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catena-Poly[[[tetra­aqua­cobalt(II)]-μ-4,4′-bipyridine-κ(2) N:N′] pyridine-3,5-dicarboxyl­ate trihydrate]

The crystal structure of the title compound, {[Co(C(10)H(8)N(2))(H(2)O)(4)](C(7)H(3)NO(4))·3H(2)O}(n), consists of Co(II) polymeric complex cations, uncoordinated pyridine-3,5-dicarboxyl­ate anions and lattice water mol­ecules. The Co(II) cation is coordinated by two N atoms from two 4,4′-bipyridine...

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Autor principal: Zhu, Xian-Dong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151975/
https://www.ncbi.nlm.nih.gov/pubmed/21836946
http://dx.doi.org/10.1107/S1600536811023816
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author Zhu, Xian-Dong
author_facet Zhu, Xian-Dong
author_sort Zhu, Xian-Dong
collection PubMed
description The crystal structure of the title compound, {[Co(C(10)H(8)N(2))(H(2)O)(4)](C(7)H(3)NO(4))·3H(2)O}(n), consists of Co(II) polymeric complex cations, uncoordinated pyridine-3,5-dicarboxyl­ate anions and lattice water mol­ecules. The Co(II) cation is coordinated by two N atoms from two 4,4′-bipyridine ligands and four water mol­ecules in a distorted octa­hedral geometry. The 4,4′-bipyridine ligands bridge Co cations, forming a polymeric chain running along the b axis. The two pyridine rings of the 4,4′-biyridine are twisted to each other by a dihedral angle of 8.95 (9)°. Extensive O—H⋯O hydrogen bonding network is present in the crystal structure.
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spelling pubmed-31519752011-08-11 catena-Poly[[[tetra­aqua­cobalt(II)]-μ-4,4′-bipyridine-κ(2) N:N′] pyridine-3,5-dicarboxyl­ate trihydrate] Zhu, Xian-Dong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title compound, {[Co(C(10)H(8)N(2))(H(2)O)(4)](C(7)H(3)NO(4))·3H(2)O}(n), consists of Co(II) polymeric complex cations, uncoordinated pyridine-3,5-dicarboxyl­ate anions and lattice water mol­ecules. The Co(II) cation is coordinated by two N atoms from two 4,4′-bipyridine ligands and four water mol­ecules in a distorted octa­hedral geometry. The 4,4′-bipyridine ligands bridge Co cations, forming a polymeric chain running along the b axis. The two pyridine rings of the 4,4′-biyridine are twisted to each other by a dihedral angle of 8.95 (9)°. Extensive O—H⋯O hydrogen bonding network is present in the crystal structure. International Union of Crystallography 2011-06-25 /pmc/articles/PMC3151975/ /pubmed/21836946 http://dx.doi.org/10.1107/S1600536811023816 Text en © Xian-Dong Zhu 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhu, Xian-Dong
catena-Poly[[[tetra­aqua­cobalt(II)]-μ-4,4′-bipyridine-κ(2) N:N′] pyridine-3,5-dicarboxyl­ate trihydrate]
title catena-Poly[[[tetra­aqua­cobalt(II)]-μ-4,4′-bipyridine-κ(2) N:N′] pyridine-3,5-dicarboxyl­ate trihydrate]
title_full catena-Poly[[[tetra­aqua­cobalt(II)]-μ-4,4′-bipyridine-κ(2) N:N′] pyridine-3,5-dicarboxyl­ate trihydrate]
title_fullStr catena-Poly[[[tetra­aqua­cobalt(II)]-μ-4,4′-bipyridine-κ(2) N:N′] pyridine-3,5-dicarboxyl­ate trihydrate]
title_full_unstemmed catena-Poly[[[tetra­aqua­cobalt(II)]-μ-4,4′-bipyridine-κ(2) N:N′] pyridine-3,5-dicarboxyl­ate trihydrate]
title_short catena-Poly[[[tetra­aqua­cobalt(II)]-μ-4,4′-bipyridine-κ(2) N:N′] pyridine-3,5-dicarboxyl­ate trihydrate]
title_sort catena-poly[[[tetra­aqua­cobalt(ii)]-μ-4,4′-bipyridine-κ(2) n:n′] pyridine-3,5-dicarboxyl­ate trihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151975/
https://www.ncbi.nlm.nih.gov/pubmed/21836946
http://dx.doi.org/10.1107/S1600536811023816
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