2-(4-Bromo­phen­yl)-2-oxoethyl 4-bromo­benzoate

The asymmetric unit of the title compound, C(15)H(10)Br(2)O(3), consists of three crystallographically independent mol­ecules (A, B and C). The phenyl rings in mol­ecules A, B and C make dihedral angles of 6.1 (3), 3.2 (2) and 54.6 (2)° to each other, respectively. In the crystal, mol­ecules are lin...

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Autores principales: Fun, Hoong-Kun, Arshad, Suhana, Garudachari, B., Isloor, Arun M., Satyanarayan, M. N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152043/
https://www.ncbi.nlm.nih.gov/pubmed/21836992
http://dx.doi.org/10.1107/S1600536811020654
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author Fun, Hoong-Kun
Arshad, Suhana
Garudachari, B.
Isloor, Arun M.
Satyanarayan, M. N.
author_facet Fun, Hoong-Kun
Arshad, Suhana
Garudachari, B.
Isloor, Arun M.
Satyanarayan, M. N.
author_sort Fun, Hoong-Kun
collection PubMed
description The asymmetric unit of the title compound, C(15)H(10)Br(2)O(3), consists of three crystallographically independent mol­ecules (A, B and C). The phenyl rings in mol­ecules A, B and C make dihedral angles of 6.1 (3), 3.2 (2) and 54.6 (2)° to each other, respectively. In the crystal, mol­ecules are linked into two-dimensional layers parallel to the ab plane by inter­molecular C—H⋯O hydrogen bonds. The crystal structure is further stabilized by C—H⋯π inter­actions. The studied crystal is an inversion twin, the refined ratio of the twin components being 0.128 (8):0.872 (8).
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spelling pubmed-31520432011-08-11 2-(4-Bromo­phen­yl)-2-oxoethyl 4-bromo­benzoate Fun, Hoong-Kun Arshad, Suhana Garudachari, B. Isloor, Arun M. Satyanarayan, M. N. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(15)H(10)Br(2)O(3), consists of three crystallographically independent mol­ecules (A, B and C). The phenyl rings in mol­ecules A, B and C make dihedral angles of 6.1 (3), 3.2 (2) and 54.6 (2)° to each other, respectively. In the crystal, mol­ecules are linked into two-dimensional layers parallel to the ab plane by inter­molecular C—H⋯O hydrogen bonds. The crystal structure is further stabilized by C—H⋯π inter­actions. The studied crystal is an inversion twin, the refined ratio of the twin components being 0.128 (8):0.872 (8). International Union of Crystallography 2011-06-04 /pmc/articles/PMC3152043/ /pubmed/21836992 http://dx.doi.org/10.1107/S1600536811020654 Text en © Fun et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Arshad, Suhana
Garudachari, B.
Isloor, Arun M.
Satyanarayan, M. N.
2-(4-Bromo­phen­yl)-2-oxoethyl 4-bromo­benzoate
title 2-(4-Bromo­phen­yl)-2-oxoethyl 4-bromo­benzoate
title_full 2-(4-Bromo­phen­yl)-2-oxoethyl 4-bromo­benzoate
title_fullStr 2-(4-Bromo­phen­yl)-2-oxoethyl 4-bromo­benzoate
title_full_unstemmed 2-(4-Bromo­phen­yl)-2-oxoethyl 4-bromo­benzoate
title_short 2-(4-Bromo­phen­yl)-2-oxoethyl 4-bromo­benzoate
title_sort 2-(4-bromo­phen­yl)-2-oxoethyl 4-bromo­benzoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152043/
https://www.ncbi.nlm.nih.gov/pubmed/21836992
http://dx.doi.org/10.1107/S1600536811020654
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