catena-Poly[[chloridocadmium(II)]bis­{μ-1-[(2-ethyl-1H-imidazol-1-yl)meth­yl]-1H-benzotriazole}[chloridocadmium(II)]di-μ-chlorido]

In the polymeric title complex, [CdCl(2)(C(12)H(13)N(5))](n), the Cd(II) atom is five-coordinated by two N atoms from two bridging 1-[(2-ethyl-1H-imidazol-1-yl)meth­yl]-1H-benzotriazole (bmei) ligands, two bridging Cl atoms and one terminal Cl atom in a distorted trigonal–bipyramidal geometry. The C...

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Detalles Bibliográficos
Autores principales: Wang, Xia, Shi, Xian-Ju, Yang, Huai-Xia, Feng, Hu, Liu, Pan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151992/
https://www.ncbi.nlm.nih.gov/pubmed/21836849
http://dx.doi.org/10.1107/S1600536811019908
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author Wang, Xia
Shi, Xian-Ju
Yang, Huai-Xia
Feng, Hu
Liu, Pan
author_facet Wang, Xia
Shi, Xian-Ju
Yang, Huai-Xia
Feng, Hu
Liu, Pan
author_sort Wang, Xia
collection PubMed
description In the polymeric title complex, [CdCl(2)(C(12)H(13)N(5))](n), the Cd(II) atom is five-coordinated by two N atoms from two bridging 1-[(2-ethyl-1H-imidazol-1-yl)meth­yl]-1H-benzotriazole (bmei) ligands, two bridging Cl atoms and one terminal Cl atom in a distorted trigonal–bipyramidal geometry. The Cd(II) atoms are connected alternately by the Cl atoms and bmei ligands, leading to a zigzag chain extending parallel to [011]. π–π inter­actions, with a centroid–centroid distance of 3.3016 (3) Å, help to stabilize the crystal packing.
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spelling pubmed-31519922011-08-11 catena-Poly[[chloridocadmium(II)]bis­{μ-1-[(2-ethyl-1H-imidazol-1-yl)meth­yl]-1H-benzotriazole}[chloridocadmium(II)]di-μ-chlorido] Wang, Xia Shi, Xian-Ju Yang, Huai-Xia Feng, Hu Liu, Pan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the polymeric title complex, [CdCl(2)(C(12)H(13)N(5))](n), the Cd(II) atom is five-coordinated by two N atoms from two bridging 1-[(2-ethyl-1H-imidazol-1-yl)meth­yl]-1H-benzotriazole (bmei) ligands, two bridging Cl atoms and one terminal Cl atom in a distorted trigonal–bipyramidal geometry. The Cd(II) atoms are connected alternately by the Cl atoms and bmei ligands, leading to a zigzag chain extending parallel to [011]. π–π inter­actions, with a centroid–centroid distance of 3.3016 (3) Å, help to stabilize the crystal packing. International Union of Crystallography 2011-06-04 /pmc/articles/PMC3151992/ /pubmed/21836849 http://dx.doi.org/10.1107/S1600536811019908 Text en © Wang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Xia
Shi, Xian-Ju
Yang, Huai-Xia
Feng, Hu
Liu, Pan
catena-Poly[[chloridocadmium(II)]bis­{μ-1-[(2-ethyl-1H-imidazol-1-yl)meth­yl]-1H-benzotriazole}[chloridocadmium(II)]di-μ-chlorido]
title catena-Poly[[chloridocadmium(II)]bis­{μ-1-[(2-ethyl-1H-imidazol-1-yl)meth­yl]-1H-benzotriazole}[chloridocadmium(II)]di-μ-chlorido]
title_full catena-Poly[[chloridocadmium(II)]bis­{μ-1-[(2-ethyl-1H-imidazol-1-yl)meth­yl]-1H-benzotriazole}[chloridocadmium(II)]di-μ-chlorido]
title_fullStr catena-Poly[[chloridocadmium(II)]bis­{μ-1-[(2-ethyl-1H-imidazol-1-yl)meth­yl]-1H-benzotriazole}[chloridocadmium(II)]di-μ-chlorido]
title_full_unstemmed catena-Poly[[chloridocadmium(II)]bis­{μ-1-[(2-ethyl-1H-imidazol-1-yl)meth­yl]-1H-benzotriazole}[chloridocadmium(II)]di-μ-chlorido]
title_short catena-Poly[[chloridocadmium(II)]bis­{μ-1-[(2-ethyl-1H-imidazol-1-yl)meth­yl]-1H-benzotriazole}[chloridocadmium(II)]di-μ-chlorido]
title_sort catena-poly[[chloridocadmium(ii)]bis­{μ-1-[(2-ethyl-1h-imidazol-1-yl)meth­yl]-1h-benzotriazole}[chloridocadmium(ii)]di-μ-chlorido]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151992/
https://www.ncbi.nlm.nih.gov/pubmed/21836849
http://dx.doi.org/10.1107/S1600536811019908
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