Sodium piperidine-1-carbodithio­ate dihydrate

The asymmetric unit of the title compound, Na(+)·C(6)H(10)NS(2) (−)·2H(2)O, is composed of a sodium cation, a piperidine­dithio­carbamate anion which exhibits positional disorder, and two lattice water mol­ecules. The atoms of the piperidine ring are divided over two sites with occupancy factors of...

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Detalles Bibliográficos
Autores principales: Mafud, Ana C., Gambardella, Maria Teresa P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151976/
https://www.ncbi.nlm.nih.gov/pubmed/21836925
http://dx.doi.org/10.1107/S1600536811022604
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author Mafud, Ana C.
Gambardella, Maria Teresa P.
author_facet Mafud, Ana C.
Gambardella, Maria Teresa P.
author_sort Mafud, Ana C.
collection PubMed
description The asymmetric unit of the title compound, Na(+)·C(6)H(10)NS(2) (−)·2H(2)O, is composed of a sodium cation, a piperidine­dithio­carbamate anion which exhibits positional disorder, and two lattice water mol­ecules. The atoms of the piperidine ring are divided over two sites with occupancy factors of 0.554 (6) and 0.446 (6). In the crystal, the sodium cation (coordination number of 6) and the piperidine­dithio­carbamate anion are linked, forming an infinite two-dimensional network extending parallel to (001). O—H⋯S hydrogen bonds, involving the lattice water mol­ecules, also aid in stabilizing the crystal sructure.
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spelling pubmed-31519762011-08-11 Sodium piperidine-1-carbodithio­ate dihydrate Mafud, Ana C. Gambardella, Maria Teresa P. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, Na(+)·C(6)H(10)NS(2) (−)·2H(2)O, is composed of a sodium cation, a piperidine­dithio­carbamate anion which exhibits positional disorder, and two lattice water mol­ecules. The atoms of the piperidine ring are divided over two sites with occupancy factors of 0.554 (6) and 0.446 (6). In the crystal, the sodium cation (coordination number of 6) and the piperidine­dithio­carbamate anion are linked, forming an infinite two-dimensional network extending parallel to (001). O—H⋯S hydrogen bonds, involving the lattice water mol­ecules, also aid in stabilizing the crystal sructure. International Union of Crystallography 2011-06-18 /pmc/articles/PMC3151976/ /pubmed/21836925 http://dx.doi.org/10.1107/S1600536811022604 Text en © Mafud and Gambardella 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Mafud, Ana C.
Gambardella, Maria Teresa P.
Sodium piperidine-1-carbodithio­ate dihydrate
title Sodium piperidine-1-carbodithio­ate dihydrate
title_full Sodium piperidine-1-carbodithio­ate dihydrate
title_fullStr Sodium piperidine-1-carbodithio­ate dihydrate
title_full_unstemmed Sodium piperidine-1-carbodithio­ate dihydrate
title_short Sodium piperidine-1-carbodithio­ate dihydrate
title_sort sodium piperidine-1-carbodithio­ate dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151976/
https://www.ncbi.nlm.nih.gov/pubmed/21836925
http://dx.doi.org/10.1107/S1600536811022604
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