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Diaqua­bis­(4-carb­oxy-2-ethyl-1H-imidazole-5-carboxyl­ato-κ(2) N (3),O (4))cadmium dihydrate

The asymmetric unit of the title compound, [Cd(C(7)H(7)N(2)O(4))(2)(H(2)O)(2)]·2H(2)O, consists of one Cd(II) ion, one 4-carb­oxy-2-ethyl-1H-imidazole-5-carboxyl­ate anion, one coordinated water mol­ecule and one lattice water mol­ecule. The Cd(II) ion lies on a twofold axis, and is hexa­coordinated...

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Detalles Bibliográficos
Autores principales: Zhang, Gang, Wang, Yong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151988/
https://www.ncbi.nlm.nih.gov/pubmed/21836881
http://dx.doi.org/10.1107/S1600536811021428
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author Zhang, Gang
Wang, Yong
author_facet Zhang, Gang
Wang, Yong
author_sort Zhang, Gang
collection PubMed
description The asymmetric unit of the title compound, [Cd(C(7)H(7)N(2)O(4))(2)(H(2)O)(2)]·2H(2)O, consists of one Cd(II) ion, one 4-carb­oxy-2-ethyl-1H-imidazole-5-carboxyl­ate anion, one coordinated water mol­ecule and one lattice water mol­ecule. The Cd(II) ion lies on a twofold axis, and is hexa­coordinated by four O atoms from water mol­ecules and carboxyl­ate groups and two N atoms from two imidazole rings, in a distorted octa­hedral arrangement. An extensive framework of N—H⋯O and O—H⋯O hydrogen bonds with the participation of coordinated and free water mol­ecules is found in the crystal structure, which contributes to the formation of a three-dimensional structure.
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spelling pubmed-31519882011-08-11 Diaqua­bis­(4-carb­oxy-2-ethyl-1H-imidazole-5-carboxyl­ato-κ(2) N (3),O (4))cadmium dihydrate Zhang, Gang Wang, Yong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Cd(C(7)H(7)N(2)O(4))(2)(H(2)O)(2)]·2H(2)O, consists of one Cd(II) ion, one 4-carb­oxy-2-ethyl-1H-imidazole-5-carboxyl­ate anion, one coordinated water mol­ecule and one lattice water mol­ecule. The Cd(II) ion lies on a twofold axis, and is hexa­coordinated by four O atoms from water mol­ecules and carboxyl­ate groups and two N atoms from two imidazole rings, in a distorted octa­hedral arrangement. An extensive framework of N—H⋯O and O—H⋯O hydrogen bonds with the participation of coordinated and free water mol­ecules is found in the crystal structure, which contributes to the formation of a three-dimensional structure. International Union of Crystallography 2011-06-11 /pmc/articles/PMC3151988/ /pubmed/21836881 http://dx.doi.org/10.1107/S1600536811021428 Text en © Zhang and Wang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Gang
Wang, Yong
Diaqua­bis­(4-carb­oxy-2-ethyl-1H-imidazole-5-carboxyl­ato-κ(2) N (3),O (4))cadmium dihydrate
title Diaqua­bis­(4-carb­oxy-2-ethyl-1H-imidazole-5-carboxyl­ato-κ(2) N (3),O (4))cadmium dihydrate
title_full Diaqua­bis­(4-carb­oxy-2-ethyl-1H-imidazole-5-carboxyl­ato-κ(2) N (3),O (4))cadmium dihydrate
title_fullStr Diaqua­bis­(4-carb­oxy-2-ethyl-1H-imidazole-5-carboxyl­ato-κ(2) N (3),O (4))cadmium dihydrate
title_full_unstemmed Diaqua­bis­(4-carb­oxy-2-ethyl-1H-imidazole-5-carboxyl­ato-κ(2) N (3),O (4))cadmium dihydrate
title_short Diaqua­bis­(4-carb­oxy-2-ethyl-1H-imidazole-5-carboxyl­ato-κ(2) N (3),O (4))cadmium dihydrate
title_sort diaqua­bis­(4-carb­oxy-2-ethyl-1h-imidazole-5-carboxyl­ato-κ(2) n (3),o (4))cadmium dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151988/
https://www.ncbi.nlm.nih.gov/pubmed/21836881
http://dx.doi.org/10.1107/S1600536811021428
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