(Z)-4-(2-Naphthyl­amino)­pent-3-en-2-one

The title compound, C(15)H(15)NO, which was synthesized under solvent-free conditions by the reaction of acetoacetone and 2-naphthyl­amine, adopts a Z conformation about the C=C bond. The enamine–ketone fragment is approximately planar [maximum deviation = 0.026 (3) Å] and forms a dihedral angle of...

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Detalles Bibliográficos
Autores principales: Harrad, Mohamed Anoir, Boualy, Brahim, Oudahmane, Abdelghani, Avignant, Daniel, Rizzoli, Corrado
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151978/
https://www.ncbi.nlm.nih.gov/pubmed/21837187
http://dx.doi.org/10.1107/S1600536811024494
Descripción
Sumario:The title compound, C(15)H(15)NO, which was synthesized under solvent-free conditions by the reaction of acetoacetone and 2-naphthyl­amine, adopts a Z conformation about the C=C bond. The enamine–ketone fragment is approximately planar [maximum deviation = 0.026 (3) Å] and forms a dihedral angle of 39.78 (3)° with the naphthalene ring system. An intra­molecular N—H⋯O hydrogen bond is observed.

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