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μ-4,4′-Bipyridine-κ(2) N:N′-bis[bis(2-chlorobenzoato-κ(2) O,O′)lead(II)]
In the title dinuclear complex, [Pb(2)(C(7)H(4)ClO(2))(4)(C(10)H(8)N(2))], the Pb(II) atom is five-coordinated by four carboxylate O atoms from two 2-chlorobenzoate ligands and one N atom from a bridging 4,4′-bipyridine (4,4′-bpy) ligand, displaying a hemi-directed coordination. The 4,4′-bpy ligan...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152032/ https://www.ncbi.nlm.nih.gov/pubmed/21836919 http://dx.doi.org/10.1107/S1600536811022422 |
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author | Feng, Tian-Jun |
author_facet | Feng, Tian-Jun |
author_sort | Feng, Tian-Jun |
collection | PubMed |
description | In the title dinuclear complex, [Pb(2)(C(7)H(4)ClO(2))(4)(C(10)H(8)N(2))], the Pb(II) atom is five-coordinated by four carboxylate O atoms from two 2-chlorobenzoate ligands and one N atom from a bridging 4,4′-bipyridine (4,4′-bpy) ligand, displaying a hemi-directed coordination. The 4,4′-bpy ligand has an inversion center at the mid-point of the central C—C bond. The empty side of the metal ion is capped by two carboxylate O atoms from a neighboring molecule, with weak Pb⋯O contacts [Pb⋯O = 3.069 (2) and 3.071 (3) Å]. The crystal structure is stabilized by C—H⋯O hydrogen bonds and π–π stacking interactions between the benzene and pyridine rings [centroid–centroid distance = 3.749 (3) Å]. |
format | Online Article Text |
id | pubmed-3152032 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31520322011-08-11 μ-4,4′-Bipyridine-κ(2) N:N′-bis[bis(2-chlorobenzoato-κ(2) O,O′)lead(II)] Feng, Tian-Jun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title dinuclear complex, [Pb(2)(C(7)H(4)ClO(2))(4)(C(10)H(8)N(2))], the Pb(II) atom is five-coordinated by four carboxylate O atoms from two 2-chlorobenzoate ligands and one N atom from a bridging 4,4′-bipyridine (4,4′-bpy) ligand, displaying a hemi-directed coordination. The 4,4′-bpy ligand has an inversion center at the mid-point of the central C—C bond. The empty side of the metal ion is capped by two carboxylate O atoms from a neighboring molecule, with weak Pb⋯O contacts [Pb⋯O = 3.069 (2) and 3.071 (3) Å]. The crystal structure is stabilized by C—H⋯O hydrogen bonds and π–π stacking interactions between the benzene and pyridine rings [centroid–centroid distance = 3.749 (3) Å]. International Union of Crystallography 2011-06-18 /pmc/articles/PMC3152032/ /pubmed/21836919 http://dx.doi.org/10.1107/S1600536811022422 Text en © Tian-Jun Feng 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Feng, Tian-Jun μ-4,4′-Bipyridine-κ(2) N:N′-bis[bis(2-chlorobenzoato-κ(2) O,O′)lead(II)] |
title | μ-4,4′-Bipyridine-κ(2)
N:N′-bis[bis(2-chlorobenzoato-κ(2)
O,O′)lead(II)] |
title_full | μ-4,4′-Bipyridine-κ(2)
N:N′-bis[bis(2-chlorobenzoato-κ(2)
O,O′)lead(II)] |
title_fullStr | μ-4,4′-Bipyridine-κ(2)
N:N′-bis[bis(2-chlorobenzoato-κ(2)
O,O′)lead(II)] |
title_full_unstemmed | μ-4,4′-Bipyridine-κ(2)
N:N′-bis[bis(2-chlorobenzoato-κ(2)
O,O′)lead(II)] |
title_short | μ-4,4′-Bipyridine-κ(2)
N:N′-bis[bis(2-chlorobenzoato-κ(2)
O,O′)lead(II)] |
title_sort | μ-4,4′-bipyridine-κ(2)
n:n′-bis[bis(2-chlorobenzoato-κ(2)
o,o′)lead(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152032/ https://www.ncbi.nlm.nih.gov/pubmed/21836919 http://dx.doi.org/10.1107/S1600536811022422 |
work_keys_str_mv | AT fengtianjun m44bipyridinek2nnbisbis2chlorobenzoatok2ooleadii |