Sodium p-toluenesulfinate tetra­hydrate

The title compound, Na(+)·C(7)H(7)O(2)S(−)·4H(2)O, is the hydrate of the sodium salt of para-toluene­sulfinic acid. The mol­ecular geometry around the sulfur atom is tetra­hedral with X–S–Y angles spanning a range of 102.23 (6)–110.04 (6)°. In the crystal, the water mol­ecules connect the sodium cat...

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Detalles Bibliográficos
Autores principales: Betz, Richard, Gerber, Thomas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152039/
https://www.ncbi.nlm.nih.gov/pubmed/21836887
http://dx.doi.org/10.1107/S1600536811021738
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author Betz, Richard
Gerber, Thomas
author_facet Betz, Richard
Gerber, Thomas
author_sort Betz, Richard
collection PubMed
description The title compound, Na(+)·C(7)H(7)O(2)S(−)·4H(2)O, is the hydrate of the sodium salt of para-toluene­sulfinic acid. The mol­ecular geometry around the sulfur atom is tetra­hedral with X–S–Y angles spanning a range of 102.23 (6)–110.04 (6)°. In the crystal, the water mol­ecules connect the sodium cations into chains along the b axis via O—H⋯O hydrogen bonds. An inter­molecular O—H⋯π inter­action is also observed.
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spelling pubmed-31520392011-08-11 Sodium p-toluenesulfinate tetra­hydrate Betz, Richard Gerber, Thomas Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, Na(+)·C(7)H(7)O(2)S(−)·4H(2)O, is the hydrate of the sodium salt of para-toluene­sulfinic acid. The mol­ecular geometry around the sulfur atom is tetra­hedral with X–S–Y angles spanning a range of 102.23 (6)–110.04 (6)°. In the crystal, the water mol­ecules connect the sodium cations into chains along the b axis via O—H⋯O hydrogen bonds. An inter­molecular O—H⋯π inter­action is also observed. International Union of Crystallography 2011-06-11 /pmc/articles/PMC3152039/ /pubmed/21836887 http://dx.doi.org/10.1107/S1600536811021738 Text en © Betz and Gerber 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Betz, Richard
Gerber, Thomas
Sodium p-toluenesulfinate tetra­hydrate
title Sodium p-toluenesulfinate tetra­hydrate
title_full Sodium p-toluenesulfinate tetra­hydrate
title_fullStr Sodium p-toluenesulfinate tetra­hydrate
title_full_unstemmed Sodium p-toluenesulfinate tetra­hydrate
title_short Sodium p-toluenesulfinate tetra­hydrate
title_sort sodium p-toluenesulfinate tetra­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152039/
https://www.ncbi.nlm.nih.gov/pubmed/21836887
http://dx.doi.org/10.1107/S1600536811021738
work_keys_str_mv AT betzrichard sodiumptoluenesulfinatetetrahydrate
AT gerberthomas sodiumptoluenesulfinatetetrahydrate

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