ng, Seik Weng
3-{[3-(4-Meth­oxy­phen­yl)-4,5-dihydro-1,2-oxazol-5-yl]meth­yl}-1,5-dimethyl-1H-1,5-benzodiazepine-2,4(3H,5H)-dione
title 3-{[3-(4-Meth­oxy­phen­yl)-4,5-dihydro-1,2-oxazol-5-yl]meth­yl}-1,5-dimethyl-1H-1,5-benzodiazepine-2,4(3H,5H)-dione
title_full 3-{[3-(4-Meth­oxy­phen­yl)-4,5-dihydro-1,2-oxazol-5-yl]meth­yl}-1,5-dimethyl-1H-1,5-benzodiazepine-2,4(3H,5H)-dione
title_fullStr 3-{[3-(4-Meth­oxy­phen­yl)-4,5-dihydro-1,2-oxazol-5-yl]meth­yl}-1,5-dimethyl-1H-1,5-benzodiazepine-2,4(3H,5H)-dione
title_full_unstemmed 3-{[3-(4-Meth­oxy­phen­yl)-4,5-dihydro-1,2-oxazol-5-yl]meth­yl}-1,5-dimethyl-1H-1,5-benzodiazepine-2,4(3H,5H)-dione
title_short 3-{[3-(4-Meth­oxy­phen­yl)-4,5-dihydro-1,2-oxazol-5-yl]meth­yl}-1,5-dimethyl-1H-1,5-benzodiazepine-2,4(3H,5H)-dione
title_sort 3-{[3-(4-meth­oxy­phen­yl)-4,5-dihydro-1,2-oxazol-5-yl]meth­yl}-1,5-dimethyl-1h-1,5-benzodiazepine-2,4(3h,5h)-dione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151967/
https://www.ncbi.nlm.nih.gov/pubmed/21837118
http://dx.doi.org/10.1107/S1600536811022872
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