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catena-Poly[[[tetra­aqua­cobalt(II)]-μ-4,4′-bipyridine-κ(2) N:N′] pyridine-3,5-dicarboxyl­ate trihydrate]

The crystal structure of the title compound, {[Co(C(10)H(8)N(2))(H(2)O)(4)](C(7)H(3)NO(4))·3H(2)O}(n), consists of Co(II) polymeric complex cations, uncoordinated pyridine-3,5-dicarboxyl­ate anions and lattice water mol­ecules. The Co(II) cation is coordinated by two N atoms from two 4,4′-bipyridine...

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Detalles Bibliográficos
Autor principal: Zhu, Xian-Dong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151975/
https://www.ncbi.nlm.nih.gov/pubmed/21836946
http://dx.doi.org/10.1107/S1600536811023816
Descripción
Sumario:The crystal structure of the title compound, {[Co(C(10)H(8)N(2))(H(2)O)(4)](C(7)H(3)NO(4))·3H(2)O}(n), consists of Co(II) polymeric complex cations, uncoordinated pyridine-3,5-dicarboxyl­ate anions and lattice water mol­ecules. The Co(II) cation is coordinated by two N atoms from two 4,4′-bipyridine ligands and four water mol­ecules in a distorted octa­hedral geometry. The 4,4′-bipyridine ligands bridge Co cations, forming a polymeric chain running along the b axis. The two pyridine rings of the 4,4′-biyridine are twisted to each other by a dihedral angle of 8.95 (9)°. Extensive O—H⋯O hydrogen bonding network is present in the crystal structure.