catena-Poly[1,1′-dimethyl-4,4′-(ethane-1,2-di­yl)dipyridinium [lead(II)-tri-μ-iodido-lead(II)-tri-μ-iodido]]

The title compound, {(C(14)H(18)N(2))[Pb(2)I(6)]}(n), consists of discrete 1,1′-dimethyl-4,4′-(ethane-1,2-di­yl)dipyridinium cations and one-dimensional [Pb(2)I(6)](n) anions. The organic cation has an inversion center at the mid-point of the ethane C—C bond. In the anion, the Pb(II) atom is coordin...

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Detalles Bibliográficos
Autores principales: Xu, Guohai, He, Xiyun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151972/
https://www.ncbi.nlm.nih.gov/pubmed/21836850
http://dx.doi.org/10.1107/S160053681102006X
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author Xu, Guohai
He, Xiyun
author_facet Xu, Guohai
He, Xiyun
author_sort Xu, Guohai
collection PubMed
description The title compound, {(C(14)H(18)N(2))[Pb(2)I(6)]}(n), consists of discrete 1,1′-dimethyl-4,4′-(ethane-1,2-di­yl)dipyridinium cations and one-dimensional [Pb(2)I(6)](n) anions. The organic cation has an inversion center at the mid-point of the ethane C—C bond. In the anion, the Pb(II) atom is coordinated by six I atoms in a distorted octa­hedral geometry. The I atoms bridge the Pb(II) atoms into a polymeric chain running along [001]. These inorganic chains are separated by the isolated organic cations.
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spelling pubmed-31519722011-08-11 catena-Poly[1,1′-dimethyl-4,4′-(ethane-1,2-di­yl)dipyridinium [lead(II)-tri-μ-iodido-lead(II)-tri-μ-iodido]] Xu, Guohai He, Xiyun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, {(C(14)H(18)N(2))[Pb(2)I(6)]}(n), consists of discrete 1,1′-dimethyl-4,4′-(ethane-1,2-di­yl)dipyridinium cations and one-dimensional [Pb(2)I(6)](n) anions. The organic cation has an inversion center at the mid-point of the ethane C—C bond. In the anion, the Pb(II) atom is coordinated by six I atoms in a distorted octa­hedral geometry. The I atoms bridge the Pb(II) atoms into a polymeric chain running along [001]. These inorganic chains are separated by the isolated organic cations. International Union of Crystallography 2011-06-04 /pmc/articles/PMC3151972/ /pubmed/21836850 http://dx.doi.org/10.1107/S160053681102006X Text en © Xu and He 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xu, Guohai
He, Xiyun
catena-Poly[1,1′-dimethyl-4,4′-(ethane-1,2-di­yl)dipyridinium [lead(II)-tri-μ-iodido-lead(II)-tri-μ-iodido]]
title catena-Poly[1,1′-dimethyl-4,4′-(ethane-1,2-di­yl)dipyridinium [lead(II)-tri-μ-iodido-lead(II)-tri-μ-iodido]]
title_full catena-Poly[1,1′-dimethyl-4,4′-(ethane-1,2-di­yl)dipyridinium [lead(II)-tri-μ-iodido-lead(II)-tri-μ-iodido]]
title_fullStr catena-Poly[1,1′-dimethyl-4,4′-(ethane-1,2-di­yl)dipyridinium [lead(II)-tri-μ-iodido-lead(II)-tri-μ-iodido]]
title_full_unstemmed catena-Poly[1,1′-dimethyl-4,4′-(ethane-1,2-di­yl)dipyridinium [lead(II)-tri-μ-iodido-lead(II)-tri-μ-iodido]]
title_short catena-Poly[1,1′-dimethyl-4,4′-(ethane-1,2-di­yl)dipyridinium [lead(II)-tri-μ-iodido-lead(II)-tri-μ-iodido]]
title_sort catena-poly[1,1′-dimethyl-4,4′-(ethane-1,2-di­yl)dipyridinium [lead(ii)-tri-μ-iodido-lead(ii)-tri-μ-iodido]]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151972/
https://www.ncbi.nlm.nih.gov/pubmed/21836850
http://dx.doi.org/10.1107/S160053681102006X
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AT hexiyun catenapoly11dimethyl44ethane12diyldipyridiniumleadiitrimiodidoleadiitrimiodido

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