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Crystallographic coincidence of two bridging species in a dinuclear Co(III) ethynyl­benzene complex

In the title compound, trans,trans-[μ-(m-phenyl­ene)bis­(ethyne-1,2-di­yl)]bis­[chlorido(1,4,8,11-tetra­aza­cyclo­tetra­deca­ne)cobalt(III)]–trans,trans-[μ-(5-bromo-m-phenyl­ene)bis­(ethyne-1,2-di­yl)]bis­[chlorido(1,4,8,11-tetra­aza­cyclo­tetra­deca­ne)cobalt(III)]–tetra­phenyl­borate–acetone (0.88...

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Autores principales: Hoffert, Wesley A., Shores, Matthew P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151980/
https://www.ncbi.nlm.nih.gov/pubmed/21836854
http://dx.doi.org/10.1107/S1600536811019969
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author Hoffert, Wesley A.
Shores, Matthew P.
author_facet Hoffert, Wesley A.
Shores, Matthew P.
author_sort Hoffert, Wesley A.
collection PubMed
description In the title compound, trans,trans-[μ-(m-phenyl­ene)bis­(ethyne-1,2-di­yl)]bis­[chlorido(1,4,8,11-tetra­aza­cyclo­tetra­deca­ne)cobalt(III)]–trans,trans-[μ-(5-bromo-m-phenyl­ene)bis­(ethyne-1,2-di­yl)]bis­[chlorido(1,4,8,11-tetra­aza­cyclo­tetra­deca­ne)cobalt(III)]–tetra­phenyl­borate–acetone (0.88/0.12/2/4), [Co(2)(C(12)H(4))Cl(2)(C(10)H(24)N(4))(2)](0.88)[Co(2)(C(10)H(3)Br)Cl(2)(C(10)H(24)N(4))(2)](0.12)(C(24)H(20)B)(2)·4C(3)H(6)O, with the exception of the acetyl­ene and bromine groups, all atomic postitions are the same in the two compounds and are modeled at full occupancy. The Co(III) ions are six-coordinate with acetyl­ide and chloride ligands bound to the axial sites and the N atoms from the cyclam rings coordinated at the equatorial positions. N—H⋯O and N—H⋯Cl hydrogen-bonding interactions help to consolidate the crystal packing.
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spelling pubmed-31519802011-08-11 Crystallographic coincidence of two bridging species in a dinuclear Co(III) ethynyl­benzene complex Hoffert, Wesley A. Shores, Matthew P. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, trans,trans-[μ-(m-phenyl­ene)bis­(ethyne-1,2-di­yl)]bis­[chlorido(1,4,8,11-tetra­aza­cyclo­tetra­deca­ne)cobalt(III)]–trans,trans-[μ-(5-bromo-m-phenyl­ene)bis­(ethyne-1,2-di­yl)]bis­[chlorido(1,4,8,11-tetra­aza­cyclo­tetra­deca­ne)cobalt(III)]–tetra­phenyl­borate–acetone (0.88/0.12/2/4), [Co(2)(C(12)H(4))Cl(2)(C(10)H(24)N(4))(2)](0.88)[Co(2)(C(10)H(3)Br)Cl(2)(C(10)H(24)N(4))(2)](0.12)(C(24)H(20)B)(2)·4C(3)H(6)O, with the exception of the acetyl­ene and bromine groups, all atomic postitions are the same in the two compounds and are modeled at full occupancy. The Co(III) ions are six-coordinate with acetyl­ide and chloride ligands bound to the axial sites and the N atoms from the cyclam rings coordinated at the equatorial positions. N—H⋯O and N—H⋯Cl hydrogen-bonding interactions help to consolidate the crystal packing. International Union of Crystallography 2011-06-04 /pmc/articles/PMC3151980/ /pubmed/21836854 http://dx.doi.org/10.1107/S1600536811019969 Text en © Hoffert and Shores 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hoffert, Wesley A.
Shores, Matthew P.
Crystallographic coincidence of two bridging species in a dinuclear Co(III) ethynyl­benzene complex
title Crystallographic coincidence of two bridging species in a dinuclear Co(III) ethynyl­benzene complex
title_full Crystallographic coincidence of two bridging species in a dinuclear Co(III) ethynyl­benzene complex
title_fullStr Crystallographic coincidence of two bridging species in a dinuclear Co(III) ethynyl­benzene complex
title_full_unstemmed Crystallographic coincidence of two bridging species in a dinuclear Co(III) ethynyl­benzene complex
title_short Crystallographic coincidence of two bridging species in a dinuclear Co(III) ethynyl­benzene complex
title_sort crystallographic coincidence of two bridging species in a dinuclear co(iii) ethynyl­benzene complex
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151980/
https://www.ncbi.nlm.nih.gov/pubmed/21836854
http://dx.doi.org/10.1107/S1600536811019969
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