Cargando…
catena-Poly[[bis(nitrato-κO)copper(II)]-μ-1,4-bis(4,5-dihydro-1,3-oxazol-2-yl)benzene-κ(2) N:N′]
In the title coordination polymer, [Cu(NO(3))(2)(C(12)H(12)N(2)O(2))](n), the Cu(II) ion, situated on an inversion center, is coordinated by two O atoms from two nitrate anions and two N atoms from two 1,4-bis(4,5-dihydro-1,3-oxazol-2-yl)benzene (L) ligands in a distorted square-planar geometry. Ea...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152049/ https://www.ncbi.nlm.nih.gov/pubmed/21836874 http://dx.doi.org/10.1107/S1600536811020605 |
_version_ | 1782209715713867776 |
---|---|
author | Wang, Pin-Ning Yeh, Chun-Wei Tsai, Hui-An Wang, Ju-Chun Suen, Maw-Cherng |
author_facet | Wang, Pin-Ning Yeh, Chun-Wei Tsai, Hui-An Wang, Ju-Chun Suen, Maw-Cherng |
author_sort | Wang, Pin-Ning |
collection | PubMed |
description | In the title coordination polymer, [Cu(NO(3))(2)(C(12)H(12)N(2)O(2))](n), the Cu(II) ion, situated on an inversion center, is coordinated by two O atoms from two nitrate anions and two N atoms from two 1,4-bis(4,5-dihydro-1,3-oxazol-2-yl)benzene (L) ligands in a distorted square-planar geometry. Each L ligand also lies across an inversion center and bridges two Cu(II) ions, forming a polymeric chain running along the [101] direction. The three O atoms of the nitrate group are disordered over two positions in a 3:2 ratio. |
format | Online Article Text |
id | pubmed-3152049 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31520492011-08-11 catena-Poly[[bis(nitrato-κO)copper(II)]-μ-1,4-bis(4,5-dihydro-1,3-oxazol-2-yl)benzene-κ(2) N:N′] Wang, Pin-Ning Yeh, Chun-Wei Tsai, Hui-An Wang, Ju-Chun Suen, Maw-Cherng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, [Cu(NO(3))(2)(C(12)H(12)N(2)O(2))](n), the Cu(II) ion, situated on an inversion center, is coordinated by two O atoms from two nitrate anions and two N atoms from two 1,4-bis(4,5-dihydro-1,3-oxazol-2-yl)benzene (L) ligands in a distorted square-planar geometry. Each L ligand also lies across an inversion center and bridges two Cu(II) ions, forming a polymeric chain running along the [101] direction. The three O atoms of the nitrate group are disordered over two positions in a 3:2 ratio. International Union of Crystallography 2011-06-11 /pmc/articles/PMC3152049/ /pubmed/21836874 http://dx.doi.org/10.1107/S1600536811020605 Text en © Wang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wang, Pin-Ning Yeh, Chun-Wei Tsai, Hui-An Wang, Ju-Chun Suen, Maw-Cherng catena-Poly[[bis(nitrato-κO)copper(II)]-μ-1,4-bis(4,5-dihydro-1,3-oxazol-2-yl)benzene-κ(2) N:N′] |
title |
catena-Poly[[bis(nitrato-κO)copper(II)]-μ-1,4-bis(4,5-dihydro-1,3-oxazol-2-yl)benzene-κ(2)
N:N′] |
title_full |
catena-Poly[[bis(nitrato-κO)copper(II)]-μ-1,4-bis(4,5-dihydro-1,3-oxazol-2-yl)benzene-κ(2)
N:N′] |
title_fullStr |
catena-Poly[[bis(nitrato-κO)copper(II)]-μ-1,4-bis(4,5-dihydro-1,3-oxazol-2-yl)benzene-κ(2)
N:N′] |
title_full_unstemmed |
catena-Poly[[bis(nitrato-κO)copper(II)]-μ-1,4-bis(4,5-dihydro-1,3-oxazol-2-yl)benzene-κ(2)
N:N′] |
title_short |
catena-Poly[[bis(nitrato-κO)copper(II)]-μ-1,4-bis(4,5-dihydro-1,3-oxazol-2-yl)benzene-κ(2)
N:N′] |
title_sort | catena-poly[[bis(nitrato-κo)copper(ii)]-μ-1,4-bis(4,5-dihydro-1,3-oxazol-2-yl)benzene-κ(2)
n:n′] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152049/ https://www.ncbi.nlm.nih.gov/pubmed/21836874 http://dx.doi.org/10.1107/S1600536811020605 |
work_keys_str_mv | AT wangpinning catenapolybisnitratokocopperiim14bis45dihydro13oxazol2ylbenzenek2nn AT yehchunwei catenapolybisnitratokocopperiim14bis45dihydro13oxazol2ylbenzenek2nn AT tsaihuian catenapolybisnitratokocopperiim14bis45dihydro13oxazol2ylbenzenek2nn AT wangjuchun catenapolybisnitratokocopperiim14bis45dihydro13oxazol2ylbenzenek2nn AT suenmawcherng catenapolybisnitratokocopperiim14bis45dihydro13oxazol2ylbenzenek2nn |