4-[(4-Chloro­phen­yl)diazen­yl]-3-meth­oxy­aniline

The title compound, C(13)H(12)ClN(3)O, exhibits a trans geometry about the N=N double bond in the solid state. The dihedral angle between the rings is 22.20 (8)°. Inter­molecular N—H⋯O hydrogen bonds between the amine and meth­oxy groups lead to the formation of a chain-like polymer along the c axis...

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Detalles Bibliográficos
Autores principales: Rofouei, Mohammad Kazem, Ghalami, Zahra, Attar Gharamaleki, Jafar, Bruno, Giuseppe, Amiri Rudbari, Hadi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152038/
https://www.ncbi.nlm.nih.gov/pubmed/21837217
http://dx.doi.org/10.1107/S160053681102472X
Descripción
Sumario:The title compound, C(13)H(12)ClN(3)O, exhibits a trans geometry about the N=N double bond in the solid state. The dihedral angle between the rings is 22.20 (8)°. Inter­molecular N—H⋯O hydrogen bonds between the amine and meth­oxy groups lead to the formation of a chain-like polymer along the c axis with a C(6) graph set. There is also weak non-classical C—H⋯N hydrogen bonds involving an aromatic C—H group and a diazenyl N atom, which connect the chains into a two-dimensional framework.

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