Ethyl 3-(2-chloro-5,8-dimeth­oxy­quinolin-3-yl)-2-cyano­oxirane-2-carboxyl­ate

The title mol­ecule, C(17)H(15)ClN(2)O(5), contains a quinolyl unit linked to a functionalized oxirane system with a 2,3-trans arrangement of the substituents (ester group versus quinol­yl). The structure can be described as being built up from zigzag layers parallel to (1[Image: see text]0). The he...

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Detalles Bibliográficos
Autores principales: Alliouche, Hayette, Bouacida, Sofiane, Roisnel, Thierry, Belfaitah, Ali
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152015/
https://www.ncbi.nlm.nih.gov/pubmed/21837137
http://dx.doi.org/10.1107/S1600536811023336
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author Alliouche, Hayette
Bouacida, Sofiane
Roisnel, Thierry
Belfaitah, Ali
author_facet Alliouche, Hayette
Bouacida, Sofiane
Roisnel, Thierry
Belfaitah, Ali
author_sort Alliouche, Hayette
collection PubMed
description The title mol­ecule, C(17)H(15)ClN(2)O(5), contains a quinolyl unit linked to a functionalized oxirane system with a 2,3-trans arrangement of the substituents (ester group versus quinol­yl). The structure can be described as being built up from zigzag layers parallel to (1[Image: see text]0). The heterocyclic ring of the quinolyl unit forms a dihedral angle of 60.05 (1)° with the oxirane plane. The crystal packing is stabilized by inter­molecular C—H⋯O and C—H⋯N hydrogen bonding, resulting in the formation of an infinite three-dimensional network and reinforcing the cohesion between the layers.
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spelling pubmed-31520152011-08-11 Ethyl 3-(2-chloro-5,8-dimeth­oxy­quinolin-3-yl)-2-cyano­oxirane-2-carboxyl­ate Alliouche, Hayette Bouacida, Sofiane Roisnel, Thierry Belfaitah, Ali Acta Crystallogr Sect E Struct Rep Online Organic Papers The title mol­ecule, C(17)H(15)ClN(2)O(5), contains a quinolyl unit linked to a functionalized oxirane system with a 2,3-trans arrangement of the substituents (ester group versus quinol­yl). The structure can be described as being built up from zigzag layers parallel to (1[Image: see text]0). The heterocyclic ring of the quinolyl unit forms a dihedral angle of 60.05 (1)° with the oxirane plane. The crystal packing is stabilized by inter­molecular C—H⋯O and C—H⋯N hydrogen bonding, resulting in the formation of an infinite three-dimensional network and reinforcing the cohesion between the layers. International Union of Crystallography 2011-06-22 /pmc/articles/PMC3152015/ /pubmed/21837137 http://dx.doi.org/10.1107/S1600536811023336 Text en © Alliouche et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Alliouche, Hayette
Bouacida, Sofiane
Roisnel, Thierry
Belfaitah, Ali
Ethyl 3-(2-chloro-5,8-dimeth­oxy­quinolin-3-yl)-2-cyano­oxirane-2-carboxyl­ate
title Ethyl 3-(2-chloro-5,8-dimeth­oxy­quinolin-3-yl)-2-cyano­oxirane-2-carboxyl­ate
title_full Ethyl 3-(2-chloro-5,8-dimeth­oxy­quinolin-3-yl)-2-cyano­oxirane-2-carboxyl­ate
title_fullStr Ethyl 3-(2-chloro-5,8-dimeth­oxy­quinolin-3-yl)-2-cyano­oxirane-2-carboxyl­ate
title_full_unstemmed Ethyl 3-(2-chloro-5,8-dimeth­oxy­quinolin-3-yl)-2-cyano­oxirane-2-carboxyl­ate
title_short Ethyl 3-(2-chloro-5,8-dimeth­oxy­quinolin-3-yl)-2-cyano­oxirane-2-carboxyl­ate
title_sort ethyl 3-(2-chloro-5,8-dimeth­oxy­quinolin-3-yl)-2-cyano­oxirane-2-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152015/
https://www.ncbi.nlm.nih.gov/pubmed/21837137
http://dx.doi.org/10.1107/S1600536811023336
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AT roisnelthierry ethyl32chloro58dimethoxyquinolin3yl2cyanooxirane2carboxylate
AT belfaitahali ethyl32chloro58dimethoxyquinolin3yl2cyanooxirane2carboxylate

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