3-(2-Bromo­benz­yl)-1-methyl-1H-imidazol-3-ium bromide

In the title compound, C(11)H(12)BrN(2) (+)·Br(−), the imidazole and phenyl rings are nearly perpendicular, making a dihedral angle of 87.71 (7)°. The crystal structure is stabilized by non-classical inter­molecular C—H⋯Br hydrogen bonds and inversion-related mol­ecules are linked through π–π inter­...

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Detalles Bibliográficos
Autores principales: Dong, Jian-Yu, You, Tian-Pa
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152033/
https://www.ncbi.nlm.nih.gov/pubmed/21836980
http://dx.doi.org/10.1107/S1600536811019842
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author Dong, Jian-Yu
You, Tian-Pa
author_facet Dong, Jian-Yu
You, Tian-Pa
author_sort Dong, Jian-Yu
collection PubMed
description In the title compound, C(11)H(12)BrN(2) (+)·Br(−), the imidazole and phenyl rings are nearly perpendicular, making a dihedral angle of 87.71 (7)°. The crystal structure is stabilized by non-classical inter­molecular C—H⋯Br hydrogen bonds and inversion-related mol­ecules are linked through π–π inter­actions between the imidazole ring systems [centroid–centroid distance = 3.472 (6) Å].
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spelling pubmed-31520332011-08-11 3-(2-Bromo­benz­yl)-1-methyl-1H-imidazol-3-ium bromide Dong, Jian-Yu You, Tian-Pa Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(11)H(12)BrN(2) (+)·Br(−), the imidazole and phenyl rings are nearly perpendicular, making a dihedral angle of 87.71 (7)°. The crystal structure is stabilized by non-classical inter­molecular C—H⋯Br hydrogen bonds and inversion-related mol­ecules are linked through π–π inter­actions between the imidazole ring systems [centroid–centroid distance = 3.472 (6) Å]. International Union of Crystallography 2011-06-04 /pmc/articles/PMC3152033/ /pubmed/21836980 http://dx.doi.org/10.1107/S1600536811019842 Text en © Dong and You 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Dong, Jian-Yu
You, Tian-Pa
3-(2-Bromo­benz­yl)-1-methyl-1H-imidazol-3-ium bromide
title 3-(2-Bromo­benz­yl)-1-methyl-1H-imidazol-3-ium bromide
title_full 3-(2-Bromo­benz­yl)-1-methyl-1H-imidazol-3-ium bromide
title_fullStr 3-(2-Bromo­benz­yl)-1-methyl-1H-imidazol-3-ium bromide
title_full_unstemmed 3-(2-Bromo­benz­yl)-1-methyl-1H-imidazol-3-ium bromide
title_short 3-(2-Bromo­benz­yl)-1-methyl-1H-imidazol-3-ium bromide
title_sort 3-(2-bromo­benz­yl)-1-methyl-1h-imidazol-3-ium bromide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152033/
https://www.ncbi.nlm.nih.gov/pubmed/21836980
http://dx.doi.org/10.1107/S1600536811019842
work_keys_str_mv AT dongjianyu 32bromobenzyl1methyl1himidazol3iumbromide
AT youtianpa 32bromobenzyl1methyl1himidazol3iumbromide

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