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{N,N′-Bis[1-(pyridin-2-yl)ethyl­idene]­propane-1,3-diamine}­(thio­cyanato-κN)copper(II) tetra­fluoridoborate

In the title compound, [Cu(NCS)(C(17)H(20)N(4))]BF(4), the Cu(II) ion is five-coordinated by the four N atoms of the tetra­dentate Schiff base ligand and one N atom of a thio­cyanate ligand, thereby forming a square-pyramidal CuN(5) ccoordination geometry. The dihedral angle between the pyridine rin...

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Detalles Bibliográficos
Autor principal: Liu, Li-Jun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152035/
https://www.ncbi.nlm.nih.gov/pubmed/21836871
http://dx.doi.org/10.1107/S1600536811021040
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author Liu, Li-Jun
author_facet Liu, Li-Jun
author_sort Liu, Li-Jun
collection PubMed
description In the title compound, [Cu(NCS)(C(17)H(20)N(4))]BF(4), the Cu(II) ion is five-coordinated by the four N atoms of the tetra­dentate Schiff base ligand and one N atom of a thio­cyanate ligand, thereby forming a square-pyramidal CuN(5) ccoordination geometry. The dihedral angle between the pyridine rings of the Schiff base is 55.58 (14)°. The F atoms of the tetra­fluoridoborate anion are disordered over two sets of sites with occupancies of 0.614 (3) and 0.386 (3). In the crystal, the components are linked by C—H⋯F inter­actions.
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spelling pubmed-31520352011-08-11 {N,N′-Bis[1-(pyridin-2-yl)ethyl­idene]­propane-1,3-diamine}­(thio­cyanato-κN)copper(II) tetra­fluoridoborate Liu, Li-Jun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(NCS)(C(17)H(20)N(4))]BF(4), the Cu(II) ion is five-coordinated by the four N atoms of the tetra­dentate Schiff base ligand and one N atom of a thio­cyanate ligand, thereby forming a square-pyramidal CuN(5) ccoordination geometry. The dihedral angle between the pyridine rings of the Schiff base is 55.58 (14)°. The F atoms of the tetra­fluoridoborate anion are disordered over two sets of sites with occupancies of 0.614 (3) and 0.386 (3). In the crystal, the components are linked by C—H⋯F inter­actions. International Union of Crystallography 2011-06-11 /pmc/articles/PMC3152035/ /pubmed/21836871 http://dx.doi.org/10.1107/S1600536811021040 Text en © Li-Jun Liu 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Li-Jun
{N,N′-Bis[1-(pyridin-2-yl)ethyl­idene]­propane-1,3-diamine}­(thio­cyanato-κN)copper(II) tetra­fluoridoborate
title {N,N′-Bis[1-(pyridin-2-yl)ethyl­idene]­propane-1,3-diamine}­(thio­cyanato-κN)copper(II) tetra­fluoridoborate
title_full {N,N′-Bis[1-(pyridin-2-yl)ethyl­idene]­propane-1,3-diamine}­(thio­cyanato-κN)copper(II) tetra­fluoridoborate
title_fullStr {N,N′-Bis[1-(pyridin-2-yl)ethyl­idene]­propane-1,3-diamine}­(thio­cyanato-κN)copper(II) tetra­fluoridoborate
title_full_unstemmed {N,N′-Bis[1-(pyridin-2-yl)ethyl­idene]­propane-1,3-diamine}­(thio­cyanato-κN)copper(II) tetra­fluoridoborate
title_short {N,N′-Bis[1-(pyridin-2-yl)ethyl­idene]­propane-1,3-diamine}­(thio­cyanato-κN)copper(II) tetra­fluoridoborate
title_sort {n,n′-bis[1-(pyridin-2-yl)ethyl­idene]­propane-1,3-diamine}­(thio­cyanato-κn)copper(ii) tetra­fluoridoborate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152035/
https://www.ncbi.nlm.nih.gov/pubmed/21836871
http://dx.doi.org/10.1107/S1600536811021040
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