A new Mo(VI) Schiff base complex: methanol[N′-(3-meth­oxy-2-oxidobenzyl­idene)benzohydrazidato]dioxido­molybdenum(VI)

In the title benzil­idene Schiff base molybdenum(VI) complex, [Mo(C(15)H(12)N(2)O(3))O(2)(CH(3)OH)], the Mo(VI) ion is coordinated by two oxide O atoms and by two O atoms and one N atom of the tridentate N′-(3-meth­oxy-2-oxidobenzyl­idene)benzo­hydrazidate (L) Schiff base ligand. The methanol O atom...

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Detalles Bibliográficos
Autores principales: Sheikhshoaie, Iran, Langer, Vratislav, Yasrebi, Seyed Ali
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152014/
https://www.ncbi.nlm.nih.gov/pubmed/21836845
http://dx.doi.org/10.1107/S1600536811020101
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author Sheikhshoaie, Iran
Langer, Vratislav
Yasrebi, Seyed Ali
author_facet Sheikhshoaie, Iran
Langer, Vratislav
Yasrebi, Seyed Ali
author_sort Sheikhshoaie, Iran
collection PubMed
description In the title benzil­idene Schiff base molybdenum(VI) complex, [Mo(C(15)H(12)N(2)O(3))O(2)(CH(3)OH)], the Mo(VI) ion is coordinated by two oxide O atoms and by two O atoms and one N atom of the tridentate N′-(3-meth­oxy-2-oxidobenzyl­idene)benzo­hydrazidate (L) Schiff base ligand. The methanol O atom completes the distorted octa­hedral configuration of the Mo(VI) atom. Strong O—H⋯N hydrogen bonds form a C(5) chain around a 2(1) screw axis. Weak C—H—O hydrogen bonds are also present.
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spelling pubmed-31520142011-08-11 A new Mo(VI) Schiff base complex: methanol[N′-(3-meth­oxy-2-oxidobenzyl­idene)benzohydrazidato]dioxido­molybdenum(VI) Sheikhshoaie, Iran Langer, Vratislav Yasrebi, Seyed Ali Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title benzil­idene Schiff base molybdenum(VI) complex, [Mo(C(15)H(12)N(2)O(3))O(2)(CH(3)OH)], the Mo(VI) ion is coordinated by two oxide O atoms and by two O atoms and one N atom of the tridentate N′-(3-meth­oxy-2-oxidobenzyl­idene)benzo­hydrazidate (L) Schiff base ligand. The methanol O atom completes the distorted octa­hedral configuration of the Mo(VI) atom. Strong O—H⋯N hydrogen bonds form a C(5) chain around a 2(1) screw axis. Weak C—H—O hydrogen bonds are also present. International Union of Crystallography 2011-06-04 /pmc/articles/PMC3152014/ /pubmed/21836845 http://dx.doi.org/10.1107/S1600536811020101 Text en © Sheikhshoaie et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sheikhshoaie, Iran
Langer, Vratislav
Yasrebi, Seyed Ali
A new Mo(VI) Schiff base complex: methanol[N′-(3-meth­oxy-2-oxidobenzyl­idene)benzohydrazidato]dioxido­molybdenum(VI)
title A new Mo(VI) Schiff base complex: methanol[N′-(3-meth­oxy-2-oxidobenzyl­idene)benzohydrazidato]dioxido­molybdenum(VI)
title_full A new Mo(VI) Schiff base complex: methanol[N′-(3-meth­oxy-2-oxidobenzyl­idene)benzohydrazidato]dioxido­molybdenum(VI)
title_fullStr A new Mo(VI) Schiff base complex: methanol[N′-(3-meth­oxy-2-oxidobenzyl­idene)benzohydrazidato]dioxido­molybdenum(VI)
title_full_unstemmed A new Mo(VI) Schiff base complex: methanol[N′-(3-meth­oxy-2-oxidobenzyl­idene)benzohydrazidato]dioxido­molybdenum(VI)
title_short A new Mo(VI) Schiff base complex: methanol[N′-(3-meth­oxy-2-oxidobenzyl­idene)benzohydrazidato]dioxido­molybdenum(VI)
title_sort new mo(vi) schiff base complex: methanol[n′-(3-meth­oxy-2-oxidobenzyl­idene)benzohydrazidato]dioxido­molybdenum(vi)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152014/
https://www.ncbi.nlm.nih.gov/pubmed/21836845
http://dx.doi.org/10.1107/S1600536811020101
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