Cargando…

catena-Poly[[bis­(nitrato-κO)copper(II)]-μ-1,4-bis­(4,5-dihydro-1,3-oxazol-2-yl)­benzene-κ(2) N:N′]

In the title coordination polymer, [Cu(NO(3))(2)(C(12)H(12)N(2)O(2))](n), the Cu(II) ion, situated on an inversion center, is coordinated by two O atoms from two nitrate anions and two N atoms from two 1,4-bis­(4,5-dihydro-1,3-oxazol-2-yl)benzene (L) ligands in a distorted square-planar geometry. Ea...

Descripción completa

Detalles Bibliográficos
Autores principales: Wang, Pin-Ning, Yeh, Chun-Wei, Tsai, Hui-An, Wang, Ju-Chun, Suen, Maw-Cherng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152049/
https://www.ncbi.nlm.nih.gov/pubmed/21836874
http://dx.doi.org/10.1107/S1600536811020605
_version_ 1782209715713867776
author Wang, Pin-Ning
Yeh, Chun-Wei
Tsai, Hui-An
Wang, Ju-Chun
Suen, Maw-Cherng
author_facet Wang, Pin-Ning
Yeh, Chun-Wei
Tsai, Hui-An
Wang, Ju-Chun
Suen, Maw-Cherng
author_sort Wang, Pin-Ning
collection PubMed
description In the title coordination polymer, [Cu(NO(3))(2)(C(12)H(12)N(2)O(2))](n), the Cu(II) ion, situated on an inversion center, is coordinated by two O atoms from two nitrate anions and two N atoms from two 1,4-bis­(4,5-dihydro-1,3-oxazol-2-yl)benzene (L) ligands in a distorted square-planar geometry. Each L ligand also lies across an inversion center and bridges two Cu(II) ions, forming a polymeric chain running along the [101] direction. The three O atoms of the nitrate group are disordered over two positions in a 3:2 ratio.
format Online
Article
Text
id pubmed-3152049
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-31520492011-08-11 catena-Poly[[bis­(nitrato-κO)copper(II)]-μ-1,4-bis­(4,5-dihydro-1,3-oxazol-2-yl)­benzene-κ(2) N:N′] Wang, Pin-Ning Yeh, Chun-Wei Tsai, Hui-An Wang, Ju-Chun Suen, Maw-Cherng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, [Cu(NO(3))(2)(C(12)H(12)N(2)O(2))](n), the Cu(II) ion, situated on an inversion center, is coordinated by two O atoms from two nitrate anions and two N atoms from two 1,4-bis­(4,5-dihydro-1,3-oxazol-2-yl)benzene (L) ligands in a distorted square-planar geometry. Each L ligand also lies across an inversion center and bridges two Cu(II) ions, forming a polymeric chain running along the [101] direction. The three O atoms of the nitrate group are disordered over two positions in a 3:2 ratio. International Union of Crystallography 2011-06-11 /pmc/articles/PMC3152049/ /pubmed/21836874 http://dx.doi.org/10.1107/S1600536811020605 Text en © Wang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Pin-Ning
Yeh, Chun-Wei
Tsai, Hui-An
Wang, Ju-Chun
Suen, Maw-Cherng
catena-Poly[[bis­(nitrato-κO)copper(II)]-μ-1,4-bis­(4,5-dihydro-1,3-oxazol-2-yl)­benzene-κ(2) N:N′]
title catena-Poly[[bis­(nitrato-κO)copper(II)]-μ-1,4-bis­(4,5-dihydro-1,3-oxazol-2-yl)­benzene-κ(2) N:N′]
title_full catena-Poly[[bis­(nitrato-κO)copper(II)]-μ-1,4-bis­(4,5-dihydro-1,3-oxazol-2-yl)­benzene-κ(2) N:N′]
title_fullStr catena-Poly[[bis­(nitrato-κO)copper(II)]-μ-1,4-bis­(4,5-dihydro-1,3-oxazol-2-yl)­benzene-κ(2) N:N′]
title_full_unstemmed catena-Poly[[bis­(nitrato-κO)copper(II)]-μ-1,4-bis­(4,5-dihydro-1,3-oxazol-2-yl)­benzene-κ(2) N:N′]
title_short catena-Poly[[bis­(nitrato-κO)copper(II)]-μ-1,4-bis­(4,5-dihydro-1,3-oxazol-2-yl)­benzene-κ(2) N:N′]
title_sort catena-poly[[bis­(nitrato-κo)copper(ii)]-μ-1,4-bis­(4,5-dihydro-1,3-oxazol-2-yl)­benzene-κ(2) n:n′]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152049/
https://www.ncbi.nlm.nih.gov/pubmed/21836874
http://dx.doi.org/10.1107/S1600536811020605
work_keys_str_mv AT wangpinning catenapolybisnitratokocopperiim14bis45dihydro13oxazol2ylbenzenek2nn
AT yehchunwei catenapolybisnitratokocopperiim14bis45dihydro13oxazol2ylbenzenek2nn
AT tsaihuian catenapolybisnitratokocopperiim14bis45dihydro13oxazol2ylbenzenek2nn
AT wangjuchun catenapolybisnitratokocopperiim14bis45dihydro13oxazol2ylbenzenek2nn
AT suenmawcherng catenapolybisnitratokocopperiim14bis45dihydro13oxazol2ylbenzenek2nn