catena-Poly[[tribenzyl­tin(IV)]-μ-(E)-3-(2-fur­yl)prop-2-enoato-κ(2) O:O′]

In the title carboxyl­ate-bridged polymer, [Sn(C(7)H(7))(3)(C(7)H(5)O(3))](n), the Sn(IV) atom exists in a distorted trans-C(3)SnO(2) trigonal–bipyramidal geometry. The polymer propagates as a chain along the a axis. There are two independent formula units in the asymmetric unit; the furyl ring of o...

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Detalles Bibliográficos
Autores principales: Keng, Thy Chun, Lo, Kong Mun, Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151990/
https://www.ncbi.nlm.nih.gov/pubmed/21836954
http://dx.doi.org/10.1107/S1600536811023919
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author Keng, Thy Chun
Lo, Kong Mun
Ng, Seik Weng
author_facet Keng, Thy Chun
Lo, Kong Mun
Ng, Seik Weng
author_sort Keng, Thy Chun
collection PubMed
description In the title carboxyl­ate-bridged polymer, [Sn(C(7)H(7))(3)(C(7)H(5)O(3))](n), the Sn(IV) atom exists in a distorted trans-C(3)SnO(2) trigonal–bipyramidal geometry. The polymer propagates as a chain along the a axis. There are two independent formula units in the asymmetric unit; the furyl ring of one of the anions is disordered over two positions in a 0.630 (8):0.370 (8) ratio. The crystal studied was a non-merohedral twin with a minor twin domain of 37.3 (1)%.
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spelling pubmed-31519902011-08-11 catena-Poly[[tribenzyl­tin(IV)]-μ-(E)-3-(2-fur­yl)prop-2-enoato-κ(2) O:O′] Keng, Thy Chun Lo, Kong Mun Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title carboxyl­ate-bridged polymer, [Sn(C(7)H(7))(3)(C(7)H(5)O(3))](n), the Sn(IV) atom exists in a distorted trans-C(3)SnO(2) trigonal–bipyramidal geometry. The polymer propagates as a chain along the a axis. There are two independent formula units in the asymmetric unit; the furyl ring of one of the anions is disordered over two positions in a 0.630 (8):0.370 (8) ratio. The crystal studied was a non-merohedral twin with a minor twin domain of 37.3 (1)%. International Union of Crystallography 2011-06-25 /pmc/articles/PMC3151990/ /pubmed/21836954 http://dx.doi.org/10.1107/S1600536811023919 Text en © Keng et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Keng, Thy Chun
Lo, Kong Mun
Ng, Seik Weng
catena-Poly[[tribenzyl­tin(IV)]-μ-(E)-3-(2-fur­yl)prop-2-enoato-κ(2) O:O′]
title catena-Poly[[tribenzyl­tin(IV)]-μ-(E)-3-(2-fur­yl)prop-2-enoato-κ(2) O:O′]
title_full catena-Poly[[tribenzyl­tin(IV)]-μ-(E)-3-(2-fur­yl)prop-2-enoato-κ(2) O:O′]
title_fullStr catena-Poly[[tribenzyl­tin(IV)]-μ-(E)-3-(2-fur­yl)prop-2-enoato-κ(2) O:O′]
title_full_unstemmed catena-Poly[[tribenzyl­tin(IV)]-μ-(E)-3-(2-fur­yl)prop-2-enoato-κ(2) O:O′]
title_short catena-Poly[[tribenzyl­tin(IV)]-μ-(E)-3-(2-fur­yl)prop-2-enoato-κ(2) O:O′]
title_sort catena-poly[[tribenzyl­tin(iv)]-μ-(e)-3-(2-fur­yl)prop-2-enoato-κ(2) o:o′]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151990/
https://www.ncbi.nlm.nih.gov/pubmed/21836954
http://dx.doi.org/10.1107/S1600536811023919
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