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catena-Poly[[[tetraaquacobalt(II)]-μ-4,4′-bipyridine-κ(2) N:N′] pyridine-3,5-dicarboxylate trihydrate]
The crystal structure of the title compound, {[Co(C(10)H(8)N(2))(H(2)O)(4)](C(7)H(3)NO(4))·3H(2)O}(n), consists of Co(II) polymeric complex cations, uncoordinated pyridine-3,5-dicarboxylate anions and lattice water molecules. The Co(II) cation is coordinated by two N atoms from two 4,4′-bipyridine...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151975/ https://www.ncbi.nlm.nih.gov/pubmed/21836946 http://dx.doi.org/10.1107/S1600536811023816 |
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author | Zhu, Xian-Dong |
author_facet | Zhu, Xian-Dong |
author_sort | Zhu, Xian-Dong |
collection | PubMed |
description | The crystal structure of the title compound, {[Co(C(10)H(8)N(2))(H(2)O)(4)](C(7)H(3)NO(4))·3H(2)O}(n), consists of Co(II) polymeric complex cations, uncoordinated pyridine-3,5-dicarboxylate anions and lattice water molecules. The Co(II) cation is coordinated by two N atoms from two 4,4′-bipyridine ligands and four water molecules in a distorted octahedral geometry. The 4,4′-bipyridine ligands bridge Co cations, forming a polymeric chain running along the b axis. The two pyridine rings of the 4,4′-biyridine are twisted to each other by a dihedral angle of 8.95 (9)°. Extensive O—H⋯O hydrogen bonding network is present in the crystal structure. |
format | Online Article Text |
id | pubmed-3151975 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31519752011-08-11 catena-Poly[[[tetraaquacobalt(II)]-μ-4,4′-bipyridine-κ(2) N:N′] pyridine-3,5-dicarboxylate trihydrate] Zhu, Xian-Dong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title compound, {[Co(C(10)H(8)N(2))(H(2)O)(4)](C(7)H(3)NO(4))·3H(2)O}(n), consists of Co(II) polymeric complex cations, uncoordinated pyridine-3,5-dicarboxylate anions and lattice water molecules. The Co(II) cation is coordinated by two N atoms from two 4,4′-bipyridine ligands and four water molecules in a distorted octahedral geometry. The 4,4′-bipyridine ligands bridge Co cations, forming a polymeric chain running along the b axis. The two pyridine rings of the 4,4′-biyridine are twisted to each other by a dihedral angle of 8.95 (9)°. Extensive O—H⋯O hydrogen bonding network is present in the crystal structure. International Union of Crystallography 2011-06-25 /pmc/articles/PMC3151975/ /pubmed/21836946 http://dx.doi.org/10.1107/S1600536811023816 Text en © Xian-Dong Zhu 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhu, Xian-Dong catena-Poly[[[tetraaquacobalt(II)]-μ-4,4′-bipyridine-κ(2) N:N′] pyridine-3,5-dicarboxylate trihydrate] |
title |
catena-Poly[[[tetraaquacobalt(II)]-μ-4,4′-bipyridine-κ(2)
N:N′] pyridine-3,5-dicarboxylate trihydrate] |
title_full |
catena-Poly[[[tetraaquacobalt(II)]-μ-4,4′-bipyridine-κ(2)
N:N′] pyridine-3,5-dicarboxylate trihydrate] |
title_fullStr |
catena-Poly[[[tetraaquacobalt(II)]-μ-4,4′-bipyridine-κ(2)
N:N′] pyridine-3,5-dicarboxylate trihydrate] |
title_full_unstemmed |
catena-Poly[[[tetraaquacobalt(II)]-μ-4,4′-bipyridine-κ(2)
N:N′] pyridine-3,5-dicarboxylate trihydrate] |
title_short |
catena-Poly[[[tetraaquacobalt(II)]-μ-4,4′-bipyridine-κ(2)
N:N′] pyridine-3,5-dicarboxylate trihydrate] |
title_sort | catena-poly[[[tetraaquacobalt(ii)]-μ-4,4′-bipyridine-κ(2)
n:n′] pyridine-3,5-dicarboxylate trihydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151975/ https://www.ncbi.nlm.nih.gov/pubmed/21836946 http://dx.doi.org/10.1107/S1600536811023816 |
work_keys_str_mv | AT zhuxiandong catenapolytetraaquacobaltiim44bipyridinek2nnpyridine35dicarboxylatetrihydrate |