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μ-4,4′-Bipyridine-κ(2) N:N′-bis­[bis­(2-chloro­benzoato-κ(2) O,O′)lead(II)]

In the title dinuclear complex, [Pb(2)(C(7)H(4)ClO(2))(4)(C(10)H(8)N(2))], the Pb(II) atom is five-coordinated by four carboxyl­ate O atoms from two 2-chloro­benzoate ligands and one N atom from a bridging 4,4′-bipyridine (4,4′-bpy) ligand, displaying a hemi-directed coordination. The 4,4′-bpy ligan...

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Autor principal: Feng, Tian-Jun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152032/
https://www.ncbi.nlm.nih.gov/pubmed/21836919
http://dx.doi.org/10.1107/S1600536811022422
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author Feng, Tian-Jun
author_facet Feng, Tian-Jun
author_sort Feng, Tian-Jun
collection PubMed
description In the title dinuclear complex, [Pb(2)(C(7)H(4)ClO(2))(4)(C(10)H(8)N(2))], the Pb(II) atom is five-coordinated by four carboxyl­ate O atoms from two 2-chloro­benzoate ligands and one N atom from a bridging 4,4′-bipyridine (4,4′-bpy) ligand, displaying a hemi-directed coordination. The 4,4′-bpy ligand has an inversion center at the mid-point of the central C—C bond. The empty side of the metal ion is capped by two carboxyl­ate O atoms from a neighboring mol­ecule, with weak Pb⋯O contacts [Pb⋯O = 3.069 (2) and 3.071 (3) Å]. The crystal structure is stabilized by C—H⋯O hydrogen bonds and π–π stacking inter­actions between the benzene and pyridine rings [centroid–centroid distance = 3.749 (3) Å].
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spelling pubmed-31520322011-08-11 μ-4,4′-Bipyridine-κ(2) N:N′-bis­[bis­(2-chloro­benzoato-κ(2) O,O′)lead(II)] Feng, Tian-Jun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title dinuclear complex, [Pb(2)(C(7)H(4)ClO(2))(4)(C(10)H(8)N(2))], the Pb(II) atom is five-coordinated by four carboxyl­ate O atoms from two 2-chloro­benzoate ligands and one N atom from a bridging 4,4′-bipyridine (4,4′-bpy) ligand, displaying a hemi-directed coordination. The 4,4′-bpy ligand has an inversion center at the mid-point of the central C—C bond. The empty side of the metal ion is capped by two carboxyl­ate O atoms from a neighboring mol­ecule, with weak Pb⋯O contacts [Pb⋯O = 3.069 (2) and 3.071 (3) Å]. The crystal structure is stabilized by C—H⋯O hydrogen bonds and π–π stacking inter­actions between the benzene and pyridine rings [centroid–centroid distance = 3.749 (3) Å]. International Union of Crystallography 2011-06-18 /pmc/articles/PMC3152032/ /pubmed/21836919 http://dx.doi.org/10.1107/S1600536811022422 Text en © Tian-Jun Feng 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Feng, Tian-Jun
μ-4,4′-Bipyridine-κ(2) N:N′-bis­[bis­(2-chloro­benzoato-κ(2) O,O′)lead(II)]
title μ-4,4′-Bipyridine-κ(2) N:N′-bis­[bis­(2-chloro­benzoato-κ(2) O,O′)lead(II)]
title_full μ-4,4′-Bipyridine-κ(2) N:N′-bis­[bis­(2-chloro­benzoato-κ(2) O,O′)lead(II)]
title_fullStr μ-4,4′-Bipyridine-κ(2) N:N′-bis­[bis­(2-chloro­benzoato-κ(2) O,O′)lead(II)]
title_full_unstemmed μ-4,4′-Bipyridine-κ(2) N:N′-bis­[bis­(2-chloro­benzoato-κ(2) O,O′)lead(II)]
title_short μ-4,4′-Bipyridine-κ(2) N:N′-bis­[bis­(2-chloro­benzoato-κ(2) O,O′)lead(II)]
title_sort μ-4,4′-bipyridine-κ(2) n:n′-bis­[bis­(2-chloro­benzoato-κ(2) o,o′)lead(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152032/
https://www.ncbi.nlm.nih.gov/pubmed/21836919
http://dx.doi.org/10.1107/S1600536811022422
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