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Bis[μ-N′-(2-oxidobenzylidene)thiophene-2-carbohydrazidato]bis[dimethanolnickel(II)]
In the crystal structure of the centrosymmetric binuclear title complex, [Ni(2)(C(12)H(8)N(2)O(2)S)(2)(CH(3)OH)(4)], there are intermolecular O—H⋯O, O—H⋯N and O—H⋯S hydrogen bonds. These help to stabilize the structure and link the molecules, forming a three-dimensional network structure. The Ni(2...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152025/ https://www.ncbi.nlm.nih.gov/pubmed/21836896 http://dx.doi.org/10.1107/S160053681102143X |
| _version_ | 1782209710381858816 |
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| author | Ma, Jian-Hua Wu, Wen-Shi Zhang, Xiao-Qing Tang, Sheng-Jiao Lin, Xin-Yong |
| author_facet | Ma, Jian-Hua Wu, Wen-Shi Zhang, Xiao-Qing Tang, Sheng-Jiao Lin, Xin-Yong |
| author_sort | Ma, Jian-Hua |
| collection | PubMed |
| description | In the crystal structure of the centrosymmetric binuclear title complex, [Ni(2)(C(12)H(8)N(2)O(2)S)(2)(CH(3)OH)(4)], there are intermolecular O—H⋯O, O—H⋯N and O—H⋯S hydrogen bonds. These help to stabilize the structure and link the molecules, forming a three-dimensional network structure. The Ni(2+) cation exists in a slightly distorted octahedral NiNO(5) coordination environment. The thiophene rings are disordered over two equivalent conformations with occupancies of 0.881 (3) and 0.119 (3). |
| format | Online Article Text |
| id | pubmed-3152025 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-31520252011-08-11 Bis[μ-N′-(2-oxidobenzylidene)thiophene-2-carbohydrazidato]bis[dimethanolnickel(II)] Ma, Jian-Hua Wu, Wen-Shi Zhang, Xiao-Qing Tang, Sheng-Jiao Lin, Xin-Yong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the centrosymmetric binuclear title complex, [Ni(2)(C(12)H(8)N(2)O(2)S)(2)(CH(3)OH)(4)], there are intermolecular O—H⋯O, O—H⋯N and O—H⋯S hydrogen bonds. These help to stabilize the structure and link the molecules, forming a three-dimensional network structure. The Ni(2+) cation exists in a slightly distorted octahedral NiNO(5) coordination environment. The thiophene rings are disordered over two equivalent conformations with occupancies of 0.881 (3) and 0.119 (3). International Union of Crystallography 2011-06-11 /pmc/articles/PMC3152025/ /pubmed/21836896 http://dx.doi.org/10.1107/S160053681102143X Text en © Ma et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Ma, Jian-Hua Wu, Wen-Shi Zhang, Xiao-Qing Tang, Sheng-Jiao Lin, Xin-Yong Bis[μ-N′-(2-oxidobenzylidene)thiophene-2-carbohydrazidato]bis[dimethanolnickel(II)] |
| title | Bis[μ-N′-(2-oxidobenzylidene)thiophene-2-carbohydrazidato]bis[dimethanolnickel(II)] |
| title_full | Bis[μ-N′-(2-oxidobenzylidene)thiophene-2-carbohydrazidato]bis[dimethanolnickel(II)] |
| title_fullStr | Bis[μ-N′-(2-oxidobenzylidene)thiophene-2-carbohydrazidato]bis[dimethanolnickel(II)] |
| title_full_unstemmed | Bis[μ-N′-(2-oxidobenzylidene)thiophene-2-carbohydrazidato]bis[dimethanolnickel(II)] |
| title_short | Bis[μ-N′-(2-oxidobenzylidene)thiophene-2-carbohydrazidato]bis[dimethanolnickel(II)] |
| title_sort | bis[μ-n′-(2-oxidobenzylidene)thiophene-2-carbohydrazidato]bis[dimethanolnickel(ii)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152025/ https://www.ncbi.nlm.nih.gov/pubmed/21836896 http://dx.doi.org/10.1107/S160053681102143X |
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