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2,5-Bis[(3-hydroxypropyl)amino]-1,4-benzoquinone monohydrate
The title compound, C(12)H(18)N(2)O(4)·H(2)O, was obtained as a product of the reaction of hydroquinone with n-propanol amine. The compound crystallizes as a monohydrate, integrating water into its hydrogen-bonded network. Each diaminoquinone moiety forms two centrosymmetric 10-membered rings thro...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152041/ https://www.ncbi.nlm.nih.gov/pubmed/21837038 http://dx.doi.org/10.1107/S1600536811021635 |
Sumario: | The title compound, C(12)H(18)N(2)O(4)·H(2)O, was obtained as a product of the reaction of hydroquinone with n-propanol amine. The compound crystallizes as a monohydrate, integrating water into its hydrogen-bonded network. Each diaminoquinone moiety forms two centrosymmetric 10-membered rings through C=O⋯H—N bonds. The resulting bands along [102] are interlinked through hydroxy groups and water molecules into three-dimensional network. The chemically equivalent bond lengths in the diaminoquinone moiety exhibit a perceptible discrepancy [e.g. C=O bond lengths differ by 0.016 (2) Å], apparently as a result of asymmetric hydrogen bonding: one O atom serves as an acceptor of one hydrogen bond, whereas the other is an acceptor of two. |
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