1-Chloro­methyl-1,4-diazo­niabicyclo[2.2.2]octane tetra­chloridocuprate(II)

In the crystal structure of the title compound, (C(7)H(15)ClN(2))[CuCl(4)], a weak inter­molecular N—H⋯Cl hydrogen bond is observed between the organic dication and the tetrahedral [CuCl(4)](2−) anion. The organic dication is distorted, as indicated by the N—C—C—N torsion angles, which range from 16...

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Detalles Bibliográficos
Autor principal: Rong, Tao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152011/
https://www.ncbi.nlm.nih.gov/pubmed/21836880
http://dx.doi.org/10.1107/S1600536811020782
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author Rong, Tao
author_facet Rong, Tao
author_sort Rong, Tao
collection PubMed
description In the crystal structure of the title compound, (C(7)H(15)ClN(2))[CuCl(4)], a weak inter­molecular N—H⋯Cl hydrogen bond is observed between the organic dication and the tetrahedral [CuCl(4)](2−) anion. The organic dication is distorted, as indicated by the N—C—C—N torsion angles, which range from 16.76 (4) to 19.54 (3)°.
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spelling pubmed-31520112011-08-11 1-Chloro­methyl-1,4-diazo­niabicyclo[2.2.2]octane tetra­chloridocuprate(II) Rong, Tao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, (C(7)H(15)ClN(2))[CuCl(4)], a weak inter­molecular N—H⋯Cl hydrogen bond is observed between the organic dication and the tetrahedral [CuCl(4)](2−) anion. The organic dication is distorted, as indicated by the N—C—C—N torsion angles, which range from 16.76 (4) to 19.54 (3)°. International Union of Crystallography 2011-06-11 /pmc/articles/PMC3152011/ /pubmed/21836880 http://dx.doi.org/10.1107/S1600536811020782 Text en © Tao Rong 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Rong, Tao
1-Chloro­methyl-1,4-diazo­niabicyclo[2.2.2]octane tetra­chloridocuprate(II)
title 1-Chloro­methyl-1,4-diazo­niabicyclo[2.2.2]octane tetra­chloridocuprate(II)
title_full 1-Chloro­methyl-1,4-diazo­niabicyclo[2.2.2]octane tetra­chloridocuprate(II)
title_fullStr 1-Chloro­methyl-1,4-diazo­niabicyclo[2.2.2]octane tetra­chloridocuprate(II)
title_full_unstemmed 1-Chloro­methyl-1,4-diazo­niabicyclo[2.2.2]octane tetra­chloridocuprate(II)
title_short 1-Chloro­methyl-1,4-diazo­niabicyclo[2.2.2]octane tetra­chloridocuprate(II)
title_sort 1-chloro­methyl-1,4-diazo­niabicyclo[2.2.2]octane tetra­chloridocuprate(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152011/
https://www.ncbi.nlm.nih.gov/pubmed/21836880
http://dx.doi.org/10.1107/S1600536811020782
work_keys_str_mv AT rongtao 1chloromethyl14diazoniabicyclo222octanetetrachloridocuprateii

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