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Propane-1,2-diaminium bis(pyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))mercurate(II) dihydrate
In the title compound, (C(3)H(12)N(2))[Hg(C(7)H(3)NO(4))(2)]·2H(2)O, the Hg(II) ion is coordinated by four O and two N atoms of two pyridine-2,6-dicarboxylate (pydc) ligands in a distorted octahedral environment. The structure contains two uncoordinated water molecules. In the crystal, N—H⋯O, O—H...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152051/ https://www.ncbi.nlm.nih.gov/pubmed/21836957 http://dx.doi.org/10.1107/S1600536811024366 |
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author | Agah, Ali Akbar Saadati Moshtaghin, Hamid Reza Notash, Behrouz Amiri Rudbari, Hadi Bruno, Giuseppe |
author_facet | Agah, Ali Akbar Saadati Moshtaghin, Hamid Reza Notash, Behrouz Amiri Rudbari, Hadi Bruno, Giuseppe |
author_sort | Agah, Ali Akbar |
collection | PubMed |
description | In the title compound, (C(3)H(12)N(2))[Hg(C(7)H(3)NO(4))(2)]·2H(2)O, the Hg(II) ion is coordinated by four O and two N atoms of two pyridine-2,6-dicarboxylate (pydc) ligands in a distorted octahedral environment. The structure contains two uncoordinated water molecules. In the crystal, N—H⋯O, O—H⋯O and weak C—H⋯O hydrogen bonds and π–π stacking interactions between the pyridine rings of the pydc ligands, with a centroid–centroid distance of 3.4582 (18) Å, stabilize the structure. |
format | Online Article Text |
id | pubmed-3152051 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31520512011-08-11 Propane-1,2-diaminium bis(pyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))mercurate(II) dihydrate Agah, Ali Akbar Saadati Moshtaghin, Hamid Reza Notash, Behrouz Amiri Rudbari, Hadi Bruno, Giuseppe Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(3)H(12)N(2))[Hg(C(7)H(3)NO(4))(2)]·2H(2)O, the Hg(II) ion is coordinated by four O and two N atoms of two pyridine-2,6-dicarboxylate (pydc) ligands in a distorted octahedral environment. The structure contains two uncoordinated water molecules. In the crystal, N—H⋯O, O—H⋯O and weak C—H⋯O hydrogen bonds and π–π stacking interactions between the pyridine rings of the pydc ligands, with a centroid–centroid distance of 3.4582 (18) Å, stabilize the structure. International Union of Crystallography 2011-06-25 /pmc/articles/PMC3152051/ /pubmed/21836957 http://dx.doi.org/10.1107/S1600536811024366 Text en © Agah et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Agah, Ali Akbar Saadati Moshtaghin, Hamid Reza Notash, Behrouz Amiri Rudbari, Hadi Bruno, Giuseppe Propane-1,2-diaminium bis(pyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))mercurate(II) dihydrate |
title | Propane-1,2-diaminium bis(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))mercurate(II) dihydrate |
title_full | Propane-1,2-diaminium bis(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))mercurate(II) dihydrate |
title_fullStr | Propane-1,2-diaminium bis(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))mercurate(II) dihydrate |
title_full_unstemmed | Propane-1,2-diaminium bis(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))mercurate(II) dihydrate |
title_short | Propane-1,2-diaminium bis(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))mercurate(II) dihydrate |
title_sort | propane-1,2-diaminium bis(pyridine-2,6-dicarboxylato-κ(3)
o
(2),n,o
(6))mercurate(ii) dihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152051/ https://www.ncbi.nlm.nih.gov/pubmed/21836957 http://dx.doi.org/10.1107/S1600536811024366 |
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