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Poly[[(1,10-phenanthroline){μ(3)-2,2′,2′′-[1,3,5-triazine-2,4,6-triyltris(sulfanediyl)]triacetato}cadmium] 0.42-hydrate]
The asymmetric unit of the title complex, {[Cd(C(9)H(7)N(3)O(6)S(3))(C(12)H(8)N(2))]·0.42H(2)O}(n), contains a Cd(II) atom, one doubly deprotonated 2,2′,2′′-[1,3,5-triazine-2,4,6-triyltris(sulfanediyl)]triacetic acid ligand (HTTTA(2−)), a 1,10-phenanthroline (phen) ligand and a fractionally occupied...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151984/ https://www.ncbi.nlm.nih.gov/pubmed/21836837 http://dx.doi.org/10.1107/S1600536811019210 |
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author | Chi, Chun-Jing Peng, Yan-Qiang Zeng, Su-Yuan Sun, De-Zhi |
author_facet | Chi, Chun-Jing Peng, Yan-Qiang Zeng, Su-Yuan Sun, De-Zhi |
author_sort | Chi, Chun-Jing |
collection | PubMed |
description | The asymmetric unit of the title complex, {[Cd(C(9)H(7)N(3)O(6)S(3))(C(12)H(8)N(2))]·0.42H(2)O}(n), contains a Cd(II) atom, one doubly deprotonated 2,2′,2′′-[1,3,5-triazine-2,4,6-triyltris(sulfanediyl)]triacetic acid ligand (HTTTA(2−)), a 1,10-phenanthroline (phen) ligand and a fractionally occupied water molecule [site occupancy = 0.421 (15)]. The Cd(II) atom is six-coordinated within a distorted octahedral coordination geometry. Six coordination arises from four O atoms derived from three different HTTTA(2−) ligands, and two N atoms of the chelating phen molecule. The incompletely deprotonated triazine ligand adopts a μ(3)-η(1):η(1):η(2) coordination mode, resulting in the formation of chains along the c axis based on Cd(2)O(2) dimeric units. Adjacent chains are stacked through π–π stacking [3.533 (2) Å between phen and triazine rings] and C—H⋯O interactions, forming supramolecular sheets in the ab plane. Intra-and intermolecular O—H⋯O hydrogen bonds are also observed. |
format | Online Article Text |
id | pubmed-3151984 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31519842011-08-11 Poly[[(1,10-phenanthroline){μ(3)-2,2′,2′′-[1,3,5-triazine-2,4,6-triyltris(sulfanediyl)]triacetato}cadmium] 0.42-hydrate] Chi, Chun-Jing Peng, Yan-Qiang Zeng, Su-Yuan Sun, De-Zhi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title complex, {[Cd(C(9)H(7)N(3)O(6)S(3))(C(12)H(8)N(2))]·0.42H(2)O}(n), contains a Cd(II) atom, one doubly deprotonated 2,2′,2′′-[1,3,5-triazine-2,4,6-triyltris(sulfanediyl)]triacetic acid ligand (HTTTA(2−)), a 1,10-phenanthroline (phen) ligand and a fractionally occupied water molecule [site occupancy = 0.421 (15)]. The Cd(II) atom is six-coordinated within a distorted octahedral coordination geometry. Six coordination arises from four O atoms derived from three different HTTTA(2−) ligands, and two N atoms of the chelating phen molecule. The incompletely deprotonated triazine ligand adopts a μ(3)-η(1):η(1):η(2) coordination mode, resulting in the formation of chains along the c axis based on Cd(2)O(2) dimeric units. Adjacent chains are stacked through π–π stacking [3.533 (2) Å between phen and triazine rings] and C—H⋯O interactions, forming supramolecular sheets in the ab plane. Intra-and intermolecular O—H⋯O hydrogen bonds are also observed. International Union of Crystallography 2011-06-04 /pmc/articles/PMC3151984/ /pubmed/21836837 http://dx.doi.org/10.1107/S1600536811019210 Text en © Chi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Chi, Chun-Jing Peng, Yan-Qiang Zeng, Su-Yuan Sun, De-Zhi Poly[[(1,10-phenanthroline){μ(3)-2,2′,2′′-[1,3,5-triazine-2,4,6-triyltris(sulfanediyl)]triacetato}cadmium] 0.42-hydrate] |
title | Poly[[(1,10-phenanthroline){μ(3)-2,2′,2′′-[1,3,5-triazine-2,4,6-triyltris(sulfanediyl)]triacetato}cadmium] 0.42-hydrate] |
title_full | Poly[[(1,10-phenanthroline){μ(3)-2,2′,2′′-[1,3,5-triazine-2,4,6-triyltris(sulfanediyl)]triacetato}cadmium] 0.42-hydrate] |
title_fullStr | Poly[[(1,10-phenanthroline){μ(3)-2,2′,2′′-[1,3,5-triazine-2,4,6-triyltris(sulfanediyl)]triacetato}cadmium] 0.42-hydrate] |
title_full_unstemmed | Poly[[(1,10-phenanthroline){μ(3)-2,2′,2′′-[1,3,5-triazine-2,4,6-triyltris(sulfanediyl)]triacetato}cadmium] 0.42-hydrate] |
title_short | Poly[[(1,10-phenanthroline){μ(3)-2,2′,2′′-[1,3,5-triazine-2,4,6-triyltris(sulfanediyl)]triacetato}cadmium] 0.42-hydrate] |
title_sort | poly[[(1,10-phenanthroline){μ(3)-2,2′,2′′-[1,3,5-triazine-2,4,6-triyltris(sulfanediyl)]triacetato}cadmium] 0.42-hydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151984/ https://www.ncbi.nlm.nih.gov/pubmed/21836837 http://dx.doi.org/10.1107/S1600536811019210 |
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