2,6-Anhydro-1,3-di-O-benzyl-d-mannitol

In the title compound, C(20)H(24)O(5), the six-membered pyran­ose ring adopts a chair conformation. The dihedral angle between the planes of the phenyl groups of the benzyl substituents is 63.1°. Two types of inter­molecular O—H⋯O hydrogen bonds lead to the formation of infinite chains along the b a...

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Detalles Bibliográficos
Autores principales: de Siqueira, Edmilson Clarindo, Doboszewski, Bogdan, McGarrah, James, Nazarenko, Alexander Y.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152021/
https://www.ncbi.nlm.nih.gov/pubmed/21837055
http://dx.doi.org/10.1107/S1600536811022306
Descripción
Sumario:In the title compound, C(20)H(24)O(5), the six-membered pyran­ose ring adopts a chair conformation. The dihedral angle between the planes of the phenyl groups of the benzyl substituents is 63.1°. Two types of inter­molecular O—H⋯O hydrogen bonds lead to the formation of infinite chains along the b axis. Only weak C—H⋯O contacts exist between neighboring chains.

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