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Crystallographic coincidence of two bridging species in a dinuclear Co(III) ethynyl­benzene complex

In the title compound, trans,trans-[μ-(m-phenyl­ene)bis­(ethyne-1,2-di­yl)]bis­[chlorido(1,4,8,11-tetra­aza­cyclo­tetra­deca­ne)cobalt(III)]–trans,trans-[μ-(5-bromo-m-phenyl­ene)bis­(ethyne-1,2-di­yl)]bis­[chlorido(1,4,8,11-tetra­aza­cyclo­tetra­deca­ne)cobalt(III)]–tetra­phenyl­borate–acetone (0.88...

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Detalles Bibliográficos
Autores principales: Hoffert, Wesley A., Shores, Matthew P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151980/
https://www.ncbi.nlm.nih.gov/pubmed/21836854
http://dx.doi.org/10.1107/S1600536811019969
Descripción
Sumario:In the title compound, trans,trans-[μ-(m-phenyl­ene)bis­(ethyne-1,2-di­yl)]bis­[chlorido(1,4,8,11-tetra­aza­cyclo­tetra­deca­ne)cobalt(III)]–trans,trans-[μ-(5-bromo-m-phenyl­ene)bis­(ethyne-1,2-di­yl)]bis­[chlorido(1,4,8,11-tetra­aza­cyclo­tetra­deca­ne)cobalt(III)]–tetra­phenyl­borate–acetone (0.88/0.12/2/4), [Co(2)(C(12)H(4))Cl(2)(C(10)H(24)N(4))(2)](0.88)[Co(2)(C(10)H(3)Br)Cl(2)(C(10)H(24)N(4))(2)](0.12)(C(24)H(20)B)(2)·4C(3)H(6)O, with the exception of the acetyl­ene and bromine groups, all atomic postitions are the same in the two compounds and are modeled at full occupancy. The Co(III) ions are six-coordinate with acetyl­ide and chloride ligands bound to the axial sites and the N atoms from the cyclam rings coordinated at the equatorial positions. N—H⋯O and N—H⋯Cl hydrogen-bonding interactions help to consolidate the crystal packing.