Cargando…

Poly[[(1,10-phenanthroline){μ(3)-2,2′,2′′-[1,3,5-triazine-2,4,6-triyltris(sulfane­diyl)]triacetato}­cadmium] 0.42-hydrate]

The asymmetric unit of the title complex, {[Cd(C(9)H(7)N(3)O(6)S(3))(C(12)H(8)N(2))]·0.42H(2)O}(n), contains a Cd(II) atom, one doubly deprotonated 2,2′,2′′-[1,3,5-triazine-2,4,6-triyltris(sulfanediyl)]triacetic acid ligand (HTTTA(2−)), a 1,10-phenanthroline (phen) ligand and a fractionally occupied...

Descripción completa

Detalles Bibliográficos
Autores principales: Chi, Chun-Jing, Peng, Yan-Qiang, Zeng, Su-Yuan, Sun, De-Zhi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151984/
https://www.ncbi.nlm.nih.gov/pubmed/21836837
http://dx.doi.org/10.1107/S1600536811019210
_version_ 1782209701022269440
author Chi, Chun-Jing
Peng, Yan-Qiang
Zeng, Su-Yuan
Sun, De-Zhi
author_facet Chi, Chun-Jing
Peng, Yan-Qiang
Zeng, Su-Yuan
Sun, De-Zhi
author_sort Chi, Chun-Jing
collection PubMed
description The asymmetric unit of the title complex, {[Cd(C(9)H(7)N(3)O(6)S(3))(C(12)H(8)N(2))]·0.42H(2)O}(n), contains a Cd(II) atom, one doubly deprotonated 2,2′,2′′-[1,3,5-triazine-2,4,6-triyltris(sulfanediyl)]triacetic acid ligand (HTTTA(2−)), a 1,10-phenanthroline (phen) ligand and a fractionally occupied water mol­ecule [site occupancy = 0.421 (15)]. The Cd(II) atom is six-coordinated within a distorted octa­hedral coordination geometry. Six coordination arises from four O atoms derived from three different HTTTA(2−) ligands, and two N atoms of the chelating phen mol­ecule. The incompletely deprotonated triazine ligand adopts a μ(3)-η(1):η(1):η(2) coordination mode, resulting in the formation of chains along the c axis based on Cd(2)O(2) dimeric units. Adjacent chains are stacked through π–π stacking [3.533 (2) Å between phen and triazine rings] and C—H⋯O inter­actions, forming supra­molecular sheets in the ab plane. Intra-and intermolecular O—H⋯O hydrogen bonds are also observed.
format Online
Article
Text
id pubmed-3151984
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-31519842011-08-11 Poly[[(1,10-phenanthroline){μ(3)-2,2′,2′′-[1,3,5-triazine-2,4,6-triyltris(sulfane­diyl)]triacetato}­cadmium] 0.42-hydrate] Chi, Chun-Jing Peng, Yan-Qiang Zeng, Su-Yuan Sun, De-Zhi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title complex, {[Cd(C(9)H(7)N(3)O(6)S(3))(C(12)H(8)N(2))]·0.42H(2)O}(n), contains a Cd(II) atom, one doubly deprotonated 2,2′,2′′-[1,3,5-triazine-2,4,6-triyltris(sulfanediyl)]triacetic acid ligand (HTTTA(2−)), a 1,10-phenanthroline (phen) ligand and a fractionally occupied water mol­ecule [site occupancy = 0.421 (15)]. The Cd(II) atom is six-coordinated within a distorted octa­hedral coordination geometry. Six coordination arises from four O atoms derived from three different HTTTA(2−) ligands, and two N atoms of the chelating phen mol­ecule. The incompletely deprotonated triazine ligand adopts a μ(3)-η(1):η(1):η(2) coordination mode, resulting in the formation of chains along the c axis based on Cd(2)O(2) dimeric units. Adjacent chains are stacked through π–π stacking [3.533 (2) Å between phen and triazine rings] and C—H⋯O inter­actions, forming supra­molecular sheets in the ab plane. Intra-and intermolecular O—H⋯O hydrogen bonds are also observed. International Union of Crystallography 2011-06-04 /pmc/articles/PMC3151984/ /pubmed/21836837 http://dx.doi.org/10.1107/S1600536811019210 Text en © Chi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chi, Chun-Jing
Peng, Yan-Qiang
Zeng, Su-Yuan
Sun, De-Zhi
Poly[[(1,10-phenanthroline){μ(3)-2,2′,2′′-[1,3,5-triazine-2,4,6-triyltris(sulfane­diyl)]triacetato}­cadmium] 0.42-hydrate]
title Poly[[(1,10-phenanthroline){μ(3)-2,2′,2′′-[1,3,5-triazine-2,4,6-triyltris(sulfane­diyl)]triacetato}­cadmium] 0.42-hydrate]
title_full Poly[[(1,10-phenanthroline){μ(3)-2,2′,2′′-[1,3,5-triazine-2,4,6-triyltris(sulfane­diyl)]triacetato}­cadmium] 0.42-hydrate]
title_fullStr Poly[[(1,10-phenanthroline){μ(3)-2,2′,2′′-[1,3,5-triazine-2,4,6-triyltris(sulfane­diyl)]triacetato}­cadmium] 0.42-hydrate]
title_full_unstemmed Poly[[(1,10-phenanthroline){μ(3)-2,2′,2′′-[1,3,5-triazine-2,4,6-triyltris(sulfane­diyl)]triacetato}­cadmium] 0.42-hydrate]
title_short Poly[[(1,10-phenanthroline){μ(3)-2,2′,2′′-[1,3,5-triazine-2,4,6-triyltris(sulfane­diyl)]triacetato}­cadmium] 0.42-hydrate]
title_sort poly[[(1,10-phenanthroline){μ(3)-2,2′,2′′-[1,3,5-triazine-2,4,6-triyltris(sulfane­diyl)]triacetato}­cadmium] 0.42-hydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151984/
https://www.ncbi.nlm.nih.gov/pubmed/21836837
http://dx.doi.org/10.1107/S1600536811019210
work_keys_str_mv AT chichunjing poly110phenanthrolinem3222135triazine246triyltrissulfanediyltriacetatocadmium042hydrate
AT pengyanqiang poly110phenanthrolinem3222135triazine246triyltrissulfanediyltriacetatocadmium042hydrate
AT zengsuyuan poly110phenanthrolinem3222135triazine246triyltrissulfanediyltriacetatocadmium042hydrate
AT sundezhi poly110phenanthrolinem3222135triazine246triyltrissulfanediyltriacetatocadmium042hydrate