4-[(4-Chloro­phen­yl)diazen­yl]-3-meth­oxy­aniline

The title compound, C(13)H(12)ClN(3)O, exhibits a trans geometry about the N=N double bond in the solid state. The dihedral angle between the rings is 22.20 (8)°. Inter­molecular N—H⋯O hydrogen bonds between the amine and meth­oxy groups lead to the formation of a chain-like polymer along the c axis...

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Detalles Bibliográficos
Autores principales: Rofouei, Mohammad Kazem, Ghalami, Zahra, Attar Gharamaleki, Jafar, Bruno, Giuseppe, Amiri Rudbari, Hadi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152038/
https://www.ncbi.nlm.nih.gov/pubmed/21837217
http://dx.doi.org/10.1107/S160053681102472X
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author Rofouei, Mohammad Kazem
Ghalami, Zahra
Attar Gharamaleki, Jafar
Bruno, Giuseppe
Amiri Rudbari, Hadi
author_facet Rofouei, Mohammad Kazem
Ghalami, Zahra
Attar Gharamaleki, Jafar
Bruno, Giuseppe
Amiri Rudbari, Hadi
author_sort Rofouei, Mohammad Kazem
collection PubMed
description The title compound, C(13)H(12)ClN(3)O, exhibits a trans geometry about the N=N double bond in the solid state. The dihedral angle between the rings is 22.20 (8)°. Inter­molecular N—H⋯O hydrogen bonds between the amine and meth­oxy groups lead to the formation of a chain-like polymer along the c axis with a C(6) graph set. There is also weak non-classical C—H⋯N hydrogen bonds involving an aromatic C—H group and a diazenyl N atom, which connect the chains into a two-dimensional framework.
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spelling pubmed-31520382011-08-11 4-[(4-Chloro­phen­yl)diazen­yl]-3-meth­oxy­aniline Rofouei, Mohammad Kazem Ghalami, Zahra Attar Gharamaleki, Jafar Bruno, Giuseppe Amiri Rudbari, Hadi Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(13)H(12)ClN(3)O, exhibits a trans geometry about the N=N double bond in the solid state. The dihedral angle between the rings is 22.20 (8)°. Inter­molecular N—H⋯O hydrogen bonds between the amine and meth­oxy groups lead to the formation of a chain-like polymer along the c axis with a C(6) graph set. There is also weak non-classical C—H⋯N hydrogen bonds involving an aromatic C—H group and a diazenyl N atom, which connect the chains into a two-dimensional framework. International Union of Crystallography 2011-06-30 /pmc/articles/PMC3152038/ /pubmed/21837217 http://dx.doi.org/10.1107/S160053681102472X Text en © Rofouei et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Rofouei, Mohammad Kazem
Ghalami, Zahra
Attar Gharamaleki, Jafar
Bruno, Giuseppe
Amiri Rudbari, Hadi
4-[(4-Chloro­phen­yl)diazen­yl]-3-meth­oxy­aniline
title 4-[(4-Chloro­phen­yl)diazen­yl]-3-meth­oxy­aniline
title_full 4-[(4-Chloro­phen­yl)diazen­yl]-3-meth­oxy­aniline
title_fullStr 4-[(4-Chloro­phen­yl)diazen­yl]-3-meth­oxy­aniline
title_full_unstemmed 4-[(4-Chloro­phen­yl)diazen­yl]-3-meth­oxy­aniline
title_short 4-[(4-Chloro­phen­yl)diazen­yl]-3-meth­oxy­aniline
title_sort 4-[(4-chloro­phen­yl)diazen­yl]-3-meth­oxy­aniline
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152038/
https://www.ncbi.nlm.nih.gov/pubmed/21837217
http://dx.doi.org/10.1107/S160053681102472X
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