Cargando…

2,5-Bis[(3-hy­droxy­prop­yl)amino]-1,4-benzoquinone monohydrate

The title compound, C(12)H(18)N(2)O(4)·H(2)O, was obtained as a product of the reaction of hydro­quinone with n-propanol amine. The compound crystallizes as a monohydrate, integrating water into its hydrogen-bonded network. Each diamino­quinone moiety forms two centrosymmetric 10-membered rings thro...

Descripción completa

Detalles Bibliográficos
Autores principales: Wang, Jian, Liu, Weiwei, Guan, Tongwei, Yin, Fujun, Sun, Yuxi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152041/
https://www.ncbi.nlm.nih.gov/pubmed/21837038
http://dx.doi.org/10.1107/S1600536811021635
_version_ 1782209713944920064
author Wang, Jian
Liu, Weiwei
Guan, Tongwei
Yin, Fujun
Sun, Yuxi
author_facet Wang, Jian
Liu, Weiwei
Guan, Tongwei
Yin, Fujun
Sun, Yuxi
author_sort Wang, Jian
collection PubMed
description The title compound, C(12)H(18)N(2)O(4)·H(2)O, was obtained as a product of the reaction of hydro­quinone with n-propanol amine. The compound crystallizes as a monohydrate, integrating water into its hydrogen-bonded network. Each diamino­quinone moiety forms two centrosymmetric 10-membered rings through C=O⋯H—N bonds. The resulting bands along [102] are inter­linked through hy­droxy groups and water mol­ecules into three-dimensional network. The chemically equivalent bond lengths in the diamino­quinone moiety exhibit a perceptible discrepancy [e.g. C=O bond lengths differ by 0.016 (2) Å], apparently as a result of asymmetric hydrogen bonding: one O atom serves as an acceptor of one hydrogen bond, whereas the other is an acceptor of two.
format Online
Article
Text
id pubmed-3152041
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-31520412011-08-11 2,5-Bis[(3-hy­droxy­prop­yl)amino]-1,4-benzoquinone monohydrate Wang, Jian Liu, Weiwei Guan, Tongwei Yin, Fujun Sun, Yuxi Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(12)H(18)N(2)O(4)·H(2)O, was obtained as a product of the reaction of hydro­quinone with n-propanol amine. The compound crystallizes as a monohydrate, integrating water into its hydrogen-bonded network. Each diamino­quinone moiety forms two centrosymmetric 10-membered rings through C=O⋯H—N bonds. The resulting bands along [102] are inter­linked through hy­droxy groups and water mol­ecules into three-dimensional network. The chemically equivalent bond lengths in the diamino­quinone moiety exhibit a perceptible discrepancy [e.g. C=O bond lengths differ by 0.016 (2) Å], apparently as a result of asymmetric hydrogen bonding: one O atom serves as an acceptor of one hydrogen bond, whereas the other is an acceptor of two. International Union of Crystallography 2011-06-11 /pmc/articles/PMC3152041/ /pubmed/21837038 http://dx.doi.org/10.1107/S1600536811021635 Text en © Wang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Wang, Jian
Liu, Weiwei
Guan, Tongwei
Yin, Fujun
Sun, Yuxi
2,5-Bis[(3-hy­droxy­prop­yl)amino]-1,4-benzoquinone monohydrate
title 2,5-Bis[(3-hy­droxy­prop­yl)amino]-1,4-benzoquinone monohydrate
title_full 2,5-Bis[(3-hy­droxy­prop­yl)amino]-1,4-benzoquinone monohydrate
title_fullStr 2,5-Bis[(3-hy­droxy­prop­yl)amino]-1,4-benzoquinone monohydrate
title_full_unstemmed 2,5-Bis[(3-hy­droxy­prop­yl)amino]-1,4-benzoquinone monohydrate
title_short 2,5-Bis[(3-hy­droxy­prop­yl)amino]-1,4-benzoquinone monohydrate
title_sort 2,5-bis[(3-hy­droxy­prop­yl)amino]-1,4-benzoquinone monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152041/
https://www.ncbi.nlm.nih.gov/pubmed/21837038
http://dx.doi.org/10.1107/S1600536811021635
work_keys_str_mv AT wangjian 25bis3hydroxypropylamino14benzoquinonemonohydrate
AT liuweiwei 25bis3hydroxypropylamino14benzoquinonemonohydrate
AT guantongwei 25bis3hydroxypropylamino14benzoquinonemonohydrate
AT yinfujun 25bis3hydroxypropylamino14benzoquinonemonohydrate
AT sunyuxi 25bis3hydroxypropylamino14benzoquinonemonohydrate