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Crystallographic coincidence of two bridging species in a dinuclear Co(III) ethynylbenzene complex
In the title compound, trans,trans-[μ-(m-phenylene)bis(ethyne-1,2-diyl)]bis[chlorido(1,4,8,11-tetraazacyclotetradecane)cobalt(III)]–trans,trans-[μ-(5-bromo-m-phenylene)bis(ethyne-1,2-diyl)]bis[chlorido(1,4,8,11-tetraazacyclotetradecane)cobalt(III)]–tetraphenylborate–acetone (0.88...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151980/ https://www.ncbi.nlm.nih.gov/pubmed/21836854 http://dx.doi.org/10.1107/S1600536811019969 |
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author | Hoffert, Wesley A. Shores, Matthew P. |
author_facet | Hoffert, Wesley A. Shores, Matthew P. |
author_sort | Hoffert, Wesley A. |
collection | PubMed |
description | In the title compound, trans,trans-[μ-(m-phenylene)bis(ethyne-1,2-diyl)]bis[chlorido(1,4,8,11-tetraazacyclotetradecane)cobalt(III)]–trans,trans-[μ-(5-bromo-m-phenylene)bis(ethyne-1,2-diyl)]bis[chlorido(1,4,8,11-tetraazacyclotetradecane)cobalt(III)]–tetraphenylborate–acetone (0.88/0.12/2/4), [Co(2)(C(12)H(4))Cl(2)(C(10)H(24)N(4))(2)](0.88)[Co(2)(C(10)H(3)Br)Cl(2)(C(10)H(24)N(4))(2)](0.12)(C(24)H(20)B)(2)·4C(3)H(6)O, with the exception of the acetylene and bromine groups, all atomic postitions are the same in the two compounds and are modeled at full occupancy. The Co(III) ions are six-coordinate with acetylide and chloride ligands bound to the axial sites and the N atoms from the cyclam rings coordinated at the equatorial positions. N—H⋯O and N—H⋯Cl hydrogen-bonding interactions help to consolidate the crystal packing. |
format | Online Article Text |
id | pubmed-3151980 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31519802011-08-11 Crystallographic coincidence of two bridging species in a dinuclear Co(III) ethynylbenzene complex Hoffert, Wesley A. Shores, Matthew P. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, trans,trans-[μ-(m-phenylene)bis(ethyne-1,2-diyl)]bis[chlorido(1,4,8,11-tetraazacyclotetradecane)cobalt(III)]–trans,trans-[μ-(5-bromo-m-phenylene)bis(ethyne-1,2-diyl)]bis[chlorido(1,4,8,11-tetraazacyclotetradecane)cobalt(III)]–tetraphenylborate–acetone (0.88/0.12/2/4), [Co(2)(C(12)H(4))Cl(2)(C(10)H(24)N(4))(2)](0.88)[Co(2)(C(10)H(3)Br)Cl(2)(C(10)H(24)N(4))(2)](0.12)(C(24)H(20)B)(2)·4C(3)H(6)O, with the exception of the acetylene and bromine groups, all atomic postitions are the same in the two compounds and are modeled at full occupancy. The Co(III) ions are six-coordinate with acetylide and chloride ligands bound to the axial sites and the N atoms from the cyclam rings coordinated at the equatorial positions. N—H⋯O and N—H⋯Cl hydrogen-bonding interactions help to consolidate the crystal packing. International Union of Crystallography 2011-06-04 /pmc/articles/PMC3151980/ /pubmed/21836854 http://dx.doi.org/10.1107/S1600536811019969 Text en © Hoffert and Shores 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Hoffert, Wesley A. Shores, Matthew P. Crystallographic coincidence of two bridging species in a dinuclear Co(III) ethynylbenzene complex |
title | Crystallographic coincidence of two bridging species in a dinuclear Co(III) ethynylbenzene complex |
title_full | Crystallographic coincidence of two bridging species in a dinuclear Co(III) ethynylbenzene complex |
title_fullStr | Crystallographic coincidence of two bridging species in a dinuclear Co(III) ethynylbenzene complex |
title_full_unstemmed | Crystallographic coincidence of two bridging species in a dinuclear Co(III) ethynylbenzene complex |
title_short | Crystallographic coincidence of two bridging species in a dinuclear Co(III) ethynylbenzene complex |
title_sort | crystallographic coincidence of two bridging species in a dinuclear co(iii) ethynylbenzene complex |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151980/ https://www.ncbi.nlm.nih.gov/pubmed/21836854 http://dx.doi.org/10.1107/S1600536811019969 |
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