Substitutional disorder in bis­[(cyanato-κO)/hydroxido(0.5/0.5)](5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)tin(IV)

The title complex, [Sn(IV)(C(44)H(28)N(4))(CNO)(OH)], exhibits substitutional disorder of the OH(−) and OCN(−) axial ligands. Thus, the cyanato-O ligand and the hydroxyl group bonded to the central Sn(IV) atom share statistically the axial position. The Sn(IV) ion is hexa­coordinated by the four N a...

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Autores principales: Ben Moussa, Imen, Belkhiria, Mohamed Salah, Najmudin, Shabir, Bonifacio, Cecilia, Nasri, Habib
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152010/
https://www.ncbi.nlm.nih.gov/pubmed/21836891
http://dx.doi.org/10.1107/S1600536811021544
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author Ben Moussa, Imen
Belkhiria, Mohamed Salah
Najmudin, Shabir
Bonifacio, Cecilia
Nasri, Habib
author_facet Ben Moussa, Imen
Belkhiria, Mohamed Salah
Najmudin, Shabir
Bonifacio, Cecilia
Nasri, Habib
author_sort Ben Moussa, Imen
collection PubMed
description The title complex, [Sn(IV)(C(44)H(28)N(4))(CNO)(OH)], exhibits substitutional disorder of the OH(−) and OCN(−) axial ligands. Thus, the cyanato-O ligand and the hydroxyl group bonded to the central Sn(IV) atom share statistically the axial position. The Sn(IV) ion is hexa­coordinated by the four N atoms of the pyrrole rings of the tetra­phenyl­porphyrin (TPP) and the O atoms of the two disordered OCN(−) and OH(−) axial ligands. The equatorial tin–pyrrole N atom distance (Sn—N(p)) is 2.100 (2) Å and the axial Sn—O(OCN) or Sn—O(OH) bond length is 2.074 (2) Å.
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spelling pubmed-31520102011-08-11 Substitutional disorder in bis­[(cyanato-κO)/hydroxido(0.5/0.5)](5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)tin(IV) Ben Moussa, Imen Belkhiria, Mohamed Salah Najmudin, Shabir Bonifacio, Cecilia Nasri, Habib Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Sn(IV)(C(44)H(28)N(4))(CNO)(OH)], exhibits substitutional disorder of the OH(−) and OCN(−) axial ligands. Thus, the cyanato-O ligand and the hydroxyl group bonded to the central Sn(IV) atom share statistically the axial position. The Sn(IV) ion is hexa­coordinated by the four N atoms of the pyrrole rings of the tetra­phenyl­porphyrin (TPP) and the O atoms of the two disordered OCN(−) and OH(−) axial ligands. The equatorial tin–pyrrole N atom distance (Sn—N(p)) is 2.100 (2) Å and the axial Sn—O(OCN) or Sn—O(OH) bond length is 2.074 (2) Å. International Union of Crystallography 2011-06-11 /pmc/articles/PMC3152010/ /pubmed/21836891 http://dx.doi.org/10.1107/S1600536811021544 Text en © Ben Moussa et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ben Moussa, Imen
Belkhiria, Mohamed Salah
Najmudin, Shabir
Bonifacio, Cecilia
Nasri, Habib
Substitutional disorder in bis­[(cyanato-κO)/hydroxido(0.5/0.5)](5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)tin(IV)
title Substitutional disorder in bis­[(cyanato-κO)/hydroxido(0.5/0.5)](5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)tin(IV)
title_full Substitutional disorder in bis­[(cyanato-κO)/hydroxido(0.5/0.5)](5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)tin(IV)
title_fullStr Substitutional disorder in bis­[(cyanato-κO)/hydroxido(0.5/0.5)](5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)tin(IV)
title_full_unstemmed Substitutional disorder in bis­[(cyanato-κO)/hydroxido(0.5/0.5)](5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)tin(IV)
title_short Substitutional disorder in bis­[(cyanato-κO)/hydroxido(0.5/0.5)](5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)tin(IV)
title_sort substitutional disorder in bis­[(cyanato-κo)/hydroxido(0.5/0.5)](5,10,15,20-tetra­phenyl­porphyrinato-κ(4) n)tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152010/
https://www.ncbi.nlm.nih.gov/pubmed/21836891
http://dx.doi.org/10.1107/S1600536811021544
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