Cargando…

4-tert-Butyl-3′,4′-bis­(4-methyl­phen­yl)-3,4-dihydro-1H,4′H-spiro­[naphthalene-2,5′-[1,2]oxazol]-1-one

In the title compound, C(30)H(31)NO(2), the cyclo­hexa­none ring in the naphthalene fused-ring system adopts a half-chair conformation, presumably due to conjugation of the benzene ring. The naphthalene ring system makes dihedral angles of 86.63 (7), 65.15 (8) and 63.18 (8)° with respect to the two...

Descripción completa

Detalles Bibliográficos
Autores principales: Akhazzane, Mohamed, Zouihri, Hafid, Bennani, A.Kella, Kerbal, Abdelali, Al Houari, Ghali
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152001/
https://www.ncbi.nlm.nih.gov/pubmed/21837226
http://dx.doi.org/10.1107/S1600536811025086
Descripción
Sumario:In the title compound, C(30)H(31)NO(2), the cyclo­hexa­none ring in the naphthalene fused-ring system adopts a half-chair conformation, presumably due to conjugation of the benzene ring. The naphthalene ring system makes dihedral angles of 86.63 (7), 65.15 (8) and 63.18 (8)° with respect to the two methyl­benzene planes and the 1,2-oxazole ring system. Inter­molecular C—H⋯O and C—H⋯N hydrogen bonding and C—H⋯π inter­actions stabilize the crystal structure. The H atoms of the two methyl groups of the methyl­phenyl groups are disordered over two positions with equal occupancies.