Potassium N-bromo-4-chloro­benzene­sulfonamidate monohydrate

In the structure of the title compound, K(+)·C(6)H(4)BrClNO(2)S(−)·H(2)O, the K(+) cation is hepta­coordinated. It is connected to two water O atoms, four sulfonyl O atoms and one Br atom. Further, the sulfonyl and water O atoms in the structure are bridged in a bidentate fashion. The S—N distance o...

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Detalles Bibliográficos
Autores principales: Gowda, B. Thimme, Foro, Sabine, Shakuntala, K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152022/
https://www.ncbi.nlm.nih.gov/pubmed/21836940
http://dx.doi.org/10.1107/S1600536811023610
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author Gowda, B. Thimme
Foro, Sabine
Shakuntala, K.
author_facet Gowda, B. Thimme
Foro, Sabine
Shakuntala, K.
author_sort Gowda, B. Thimme
collection PubMed
description In the structure of the title compound, K(+)·C(6)H(4)BrClNO(2)S(−)·H(2)O, the K(+) cation is hepta­coordinated. It is connected to two water O atoms, four sulfonyl O atoms and one Br atom. Further, the sulfonyl and water O atoms in the structure are bridged in a bidentate fashion. The S—N distance of 1.584 (6) Å is consistent with an S—N double bond, The crystal structure is stabilized by inter­molecular O—H⋯N hydrogen bonds.
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spelling pubmed-31520222011-08-11 Potassium N-bromo-4-chloro­benzene­sulfonamidate monohydrate Gowda, B. Thimme Foro, Sabine Shakuntala, K. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the structure of the title compound, K(+)·C(6)H(4)BrClNO(2)S(−)·H(2)O, the K(+) cation is hepta­coordinated. It is connected to two water O atoms, four sulfonyl O atoms and one Br atom. Further, the sulfonyl and water O atoms in the structure are bridged in a bidentate fashion. The S—N distance of 1.584 (6) Å is consistent with an S—N double bond, The crystal structure is stabilized by inter­molecular O—H⋯N hydrogen bonds. International Union of Crystallography 2011-06-22 /pmc/articles/PMC3152022/ /pubmed/21836940 http://dx.doi.org/10.1107/S1600536811023610 Text en © Gowda et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gowda, B. Thimme
Foro, Sabine
Shakuntala, K.
Potassium N-bromo-4-chloro­benzene­sulfonamidate monohydrate
title Potassium N-bromo-4-chloro­benzene­sulfonamidate monohydrate
title_full Potassium N-bromo-4-chloro­benzene­sulfonamidate monohydrate
title_fullStr Potassium N-bromo-4-chloro­benzene­sulfonamidate monohydrate
title_full_unstemmed Potassium N-bromo-4-chloro­benzene­sulfonamidate monohydrate
title_short Potassium N-bromo-4-chloro­benzene­sulfonamidate monohydrate
title_sort potassium n-bromo-4-chloro­benzene­sulfonamidate monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152022/
https://www.ncbi.nlm.nih.gov/pubmed/21836940
http://dx.doi.org/10.1107/S1600536811023610
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