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cis-(Dimethyl sulfoxide-κO)[N′-(3-ethoxy-2-oxidobenzylidene-κO)-2-hydroxybenzohydrazidato-κ(2) N′,O]dioxidomolybdenum(VI)
The coordination geometry at the Mo(VI) atom in the title compound, [Mo(C(16)H(14)N(2)O(4))O(2)(C(2)H(6)OS)], is distorted octahedral. The phenolate O, imino N, oxide O from the enolized carbonyl group and one of the terminal O atoms form the equatorial plane; the axial positions are occupied by th...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152017/ https://www.ncbi.nlm.nih.gov/pubmed/21836856 http://dx.doi.org/10.1107/S1600536811020290 |
| _version_ | 1782209708610813952 |
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| author | Ngan, Ngui Khiong Lo, Kong Mun Richard Wong, Chee Seng |
| author_facet | Ngan, Ngui Khiong Lo, Kong Mun Richard Wong, Chee Seng |
| author_sort | Ngan, Ngui Khiong |
| collection | PubMed |
| description | The coordination geometry at the Mo(VI) atom in the title compound, [Mo(C(16)H(14)N(2)O(4))O(2)(C(2)H(6)OS)], is distorted octahedral. The phenolate O, imino N, oxide O from the enolized carbonyl group and one of the terminal O atoms form the equatorial plane; the axial positions are occupied by the other terminal O atom of the dioxidomolybdenum group and the donor O atom of DMSO. The O=Mo=O angle is 105.31 (6)°. An intramolecular O—H⋯N hydrogen bond and weak intermolecular C—H⋯O hydrogen bonds are present in the structure. |
| format | Online Article Text |
| id | pubmed-3152017 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-31520172011-08-11 cis-(Dimethyl sulfoxide-κO)[N′-(3-ethoxy-2-oxidobenzylidene-κO)-2-hydroxybenzohydrazidato-κ(2) N′,O]dioxidomolybdenum(VI) Ngan, Ngui Khiong Lo, Kong Mun Richard Wong, Chee Seng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The coordination geometry at the Mo(VI) atom in the title compound, [Mo(C(16)H(14)N(2)O(4))O(2)(C(2)H(6)OS)], is distorted octahedral. The phenolate O, imino N, oxide O from the enolized carbonyl group and one of the terminal O atoms form the equatorial plane; the axial positions are occupied by the other terminal O atom of the dioxidomolybdenum group and the donor O atom of DMSO. The O=Mo=O angle is 105.31 (6)°. An intramolecular O—H⋯N hydrogen bond and weak intermolecular C—H⋯O hydrogen bonds are present in the structure. International Union of Crystallography 2011-06-04 /pmc/articles/PMC3152017/ /pubmed/21836856 http://dx.doi.org/10.1107/S1600536811020290 Text en © Ngan et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Ngan, Ngui Khiong Lo, Kong Mun Richard Wong, Chee Seng cis-(Dimethyl sulfoxide-κO)[N′-(3-ethoxy-2-oxidobenzylidene-κO)-2-hydroxybenzohydrazidato-κ(2) N′,O]dioxidomolybdenum(VI) |
| title |
cis-(Dimethyl sulfoxide-κO)[N′-(3-ethoxy-2-oxidobenzylidene-κO)-2-hydroxybenzohydrazidato-κ(2)
N′,O]dioxidomolybdenum(VI) |
| title_full |
cis-(Dimethyl sulfoxide-κO)[N′-(3-ethoxy-2-oxidobenzylidene-κO)-2-hydroxybenzohydrazidato-κ(2)
N′,O]dioxidomolybdenum(VI) |
| title_fullStr |
cis-(Dimethyl sulfoxide-κO)[N′-(3-ethoxy-2-oxidobenzylidene-κO)-2-hydroxybenzohydrazidato-κ(2)
N′,O]dioxidomolybdenum(VI) |
| title_full_unstemmed |
cis-(Dimethyl sulfoxide-κO)[N′-(3-ethoxy-2-oxidobenzylidene-κO)-2-hydroxybenzohydrazidato-κ(2)
N′,O]dioxidomolybdenum(VI) |
| title_short |
cis-(Dimethyl sulfoxide-κO)[N′-(3-ethoxy-2-oxidobenzylidene-κO)-2-hydroxybenzohydrazidato-κ(2)
N′,O]dioxidomolybdenum(VI) |
| title_sort | cis-(dimethyl sulfoxide-κo)[n′-(3-ethoxy-2-oxidobenzylidene-κo)-2-hydroxybenzohydrazidato-κ(2)
n′,o]dioxidomolybdenum(vi) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152017/ https://www.ncbi.nlm.nih.gov/pubmed/21836856 http://dx.doi.org/10.1107/S1600536811020290 |
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