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Ethylenediaminium dinicotinate
In the title compound, C(2)H(10)N(2) (2+)·2C(6)H(4)NO(2) (−), the cation lies on an inversion centre. The asymmetric unit is composed of one nicotinate anion and one half ethylenediaminium cation. All the amino H atoms are involved in N—H⋯O and N—H⋯N hydrogen bonds. These hydrogen bonds link the io...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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International Union of Crystallography
2011
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152055/ https://www.ncbi.nlm.nih.gov/pubmed/21837162 http://dx.doi.org/10.1107/S1600536811023877 |
| _version_ | 1782209717118959616 |
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| author | Zhao, Liang Feng, Li-ping |
| author_facet | Zhao, Liang Feng, Li-ping |
| author_sort | Zhao, Liang |
| collection | PubMed |
| description | In the title compound, C(2)H(10)N(2) (2+)·2C(6)H(4)NO(2) (−), the cation lies on an inversion centre. The asymmetric unit is composed of one nicotinate anion and one half ethylenediaminium cation. All the amino H atoms are involved in N—H⋯O and N—H⋯N hydrogen bonds. These hydrogen bonds link the ionic units into a three-dimensional network. In addition, π–π interactions between pyridine rings [centroid–centroid distance = 3.6037 (7) Å] further stabilize the crystal structure. |
| format | Online Article Text |
| id | pubmed-3152055 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-31520552011-08-11 Ethylenediaminium dinicotinate Zhao, Liang Feng, Li-ping Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(2)H(10)N(2) (2+)·2C(6)H(4)NO(2) (−), the cation lies on an inversion centre. The asymmetric unit is composed of one nicotinate anion and one half ethylenediaminium cation. All the amino H atoms are involved in N—H⋯O and N—H⋯N hydrogen bonds. These hydrogen bonds link the ionic units into a three-dimensional network. In addition, π–π interactions between pyridine rings [centroid–centroid distance = 3.6037 (7) Å] further stabilize the crystal structure. International Union of Crystallography 2011-06-25 /pmc/articles/PMC3152055/ /pubmed/21837162 http://dx.doi.org/10.1107/S1600536811023877 Text en © Zhao and Feng 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Zhao, Liang Feng, Li-ping Ethylenediaminium dinicotinate |
| title | Ethylenediaminium dinicotinate |
| title_full | Ethylenediaminium dinicotinate |
| title_fullStr | Ethylenediaminium dinicotinate |
| title_full_unstemmed | Ethylenediaminium dinicotinate |
| title_short | Ethylenediaminium dinicotinate |
| title_sort | ethylenediaminium dinicotinate |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152055/ https://www.ncbi.nlm.nih.gov/pubmed/21837162 http://dx.doi.org/10.1107/S1600536811023877 |
| work_keys_str_mv | AT zhaoliang ethylenediaminiumdinicotinate AT fengliping ethylenediaminiumdinicotinate |