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Propane-1,2-diaminium bis­(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))mercurate(II) dihydrate

In the title compound, (C(3)H(12)N(2))[Hg(C(7)H(3)NO(4))(2)]·2H(2)O, the Hg(II) ion is coordinated by four O and two N atoms of two pyridine-2,6-dicarboxyl­ate (pydc) ligands in a distorted octa­hedral environment. The structure contains two uncoordinated water mol­ecules. In the crystal, N—H⋯O, O—H...

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Autores principales: Agah, Ali Akbar, Saadati Moshtaghin, Hamid Reza, Notash, Behrouz, Amiri Rudbari, Hadi, Bruno, Giuseppe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152051/
https://www.ncbi.nlm.nih.gov/pubmed/21836957
http://dx.doi.org/10.1107/S1600536811024366
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author Agah, Ali Akbar
Saadati Moshtaghin, Hamid Reza
Notash, Behrouz
Amiri Rudbari, Hadi
Bruno, Giuseppe
author_facet Agah, Ali Akbar
Saadati Moshtaghin, Hamid Reza
Notash, Behrouz
Amiri Rudbari, Hadi
Bruno, Giuseppe
author_sort Agah, Ali Akbar
collection PubMed
description In the title compound, (C(3)H(12)N(2))[Hg(C(7)H(3)NO(4))(2)]·2H(2)O, the Hg(II) ion is coordinated by four O and two N atoms of two pyridine-2,6-dicarboxyl­ate (pydc) ligands in a distorted octa­hedral environment. The structure contains two uncoordinated water mol­ecules. In the crystal, N—H⋯O, O—H⋯O and weak C—H⋯O hydrogen bonds and π–π stacking inter­actions between the pyridine rings of the pydc ligands, with a centroid–centroid distance of 3.4582 (18) Å, stabilize the structure.
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spelling pubmed-31520512011-08-11 Propane-1,2-diaminium bis­(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))mercurate(II) dihydrate Agah, Ali Akbar Saadati Moshtaghin, Hamid Reza Notash, Behrouz Amiri Rudbari, Hadi Bruno, Giuseppe Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(3)H(12)N(2))[Hg(C(7)H(3)NO(4))(2)]·2H(2)O, the Hg(II) ion is coordinated by four O and two N atoms of two pyridine-2,6-dicarboxyl­ate (pydc) ligands in a distorted octa­hedral environment. The structure contains two uncoordinated water mol­ecules. In the crystal, N—H⋯O, O—H⋯O and weak C—H⋯O hydrogen bonds and π–π stacking inter­actions between the pyridine rings of the pydc ligands, with a centroid–centroid distance of 3.4582 (18) Å, stabilize the structure. International Union of Crystallography 2011-06-25 /pmc/articles/PMC3152051/ /pubmed/21836957 http://dx.doi.org/10.1107/S1600536811024366 Text en © Agah et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Agah, Ali Akbar
Saadati Moshtaghin, Hamid Reza
Notash, Behrouz
Amiri Rudbari, Hadi
Bruno, Giuseppe
Propane-1,2-diaminium bis­(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))mercurate(II) dihydrate
title Propane-1,2-diaminium bis­(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))mercurate(II) dihydrate
title_full Propane-1,2-diaminium bis­(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))mercurate(II) dihydrate
title_fullStr Propane-1,2-diaminium bis­(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))mercurate(II) dihydrate
title_full_unstemmed Propane-1,2-diaminium bis­(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))mercurate(II) dihydrate
title_short Propane-1,2-diaminium bis­(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))mercurate(II) dihydrate
title_sort propane-1,2-diaminium bis­(pyridine-2,6-dicarboxyl­ato-κ(3) o (2),n,o (6))mercurate(ii) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152051/
https://www.ncbi.nlm.nih.gov/pubmed/21836957
http://dx.doi.org/10.1107/S1600536811024366
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