N′-[(E)-2-Meth­oxy­benzyl­idene]pyrazine-2-carbohydrazide

In the title compound, C(13)H(12)N(4)O(2), all the non-H atoms lie on a crystallographic mirror plane and an intra­molecular N—H⋯N hydrogen bond generates an S(5) ring; the conformation about the imine bond [1.280 (3) Å] is E. In the crystal, mol­ecules assemble into a two-dimensional array via C—H⋯...

Descripción completa

Detalles Bibliográficos
Autores principales: de Souza, Marcus V. N., da Silva Lima, Camilo H., Wardell, James L., Wardell, Solange M. S. V., Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152029/
https://www.ncbi.nlm.nih.gov/pubmed/21837107
http://dx.doi.org/10.1107/S1600536811022938
_version_ 1782209711259516928
author de Souza, Marcus V. N.
da Silva Lima, Camilo H.
Wardell, James L.
Wardell, Solange M. S. V.
Tiekink, Edward R. T.
author_facet de Souza, Marcus V. N.
da Silva Lima, Camilo H.
Wardell, James L.
Wardell, Solange M. S. V.
Tiekink, Edward R. T.
author_sort de Souza, Marcus V. N.
collection PubMed
description In the title compound, C(13)H(12)N(4)O(2), all the non-H atoms lie on a crystallographic mirror plane and an intra­molecular N—H⋯N hydrogen bond generates an S(5) ring; the conformation about the imine bond [1.280 (3) Å] is E. In the crystal, mol­ecules assemble into a two-dimensional array via C—H⋯O(carbon­yl) and C—H⋯N(pyrazine) contacts. Layers stack along the b-axis direction via weak π–π inter­actions between pyrazine rings [ring centroid distance = 3.8028 (8) Å].
format Online
Article
Text
id pubmed-3152029
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-31520292011-08-11 N′-[(E)-2-Meth­oxy­benzyl­idene]pyrazine-2-carbohydrazide de Souza, Marcus V. N. da Silva Lima, Camilo H. Wardell, James L. Wardell, Solange M. S. V. Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(13)H(12)N(4)O(2), all the non-H atoms lie on a crystallographic mirror plane and an intra­molecular N—H⋯N hydrogen bond generates an S(5) ring; the conformation about the imine bond [1.280 (3) Å] is E. In the crystal, mol­ecules assemble into a two-dimensional array via C—H⋯O(carbon­yl) and C—H⋯N(pyrazine) contacts. Layers stack along the b-axis direction via weak π–π inter­actions between pyrazine rings [ring centroid distance = 3.8028 (8) Å]. International Union of Crystallography 2011-06-18 /pmc/articles/PMC3152029/ /pubmed/21837107 http://dx.doi.org/10.1107/S1600536811022938 Text en © Souza et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
de Souza, Marcus V. N.
da Silva Lima, Camilo H.
Wardell, James L.
Wardell, Solange M. S. V.
Tiekink, Edward R. T.
N′-[(E)-2-Meth­oxy­benzyl­idene]pyrazine-2-carbohydrazide
title N′-[(E)-2-Meth­oxy­benzyl­idene]pyrazine-2-carbohydrazide
title_full N′-[(E)-2-Meth­oxy­benzyl­idene]pyrazine-2-carbohydrazide
title_fullStr N′-[(E)-2-Meth­oxy­benzyl­idene]pyrazine-2-carbohydrazide
title_full_unstemmed N′-[(E)-2-Meth­oxy­benzyl­idene]pyrazine-2-carbohydrazide
title_short N′-[(E)-2-Meth­oxy­benzyl­idene]pyrazine-2-carbohydrazide
title_sort n′-[(e)-2-meth­oxy­benzyl­idene]pyrazine-2-carbohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152029/
https://www.ncbi.nlm.nih.gov/pubmed/21837107
http://dx.doi.org/10.1107/S1600536811022938
work_keys_str_mv AT desouzamarcusvn ne2methoxybenzylidenepyrazine2carbohydrazide
AT dasilvalimacamiloh ne2methoxybenzylidenepyrazine2carbohydrazide
AT wardelljamesl ne2methoxybenzylidenepyrazine2carbohydrazide
AT wardellsolangemsv ne2methoxybenzylidenepyrazine2carbohydrazide
AT tiekinkedwardrt ne2methoxybenzylidenepyrazine2carbohydrazide

Ejemplares similares