Cargando…
Poly[[(1,10-phenanthroline)(μ-l-tartrato)zinc] hexahydrate]
The title compouand {[Zn(C(4)H(4)O(6))(C(12)H(8)N(2))]·6H(2)O}(n), has a linear chain structure parallel to [100] with Zn(C(4)H(4)O(6))(C(12)H(8)N(2)) repeat units; the asymmetric unit consists of one Zn(2+) cation, one l-tartrate dianion, one 1,10-phenanthroline and six free water molecules. The Z...
| Autores principales: | , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152042/ https://www.ncbi.nlm.nih.gov/pubmed/21836831 http://dx.doi.org/10.1107/S1600536811024780 |
| _version_ | 1782209714168266752 |
|---|---|
| author | Dong, Gui-Ying He, Cui-Hong Liu, Tong-Fei Cui, Guang-Hua Deng, Xiao-Chen |
| author_facet | Dong, Gui-Ying He, Cui-Hong Liu, Tong-Fei Cui, Guang-Hua Deng, Xiao-Chen |
| author_sort | Dong, Gui-Ying |
| collection | PubMed |
| description | The title compouand {[Zn(C(4)H(4)O(6))(C(12)H(8)N(2))]·6H(2)O}(n), has a linear chain structure parallel to [100] with Zn(C(4)H(4)O(6))(C(12)H(8)N(2)) repeat units; the asymmetric unit consists of one Zn(2+) cation, one l-tartrate dianion, one 1,10-phenanthroline and six free water molecules. The Zn atom is in a distorted octahedral ZnN(2)O(4) coordination environment. The crystal structure is stabilized by O—H⋯O hydrogen bonds and π–π stacking of the phenanthroline units [centroid–centroid distances in the range 3.552 (2)–3.625 (2)Å] occurs between the chains. The title compound is isotypic with the Cu and Mn analogues. |
| format | Online Article Text |
| id | pubmed-3152042 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-31520422011-08-11 Poly[[(1,10-phenanthroline)(μ-l-tartrato)zinc] hexahydrate] Dong, Gui-Ying He, Cui-Hong Liu, Tong-Fei Cui, Guang-Hua Deng, Xiao-Chen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compouand {[Zn(C(4)H(4)O(6))(C(12)H(8)N(2))]·6H(2)O}(n), has a linear chain structure parallel to [100] with Zn(C(4)H(4)O(6))(C(12)H(8)N(2)) repeat units; the asymmetric unit consists of one Zn(2+) cation, one l-tartrate dianion, one 1,10-phenanthroline and six free water molecules. The Zn atom is in a distorted octahedral ZnN(2)O(4) coordination environment. The crystal structure is stabilized by O—H⋯O hydrogen bonds and π–π stacking of the phenanthroline units [centroid–centroid distances in the range 3.552 (2)–3.625 (2)Å] occurs between the chains. The title compound is isotypic with the Cu and Mn analogues. International Union of Crystallography 2011-06-30 /pmc/articles/PMC3152042/ /pubmed/21836831 http://dx.doi.org/10.1107/S1600536811024780 Text en © Dong et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Dong, Gui-Ying He, Cui-Hong Liu, Tong-Fei Cui, Guang-Hua Deng, Xiao-Chen Poly[[(1,10-phenanthroline)(μ-l-tartrato)zinc] hexahydrate] |
| title | Poly[[(1,10-phenanthroline)(μ-l-tartrato)zinc] hexahydrate] |
| title_full | Poly[[(1,10-phenanthroline)(μ-l-tartrato)zinc] hexahydrate] |
| title_fullStr | Poly[[(1,10-phenanthroline)(μ-l-tartrato)zinc] hexahydrate] |
| title_full_unstemmed | Poly[[(1,10-phenanthroline)(μ-l-tartrato)zinc] hexahydrate] |
| title_short | Poly[[(1,10-phenanthroline)(μ-l-tartrato)zinc] hexahydrate] |
| title_sort | poly[[(1,10-phenanthroline)(μ-l-tartrato)zinc] hexahydrate] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152042/ https://www.ncbi.nlm.nih.gov/pubmed/21836831 http://dx.doi.org/10.1107/S1600536811024780 |
| work_keys_str_mv | AT dongguiying poly110phenanthrolinemltartratozinchexahydrate AT hecuihong poly110phenanthrolinemltartratozinchexahydrate AT liutongfei poly110phenanthrolinemltartratozinchexahydrate AT cuiguanghua poly110phenanthrolinemltartratozinchexahydrate AT dengxiaochen poly110phenanthrolinemltartratozinchexahydrate |