(Z)-4-(2-Naphthyl­amino)­pent-3-en-2-one

The title compound, C(15)H(15)NO, which was synthesized under solvent-free conditions by the reaction of acetoacetone and 2-naphthyl­amine, adopts a Z conformation about the C=C bond. The enamine–ketone fragment is approximately planar [maximum deviation = 0.026 (3) Å] and forms a dihedral angle of...

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Autores principales: Harrad, Mohamed Anoir, Boualy, Brahim, Oudahmane, Abdelghani, Avignant, Daniel, Rizzoli, Corrado
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151978/
https://www.ncbi.nlm.nih.gov/pubmed/21837187
http://dx.doi.org/10.1107/S1600536811024494
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author Harrad, Mohamed Anoir
Boualy, Brahim
Oudahmane, Abdelghani
Avignant, Daniel
Rizzoli, Corrado
author_facet Harrad, Mohamed Anoir
Boualy, Brahim
Oudahmane, Abdelghani
Avignant, Daniel
Rizzoli, Corrado
author_sort Harrad, Mohamed Anoir
collection PubMed
description The title compound, C(15)H(15)NO, which was synthesized under solvent-free conditions by the reaction of acetoacetone and 2-naphthyl­amine, adopts a Z conformation about the C=C bond. The enamine–ketone fragment is approximately planar [maximum deviation = 0.026 (3) Å] and forms a dihedral angle of 39.78 (3)° with the naphthalene ring system. An intra­molecular N—H⋯O hydrogen bond is observed.
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spelling pubmed-31519782011-08-11 (Z)-4-(2-Naphthyl­amino)­pent-3-en-2-one Harrad, Mohamed Anoir Boualy, Brahim Oudahmane, Abdelghani Avignant, Daniel Rizzoli, Corrado Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(15)NO, which was synthesized under solvent-free conditions by the reaction of acetoacetone and 2-naphthyl­amine, adopts a Z conformation about the C=C bond. The enamine–ketone fragment is approximately planar [maximum deviation = 0.026 (3) Å] and forms a dihedral angle of 39.78 (3)° with the naphthalene ring system. An intra­molecular N—H⋯O hydrogen bond is observed. International Union of Crystallography 2011-06-25 /pmc/articles/PMC3151978/ /pubmed/21837187 http://dx.doi.org/10.1107/S1600536811024494 Text en © Harrad et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Harrad, Mohamed Anoir
Boualy, Brahim
Oudahmane, Abdelghani
Avignant, Daniel
Rizzoli, Corrado
(Z)-4-(2-Naphthyl­amino)­pent-3-en-2-one
title (Z)-4-(2-Naphthyl­amino)­pent-3-en-2-one
title_full (Z)-4-(2-Naphthyl­amino)­pent-3-en-2-one
title_fullStr (Z)-4-(2-Naphthyl­amino)­pent-3-en-2-one
title_full_unstemmed (Z)-4-(2-Naphthyl­amino)­pent-3-en-2-one
title_short (Z)-4-(2-Naphthyl­amino)­pent-3-en-2-one
title_sort (z)-4-(2-naphthyl­amino)­pent-3-en-2-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151978/
https://www.ncbi.nlm.nih.gov/pubmed/21837187
http://dx.doi.org/10.1107/S1600536811024494
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AT oudahmaneabdelghani z42naphthylaminopent3en2one
AT avignantdaniel z42naphthylaminopent3en2one
AT rizzolicorrado z42naphthylaminopent3en2one

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