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Diaquabis(4-carboxy-2-ethyl-1H-imidazole-5-carboxylato-κ(2) N (3),O (4))cadmium dihydrate
The asymmetric unit of the title compound, [Cd(C(7)H(7)N(2)O(4))(2)(H(2)O)(2)]·2H(2)O, consists of one Cd(II) ion, one 4-carboxy-2-ethyl-1H-imidazole-5-carboxylate anion, one coordinated water molecule and one lattice water molecule. The Cd(II) ion lies on a twofold axis, and is hexacoordinated...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151988/ https://www.ncbi.nlm.nih.gov/pubmed/21836881 http://dx.doi.org/10.1107/S1600536811021428 |
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author | Zhang, Gang Wang, Yong |
author_facet | Zhang, Gang Wang, Yong |
author_sort | Zhang, Gang |
collection | PubMed |
description | The asymmetric unit of the title compound, [Cd(C(7)H(7)N(2)O(4))(2)(H(2)O)(2)]·2H(2)O, consists of one Cd(II) ion, one 4-carboxy-2-ethyl-1H-imidazole-5-carboxylate anion, one coordinated water molecule and one lattice water molecule. The Cd(II) ion lies on a twofold axis, and is hexacoordinated by four O atoms from water molecules and carboxylate groups and two N atoms from two imidazole rings, in a distorted octahedral arrangement. An extensive framework of N—H⋯O and O—H⋯O hydrogen bonds with the participation of coordinated and free water molecules is found in the crystal structure, which contributes to the formation of a three-dimensional structure. |
format | Online Article Text |
id | pubmed-3151988 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31519882011-08-11 Diaquabis(4-carboxy-2-ethyl-1H-imidazole-5-carboxylato-κ(2) N (3),O (4))cadmium dihydrate Zhang, Gang Wang, Yong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Cd(C(7)H(7)N(2)O(4))(2)(H(2)O)(2)]·2H(2)O, consists of one Cd(II) ion, one 4-carboxy-2-ethyl-1H-imidazole-5-carboxylate anion, one coordinated water molecule and one lattice water molecule. The Cd(II) ion lies on a twofold axis, and is hexacoordinated by four O atoms from water molecules and carboxylate groups and two N atoms from two imidazole rings, in a distorted octahedral arrangement. An extensive framework of N—H⋯O and O—H⋯O hydrogen bonds with the participation of coordinated and free water molecules is found in the crystal structure, which contributes to the formation of a three-dimensional structure. International Union of Crystallography 2011-06-11 /pmc/articles/PMC3151988/ /pubmed/21836881 http://dx.doi.org/10.1107/S1600536811021428 Text en © Zhang and Wang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhang, Gang Wang, Yong Diaquabis(4-carboxy-2-ethyl-1H-imidazole-5-carboxylato-κ(2) N (3),O (4))cadmium dihydrate |
title | Diaquabis(4-carboxy-2-ethyl-1H-imidazole-5-carboxylato-κ(2)
N
(3),O
(4))cadmium dihydrate |
title_full | Diaquabis(4-carboxy-2-ethyl-1H-imidazole-5-carboxylato-κ(2)
N
(3),O
(4))cadmium dihydrate |
title_fullStr | Diaquabis(4-carboxy-2-ethyl-1H-imidazole-5-carboxylato-κ(2)
N
(3),O
(4))cadmium dihydrate |
title_full_unstemmed | Diaquabis(4-carboxy-2-ethyl-1H-imidazole-5-carboxylato-κ(2)
N
(3),O
(4))cadmium dihydrate |
title_short | Diaquabis(4-carboxy-2-ethyl-1H-imidazole-5-carboxylato-κ(2)
N
(3),O
(4))cadmium dihydrate |
title_sort | diaquabis(4-carboxy-2-ethyl-1h-imidazole-5-carboxylato-κ(2)
n
(3),o
(4))cadmium dihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151988/ https://www.ncbi.nlm.nih.gov/pubmed/21836881 http://dx.doi.org/10.1107/S1600536811021428 |
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