Sodium p-toluenesulfinate tetra­hydrate

The title compound, Na(+)·C(7)H(7)O(2)S(−)·4H(2)O, is the hydrate of the sodium salt of para-toluene­sulfinic acid. The mol­ecular geometry around the sulfur atom is tetra­hedral with X–S–Y angles spanning a range of 102.23 (6)–110.04 (6)°. In the crystal, the water mol­ecules connect the sodium cat...

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Detalles Bibliográficos
Autores principales: Betz, Richard, Gerber, Thomas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152039/
https://www.ncbi.nlm.nih.gov/pubmed/21836887
http://dx.doi.org/10.1107/S1600536811021738
Descripción
Sumario:The title compound, Na(+)·C(7)H(7)O(2)S(−)·4H(2)O, is the hydrate of the sodium salt of para-toluene­sulfinic acid. The mol­ecular geometry around the sulfur atom is tetra­hedral with X–S–Y angles spanning a range of 102.23 (6)–110.04 (6)°. In the crystal, the water mol­ecules connect the sodium cations into chains along the b axis via O—H⋯O hydrogen bonds. An inter­molecular O—H⋯π inter­action is also observed.

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